Karim Zaghib

Last updated
Karim Zaghib
Born (1963-12-25) 25 December 1963 (age 59)
CitizenshipAlgerian, Canadian
Education Grenoble Institute of Technology (DEA, PhD)
Pierre et Marie Curie University (HDR)
Scientific career
Fields
Institutions
Thesis Analyse de la cinétique de cémentation du cuivre par le zinc en milieu sulfate [1]
Doctoral advisor Bernadette Nguyen

Karim Zaghib FRSC FCAE (born in 1963) is an Algerian-Canadian electrochemist and materials scientist known for his contributions to the field of energy storage and conversion. He is currently Professor of Chemical and Materials Engineering at Concordia University. As former director of research at Hydro-Québec, he helped to make it the world’s first company to use lithium iron phosphate in cathodes, and to develop natural graphite and nanotitanate anodes. [2]

Contents

Early life and education

Karim Zaghib was born in Constantine and grew up in Setif, Algeria. [3] He obtained the D.E.A. degree in 1987 and the Ph.D. degree in Electrochemistry under the direction of Prof. Bernadette Nguyen in 1990, both from the Grenoble Institute of Technology, and the Habilitation degree in Physics from Pierre and Marie Curie University (Paris VI) in 2002. [4]

Career

From 1990 to 1992, Karim Zaghib was a postdoctoral fellow at CNRS and Saft investigating chemical lithiation of graphite and carbon fibers. From 1992 to 1995, he was a guest researcher working on lithium-ion batteries for the Ministry of International Trade and Industry of Japan at the Osaka National Research Institute. [4] Following his research in Japan, he joined in 1995 the Hydro-Québec Research Institute where he was instrumental in introducing Li-ion technology to the company. He was promoted Director of the Energy Storage and Conversion Division of the company in 2007. In 2017, he founded the Center of Excellence in Transportation Electrification and Energy Storage of Hydro-Québec. [5] In 2014, Karim Zaghib co-founded Esstalion Technologies, a joint-venture between Sony and Hydro-Québec which aimed to research and develop large-scale energy storage systems for power grids. [6] From 2020 to 2021, he was a strategic advisor at Investissement Québec on the Government of Québec initiative to establish a battery industry from mining to electric vehicles and concurrently Professor of Practice at McGill University in the Department of Mining and Materials Engineering. [7] [8] In 2022, he joined Concordia University as Professor of Chemical and Materials Engineering. [9]

Research

Karim Zaghib’s research concerns rechargeable batteries, electrochromic devices and electrochemistry of carbon materials. During his PhD studies, he developed aluminium-manganese-lithium alloys in molten salts as negative electrode for lithium-ion batteries and investigated the copper and zinc displacement reaction. [10] He published a new method to enhance the electrodeposition of metals (electrolysis aided cementation) in Electrochimica Acta. [11] In the context of the New Sunshine Project, he developed vapor grown carbon fibers as a negative electrode, and identified additives and solid polymer and gel electrolytes for Li-ion batteries with DKS, Japan. [12]

At Hydro-Québec, Karim Zaghib started a collaboration with Prof. Michel Armand on new battery materials and electrolytes and with Prof. Kim Kinoshita from Lawrence Berkeley National Laboratory to understand the oxidation and irreversible capacity loss versus the particle size of natural graphite by proposing several models to consider the role of the basal plane and edge sites. [13] He introduced nanostructured Li4Ti5O12 (LTO) anodes for lithium-ion and solid-state batteries and new solid Li-ion batteries based on expanded metal with solid polymer or gel electrolyte in combination with 3V and 4V cathode materials and LTO. [12] His collaboration with Prof. Armand led to the invention of the hybrid supercapacitor using LTO negative and carbon positive electrodes, [14] the carbon-coated LiFePO4 cathode which enabled the commercial lithium iron phosphate battery, [15] and the LiFSI class of ionic liquids and electrolytes. [16]

During the last 28 years, Karim Zaghib has actively collaborated with Chemistry Nobel Prize Laureate 2019 Prof. John B. Goodenough from the University of Texas at Austin, Prof. Michel Armand, and Prof. Christian Julien and Prof. Alain Mauger from Sorbonne University to develop olivine and silicate cathode materials for Li-ion batteries. [17] Hydro-Québec and the University of Texas at Austin partnered to commercialize the LiFePO4 cathode. [18] Karim Zaghib also collaborated with Dr Michael Thackeray from Argonne National Laboratory on the commercialization of spinel lithium nanotitanate (LTO) anodes. [19]

Karim Zaghib is a co-inventor of 600 patents associated to 62 licenses. He has participated in more than 420 referred articles and 22 monographs and co-wrote the reference textbook Lithium Batteries: Science and Technology published by Springer, also translated into Chinese. [20] [21] His publications has been highly cited, with an h-index of 83 as of 2023, according to Google Scholar. [22]

Awards and honors

Karim Zaghib has received numerous national and international awards, including:

See also

Related Research Articles

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An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit. Electrodes are essential parts of batteries that can consist of a variety of materials depending on the type of battery.

<span class="mw-page-title-main">Lithium-ion battery</span> Rechargeable battery type

A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. The negative electrode of a conventional lithium-ion cell is typically graphite, a form of carbon. This negative electrode is sometimes called the anode as it acts as an anode during discharge. The positive electrode is typically a metal oxide; the positive electrode is sometimes called the cathode as it acts as a cathode during discharge. Positive and negative electrodes remain positive and negative in normal use whether charging or discharging and are therefore clearer terms to use than anode and cathode which are reversed during charging.

<span class="mw-page-title-main">Lithium polymer battery</span> Lithium-ion battery using a polymer electrolyte

A lithium polymer battery, or more correctly lithium-ion polymer battery, is a rechargeable battery of lithium-ion technology using a polymer electrolyte instead of a liquid electrolyte. High conductivity semisolid (gel) polymers form this electrolyte. These batteries provide higher specific energy than other lithium battery types and are used in applications where weight is a critical feature, such as mobile devices, radio-controlled aircraft and some electric vehicles.

<span class="mw-page-title-main">M. Stanley Whittingham</span> British-American chemist

Michael Stanley Whittingham is a British-American chemist. He is currently a professor of chemistry and director of both the Institute for Materials Research and the Materials Science and Engineering program at Binghamton University, State University of New York. He also serves as director of the Northeastern Center for Chemical Energy Storage (NECCES) of the U.S. Department of Energy at Binghamton. He was awarded the Nobel Prize in Chemistry in 2019 alongside Akira Yoshino and John B. Goodenough.

<span class="mw-page-title-main">Lithium iron phosphate battery</span> Type of rechargeable battery

The lithium iron phosphate battery or LFP battery is a type of lithium-ion battery using lithium iron phosphate as the cathode material, and a graphitic carbon electrode with a metallic backing as the anode. Because of their lower cost, high safety, low toxicity, long cycle life and other factors, LFP batteries are finding a number of roles in vehicle use, utility-scale stationary applications, and backup power. LFP batteries are cobalt-free. As of September 2022, LFP type battery market share for EVs reached 31%, and of that, 68% was from Tesla and Chinese EV maker BYD production alone. Chinese manufacturers currently hold a near monopoly of LFP battery type production. With patents having started to expire in 2022 and the increased demand for cheaper EV batteries, LFP type production is expected to rise further and surpass lithium nickel manganese cobalt oxides (NMC) type batteries in 2028.

<span class="mw-page-title-main">Nanobatteries</span> Type of battery

Nanobatteries are fabricated batteries employing technology at the nanoscale, particles that measure less than 100 nanometers or 10−7 meters. These batteries may be nano in size or may use nanotechnology in a macro scale battery. Nanoscale batteries can be combined to function as a macrobattery such as within a nanopore battery.

<span class="mw-page-title-main">Lithium iron phosphate</span> Chemical compound

Lithium iron phosphate or lithium ferro-phosphate (LFP) is an inorganic compound with the formula LiFePO
4
. It is a gray, red-grey, brown or black solid that is insoluble in water. The material has attracted attention as a component of lithium iron phosphate batteries, a type of Li-ion battery. This battery chemistry is targeted for use in power tools, electric vehicles, solar energy installations and more recently large grid-scale energy storage.

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The lithium–air battery (Li–air) is a metal–air electrochemical cell or battery chemistry that uses oxidation of lithium at the anode and reduction of oxygen at the cathode to induce a current flow.

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References

  1. "Analyse de la cinétique de cémentation du cuivre par le zinc en milieu sulfate". theses.fr.
  2. "Kalev Pugi Award, 2022 Recipient - Professor Karim Zaghib". Society of Chemical Industry. Retrieved 22 March 2023.
  3. Benameur, Lilia (15 March 2022). "Rencontre avec Karim Zaghib, le maître algérien de la batterie". Tout sur l'Algérie. Retrieved 22 March 2023.
  4. 1 2 3 "Keynote and Invited Speakers". International Meeting on Lithium Batteries. Retrieved 22 March 2023.
  5. "About us - A global leader in battery materials". Center of Excellence in Transportation Electrification and Energy Storage. Retrieved 22 March 2023.
  6. "Establishment of Esstalion Technologies, Inc., a joint venture between Sony and Hydro-Québec". Sony Corporation. 3 June 2014. Retrieved 22 March 2023.
  7. "Dr. Karim Zaghib Appointed as a Strategic Advisor at Investissement Québec". Investissement Québec. Retrieved 22 March 2023.
  8. Nishihata, Junji (16 September 2020). "World-leading battery expert appointed Professor of Practice in Department of Mining & Materials Engineering". McGill Reporter. Retrieved 22 March 2023.
  9. Bokser, Howard (21 June 2022). "Concordia celebrates its award-winning faculty". Concordia University. Retrieved 22 March 2023.
  10. Zaghib, K.; Poignet, J.-C. (1998). "Optimum conditions for deposition of Al-Mn alloys on a substrate of soft steel in molten salt : Application as negative electrode for Li-ion batteries". Proceedings of the Electrochemical Society. 98 (15): 423-442.
  11. Zaghib, K.; Chainet, E.; Nguyen, B. (March 1990). "Potentialities of "electrolysis aided cementation": Cu/Zn/So2−4 system". Electrochimica Acta. 35 (3): 657-663. doi:10.1016/0013-4686(90)87057-9.
  12. 1 2 Berkeley Energy Storage and Conversion for Transportation and Renewables. "Dr. Karim Zaghib". Lawrence Berkeley National Laboratory. Retrieved 23 March 2023.
  13. Zaghib, K.; Nadeau, G.; Kinoshita, K. (5 February 2000). "Effect of Graphite Particle Size on Irreversible Capacity Loss". Journal of the Electrochemical Society. 147 (6): 2110-2115. doi:10.1149/1.1393493.
  14. CA 2428090C,Zaghib, K.; Brochu, F.& Guerfi, A.et al.,"Li4Ti5O12, Li(4-.alpha.)z.alpha.Ti5O12, or Li4z.beta.Ti(5-.beta.)O12 particles, methods for obtaining same and use as electrochemical generators",published 2002/06/13, assigned to Hydro-Québec
  15. US 20150132660A1,Ravet, N.; Simoneau, M.& Armand, M.et al.,"Electrode materials with high surface conductivity",published 2015/05/14, assigned to Hydro-Québec
  16. Zaghib, K.; Charest, P.; Guerfi, K.; Shim, J.; Perrier, M.; Striebel, K. (6 May 2004). "Safe Li-ion polymer batteries for HEV applications". Journal of Power Sources. 134 (1): 124-129. doi:10.1016/j.jpowsour.2004.02.020.
  17. Zaghib, K.; Trudeau, M.L.; Reddy, M.V.; Mauger, A.; Julien, C.; Armand, M. (31 May 2022). "(Invited) John B. Goodenough's Centenarian : Success Story of LiFePO4 (LFP) As Cathode Material for Rechargeable Lithium Batteries". ECS Meeting Abstracts. 2022 (1): 356. doi:10.1149/MA2022-012356mtgabs. S2CID   250572764.
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