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Other names LiBOB | |
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3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.104.534 |
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PubChem CID | |
CompTox Dashboard (EPA) | |
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Properties | |
C4BLiO8 | |
Molar mass | 193.79 g·mol−1 |
Appearance | white solid |
Density | 2.021 g/cm3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Lithium bis(oxalate)borate is the inorganic compound with the formula LiB(C2O4)2. A white solid, it is used as an electrolyte in some lithium batteries. [1] It is one of several borate oxalates.
According to X-ray crystallography, solid LiBOB consists of tetrahedral B(C2O4)−2 anions linked by Li+ cations. [2]
A lithium-ion or Li-ion battery is a type of rechargeable battery that uses the reversible intercalation of Li+ ions into electronically conducting solids to store energy. In comparison with other commercial rechargeable batteries, Li-ion batteries are characterized by higher specific energy, higher energy density, higher energy efficiency, a longer cycle life, and a longer calendar life. Also noteworthy is a dramatic improvement in lithium-ion battery properties after their market introduction in 1991: over the following 30 years, their volumetric energy density increased threefold while their cost dropped tenfold. In late 2024 global demand passed 1 Terawatt-hour per year, while production capacity was more than twice that.
A lithium polymer battery, or more correctly, lithium-ion polymer battery, is a rechargeable battery of lithium-ion technology using a polymer electrolyte instead of a liquid electrolyte. Highly conductive semisolid (gel) polymers form this electrolyte. These batteries provide higher specific energy than other lithium battery types. They are used in applications where weight is critical, such as mobile devices, radio-controlled aircraft, and some electric vehicles.
John Bannister Goodenough was an American materials scientist, a solid-state physicist, and a Nobel laureate in chemistry. From 1986 he was a professor of Materials Science, Electrical Engineering and Mechanical Engineering, at the University of Texas at Austin. He is credited with identifying the Goodenough–Kanamori rules of the sign of the magnetic superexchange in materials, with developing materials for computer random-access memory and with inventing cathode materials for lithium-ion batteries.
Sir Michael Stanley Whittingham is a British-American chemist. He is a professor of chemistry and director of both the Institute for Materials Research and the Materials Science and Engineering program at Binghamton University, State University of New York. He also serves as director of the Northeastern Center for Chemical Energy Storage (NECCES) of the U.S. Department of Energy at Binghamton. He was awarded the Nobel Prize in Chemistry in 2019 alongside Akira Yoshino and John B. Goodenough.
Lithium cobalt oxide, sometimes called lithium cobaltate or lithium cobaltite, is a chemical compound with formula LiCoO
2. The cobalt atoms are formally in the +3 oxidation state, hence the IUPAC name lithium cobalt(III) oxide.
The lithium–air battery (Li–air) is a metal–air electrochemical cell or battery chemistry that uses oxidation of lithium at the anode and reduction of oxygen at the cathode to induce a current flow.
Ferrous oxalate (iron(II) oxalate) refers to inorganic compounds with the formula FeC2O4(H2O)x where x is 0 or 2. These are orange compounds. Characteristic of metal oxalate complexes, these compounds tend to be polymeric, hence their low solubility in water.
Cobalt(II) oxalate is the inorganic compound with the formula of CoC2O4. Like other simple inorganic oxalates, it is a coordination polymer. The oxalate ligands bridge of Co(OH2)2 centres. Each cobalt adopts octahedral coordination geometry.
Ferric oxalate, also known as iron(III) oxalate, refers to inorganic compounds with the formula Fe2(C2O4)3(H2O)x but could also refer to salts of [Fe(C2O4)3]3-. Fe2(C2O4)3(H2O)x are coordination polymers with varying degrees of hydration. The coordination complex with the formula [Fe(C2O4)3]3- forms a variety of salts, a well-known example being potassium ferrioxalate. This article emphasizes the coordination polymers.
Titanium disulfide is an inorganic compound with the formula TiS2. A golden yellow solid with high electrical conductivity, it belongs to a group of compounds called transition metal dichalcogenides, which consist of the stoichiometry ME2. TiS2 has been employed as a cathode material in rechargeable batteries.
Research in lithium-ion batteries has produced many proposed refinements of lithium-ion batteries. Areas of research interest have focused on improving energy density, safety, rate capability, cycle durability, flexibility, and reducing cost.
Caesium oxalate, or dicesium oxalate, or cesium oxalate is a chemical compound with the chemical formula Cs2C2O4. It is a caesium salt of oxalic acid. It consists of caesium cations Cs+ and oxalate anions C2O2−4.
The borate oxalates are chemical compounds containing borate and oxalate anions. Where the oxalate group is bound to the borate via oxygen, a more condensed anion is formed that balances less cations. These can be termed boro-oxalates, bis(oxalato)borates, or oxalatoborates or oxalate borates. The oxalatoborates are heterocyclic compounds with a ring containing -O-B-O-. Bis(oxalato)borates are spiro compounds with rings joined at the boron atom.
Copper(II) oxalate are inorganic compounds with the chemical formula CuC2O4(H2O)x. The value of x can be 0, 0.44, and 1. Two of these species are found as secondary minerals, whewellite (monohydrate) and moolooite. The anhydrous compound has been characterized by X-ray crystallography. Many transition metal oxalate complexes are known.
Transition metal oxalate complexes are coordination complexes with oxalate (C2O42−) ligands. Some are useful commercially, but the topic has attracted regular scholarly scrutiny. Oxalate (C2O42-) is a kind of dicarboxylate ligand. As a small, symmetrical dinegative ion, oxalate commonly forms five-membered MO2C2 chelate rings. Mixed ligand complexes are known, e.g., [Co(C2O4)(NH3)4]κ+.
The oxalate phosphates are chemical compounds containing oxalate and phosphate anions. They are also called oxalatophosphates or phosphate oxalates. Some oxalate-phosphate minerals found in bat guano deposits are known. Oxalate phosphates can form metal organic framework compounds.
Tin(II) oxalate is an inorganic compound, a salt of tin and oxalic acid with the chemical formula SnC
2O
4. The compound looks like colorless crystals, does not dissolve in water, and forms crystalline hydrates.
The oxalate phosphites are chemical compounds containing oxalate and phosphite anions. They are also called oxalatophosphites or phosphite oxalates. Oxalate phosphates can form metal organic framework compounds.
This is a history of the lithium-ion battery.
Oxalate sulfates are mixed anion compounds containing oxalate and sulfate. They are mostly transparent, and any colour comes from the cations.