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C41100 Lubaloy is a wrought copper alloy that is composed mainly of copper and zinc. Lubaloy possesses many favorable characteristics making it, and other types of brass, a popular choice in manufacturing. It is a source material in many processes including the creation of electrical components and bullet-making. There are both positive and negative health effects that are associated with the use of this material.
Lubaloy is made from combining 91% copper, 8.5% zinc, and 0.5% tin. Proportional variances are utilized for application specific demands of each desired material component. The range of compositions can vary from around 81 to 95% copper, 3 to 18% zinc, and 0.5 to 2% tin. A common variation of the Lubaloy alloy type in Lubaloy X 425, with a composition of 88% copper, 10% zinc, and 2% tin.
Documented use of brass dates back to early Romans, and is referenced in the Bible.
In 1922, the Western Cartridge Company introduced a copper-washed bullet jacketing called Lubaloy which stands for lubricating alloy. Lubaloy replaced standard bullet jacketing which had been gilding metal, cupro-nickel coated steel or solid cupro-nickel. The original jacketing was found to be detrimental to magnum cartridge firearm performance over time. Lumps of the hot jacketing were deposited near the end of the barrel during firing, eventually creating a hazard or destroying the barrel. The problem was solved in the UK, where Kynoch developed a new kind of brass similar to gilding metal with a little tin alloyed which became a breakthrough solution to this persistent dilemma, branded Nobeloy due to merge of the company into the Nobel Industries conglomerate. [1] It was composed of 90% copper, 8% zinc, and 2% tin and was licensed to the WCC under the name of Lubaloy or Lubaloy-Palma.
Lubaloy can be fabricated using blanking, forming, and drawing processes. The early versions of brass were created by co-smelting mixed ores. The process was called cementation, which involved heating zinc and copper in a closed crucible with charcoal. This dates back to the 7th century BC in Greece. Sometimes the zinc ore was pre-heated to produce metallic zinc which condensed from the hot vapour. This was called speltering. It produced a superior product where the purity can be controlled and modified. This process was noted from around 1000 AD in India. Today full-scale production is more stream-lined; modern smelters and electrolytic refineries are used.
This alloy is widely used because it is soft and more malleable than copper or zinc alone. It offers great cold workability and hot formability. The non-ferromagnetic property of brass allows it to be easily separated from other metals. It is tarnish-resistant, and has low friction and spark-less qualities. It is dull yellow and has an appearance similar to that of gold. Brass is a substitutional alloy used for decorations and jewellery. Brass is an excellent electrical and thermal conductor because copper has a simple FCC crystal structure. Silver is the best electrical conductor. Copper can conduct 97% of the amount of electricity that silver can conduct.
Common uses include manufacture of rod, wire, sheet, and foil. Lubaloy is a component in such objects as trumpets and cymbals, doorknobs and locks, ammunition, valves, gears, and bearings. It is a common alloy used to make coins. This alloy plays an important role in manufacturing tools for use around explosive gases, and in cryogenics. It is used as a test control metal for protective coatings research. Other items include plates, tubes, pipes, forgings, castings, bushings, washers, terminals, connectors, flexible metal hose, and conductors.
Health concerns surrounding brass stem from lead contamination. Lead is sometimes added to enhance the machinability of brass. It is often present in concentrations around 2%. Thirteen key manufacturers were sued by the California state attorney general in October 1999. Lab tests revealed the average brass key contained more than the acceptable limit of lead. They were required to reduce the lead content to 1.5% after April 2001. By January 1, 2010, the California law states that brass containing less than 0.25% lead must be used for each component that comes into contact with the wetted surface of pipes, plumbing fittings and fixtures. On the other hand, the copper in brass does create a natural germicidal or oligodynamic effect. Brass doorknobs will virtually disinfect themselves within eight hours.
An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductility, opacity, and luster, but may have properties that differ from those of the pure metals, such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties to the constituent metal elements such as corrosion resistance or mechanical strength.
Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally 66% copper and 34% zinc. In use since prehistoric times, it is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure.
A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile and malleable. These properties are the result of the metallic bond between the atoms or molecules of the metal.
Solder is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable for use as solder should have a lower melting point than the pieces to be joined. The solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder used in making electrical connections also needs to have favorable electrical characteristics.
Gilding metal is a form of brass with a much higher copper content than zinc content. Exact figures range from 95% copper and 5% zinc to “8 parts copper to 1 of zinc” in British Army Dress Regulations.
Beryllium copper (BeCu), also known as copper beryllium (CuBe), beryllium bronze, and spring copper, is a copper alloy with 0.5–3% beryllium. Copper beryllium alloys are often used because of their high strength and good conductivity of both heat and electricity. It is used for its ductility, weldability in metalworking, and machining properties. It has many specialized applications in tools for hazardous environments, musical instruments, precision measurement devices, bullets, and some uses in the field of aerospace. Beryllium copper and other beryllium alloys are harmful carcinogens that present a toxic inhalation hazard during manufacturing.
Cupronickel or copper–nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other elements added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent.
Brazing is a metal-joining process in which two or more metal items are joined by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.
In metallurgy, a flux is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining.
Die casting is a metal casting process that is characterized by forcing molten metal under high pressure into a mold cavity. The mold cavity is created using two hardened tool steel dies which have been machined into shape and work similarly to an injection mold during the process. Most die castings are made from non-ferrous metals, specifically zinc, copper, aluminium, magnesium, lead, pewter, and tin-based alloys. Depending on the type of metal being cast, a hot- or cold-chamber machine is used.
Phosphor bronze is a member of the family of copper alloys. It is composed of copper that is alloyed with 0.5–11% of tin and 0.01–0.35% phosphorus, and may contain other elements to confer specific properties. The tin increases the corrosion resistance and strength of the alloy, while the phosphorus increases its wear resistance and stiffness.
Tombac, or tombak, is a brass alloy with high copper content and 5–20% zinc content. Tin, lead or arsenic may be added for colouration. It is a cheap malleable alloy mainly used for medals, ornament, decoration and some munitions. In older use, the term may apply to brass alloy with a zinc content as high as 28–35%.
Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.
2024 aluminium alloy is an aluminium alloy, with copper as the primary alloying element. It is used in applications requiring high strength-to-weight ratio, as well as good fatigue resistance. It is weldable only through friction welding, and has average machinability. Due to poor corrosion resistance, it is often clad with aluminium or Al-1Zn for protection, although this may reduce the fatigue strength. In older systems of terminology, 2XXX series alloys were known as duralumin, and this alloy was named 24ST.
Bismuth bronze or bismuth brass is a copper alloy which typically contains 1-3% bismuth by weight, although some alloys contain over 6% Bi. This bronze alloy is very corrosion-resistant, a property which makes it suitable for use in environments such as the ocean. Bismuth bronzes and brasses are more malleable, thermally conductive, and polish better than regular brasses. The most common industrial application of these metals is as bearings, however the material has been in use since the late nineteenth century as kitchenware and mirrors. Bismuth bronze was also found in ceremonial Inca knives at Machu Picchu. Recently, pressure for the substitution of hazardous metals has increased and with it bismuth bronze is being marketed as a green alternative to leaded bronze bearings and bushings.
Soldering is a process of joining two metal surfaces together using a filler metal called solder. The soldering process involves heating the surfaces to be joined and melting the solder, which is then allowed to cool and solidify, creating a strong and durable joint.
Materials for use in vacuum are materials that show very low rates of outgassing in vacuum and, where applicable, are tolerant to bake-out temperatures. The requirements grow increasingly stringent with the desired degree of vacuum to be achieved in the vacuum chamber. The materials can produce gas by several mechanisms. Molecules of gases and water can be adsorbed on the material surface. Materials may sublimate in vacuum. Or the gases can be released from porous materials or from cracks and crevices. Traces of lubricants, residues from machining, can be present on the surfaces. A specific risk is outgassing of solvents absorbed in plastics after cleaning.
Copper has been used in electrical wiring since the invention of the electromagnet and the telegraph in the 1820s. The invention of the telephone in 1876 created further demand for copper wire as an electrical conductor.
Copper has earned a respected place in the related fields of architecture, building construction, and interior design. From cathedrals to castles and from homes to offices, copper is used for a variety of architectural elements, including roofs, flashings, gutters, downspouts, domes, spires, vaults, wall cladding, and building expansion joints.
CuproBraze is a copper-alloy heat exchanger technology for high-temperature and pressure environments such as those in modern diesel engines. The technology, developed by the International Copper Association (ICA), is licensed for free to heat exchanger manufacturers around the world.