List of copper alloys

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Example of a copper alloy object: a Neo-Sumerian "Foundation Nail" of Gudea, circa 2100 BC, made in the lost-wax cast method, overall: 17.5 x 4.5 x 7.3 cm, probably from modern-day Iraq, now in the Cleveland Museum of Art (Cleveland, Ohio, USA) Clevelandart 1990.31.jpg
Example of a copper alloy object: a Neo-Sumerian "Foundation Nail" of Gudea, circa 2100 BC, made in the lost-wax cast method, overall: 17.5 x 4.5 x 7.3 cm, probably from modern-day Iraq, now in the Cleveland Museum of Art (Cleveland, Ohio, USA)

Copper alloys are metal alloys that have copper as their principal component. They have high resistance against corrosion. Of the large number of different types, the best known traditional types are bronze, where tin is a significant addition, and brass, using zinc instead. Both of these are imprecise terms. Latten is a further term, mostly used for coins with a very high copper content. Today the term copper alloy tends to be substituted for all of these, especially by museums. [1]

Contents

Copper deposits are abundant in most parts of the world (globally 70 parts per million), and it has therefore always been a relatively cheap metal. By contrast, tin is relatively rare (2 parts per million), and in Europe and the Mediterranean region, and even in prehistoric times had to be traded considerable distances, and was expensive, sometimes virtually unobtainable. Zinc even commoner at 75 parts per million, but is harder to extract from its ores. Bronze with the ideal percentage of tin was therefore expensive and the proportion of tin was often reduced to save cost. The discovery and exploitation of the Bolivian tin belt in the 19th century made tin far cheaper, although forecasts for future supplies are less positive.

There are as many as 400 different copper and copper alloy compositions loosely grouped into the categories: copper, high copper alloy, brasses, bronzes, cupronickel, coppernickelzinc (nickel silver), leaded copper, and special alloys.

Composition

The similarity in external appearance of the various alloys, along with the different combinations of elements used when making each alloy, can lead to confusion when categorizing the different compositions. The following table lists the principal alloying element for four of the more common types used in modern industry, along with the name for each type. Historical types, such as those that characterize the Bronze Age, are vaguer as the mixtures were generally variable.

Classification of copper and its alloys
FamilyPrincipal alloying element UNS numbers
Copper alloys, brassZinc (Zn)C1xxxxC4xxxx,C66400C69800
Phosphor bronze Tin (Sn)C5xxxx
Aluminium bronzes Aluminium (Al)C60600C64200
Silicon bronzesSilicon (Si)C64700C66100
Cupronickel, nickel silvers Nickel (Ni)C7xxxx
Mechanical properties of common copper alloys [2]
NameNominal composition (percentages)Form and conditionYield strength (0.2% offset, ksi)Tensile strength (ksi)Elongation in 2 inches (percent)Hardness (Brinell scale)Comments
Copper (ASTM B1, B2, B3, B152, B124, R133)Cu 99.9Annealed10324542Electrical equipment, roofing, screens
Cold-drawn40451590
Cold-rolled40465100
Gilding metal (ASTM B36)Cu 95.0, Zn 5.0Cold-rolled50565114Coins, bullet jackets
Cartridge brass (ASTM B14, B19, B36, B134, B135)Cu 70.0, Zn 30.0Cold-rolled63768155Good for cold-working; radiators, hardware, electrical, drawn cartridge cases.
Phosphor bronze (ASTM B103, B139, B159)Cu 89.75, Sn 10.0, P 0.25Spring temper1224241High fatigue-strength and spring qualities
Yellow or High brass (ASTM B36, B134, B135)Cu 65.0, Zn 35.0Annealed18486055Good corrosion resistance
Cold-drawn557015115
Cold-rolled (HT)607410180
Manganese bronze (ASTM 138)Cu 58.5, Zn 39.2, Fe 1.0, Sn 1.0, Mn 0.3Annealed30603095 Forgings
Cold-drawn508020180
Naval brass (ASTM B21)Cu 60.0, Zn 39.25, Sn 0.75Annealed22564090Resistance to salt corrosion
Cold-drawn406535150
Muntz metal (ASTM B111)Cu 60.0, Zn 40.0Annealed20544580 Condensor tubes
Aluminium bronze (ASTM B169 alloy A, B124, B150)Cu 92.0, Al 8.0Annealed25706080
Hard651057210
Beryllium copper (ASTM B194, B196, B197)Cu 97.75, Be 2.0, Co or Ni 0.25Annealed, solution-treated327045B60 (Rockwell)Electrical, valves, pumps, oilfield tools, aerospace landing gears, robotic welding, mold making [3]
Cold-rolled1041105B81 (Rockwell)
Free-cutting brassCu 62.0, Zn 35.5, Pb 2.5Cold-drawn447018B80 (Rockwell)Screws, nuts, gears, keys
Nickel silver (ASTM B122)Cu 65.0, Zn 17.0, Ni 18.0Annealed25584070Hardware
Cold-rolled70854170
Nickel silver (ASTM B149)Cu 76.5, Ni 12.5, Pb 9.0, Sn 2.0Cast18351555Easy to machine; ornaments, plumbing [4]
Cupronickel (ASTM B111, B171)Cu 88.35, Ni 10.0, Fe 1.25, Mn 0.4Annealed224445Condensor, salt-water pipes
Cold-drawn tube576015
CupronickelCu 70.0, Ni 30.0WroughtHeat-exchange equipment, valves
Ounce metal [5] Copper alloy C83600 (also known as "Red brass" or "composition metal") (ASTM B62)Cu 85.0, Zn 5.0, Pb 5.0, Sn 5.0Cast17372560
Gunmetal (known as "red brass" in US)Varies Cu 80-90%, Zn <5%, Sn ~10%, +other elements@ <1%
Mechanical properties of Copper Development Association (CDA) copper alloys [6]
FamilyCDATensile strength [ksi]Yield strength [ksi]Elongation (typ.) [%]Hardness
[Brinell 10 mm-500 kg]
Machinability [YB = 100]
Min.Typ.Min.Typ.
Red brass 8333210353535
836303714173050–6584
838293512162550–6090
Semi-red brass 844293413152650–6090
848253612143050–6090
Manganese bronze 8629095454820170–19530
8631101196083182258
865657125283013026
Tin bronze 903404518213060–7530
90540451822257530
90735441822208020
Leaded tin bronze 922344016203060–7242
923364016202560–7542
926404418203065–8040
927354221207745
High-leaded tin bronze 932303514182060–7070
9342532162055–6570
935253212163055–6570
936333016211579-8380
937253512182055–7080
938253014161850–6080
9432127131042–5580
Aluminium bronze 9526580252735110–14050
953657525272514055
9547585303518140–17060
95590100404412180–20050
9588595353825150-17050
Silicon bronze 878808330372911540
Brinell scale with 3000 kg load
Comparison of copper alloy standards [6]
FamilyCDA ASTM SAE SAE supersededFederalMilitary
Red brass833
836B145-83683640QQ-C-390 (B5)C-2229 Gr2
838B145-838838QQ-C-390 (B4)
Semi-red brass844B145-844QQ-C-390 (B2)
848B145-848QQ-C-390 (B1)
Manganese bronze862B147-862862430AQQ-C-390 (C4)C-2229 Gr9
863B147-863863430BQQ-C-390 (C7)C-2229 Gr8
865B147-86586543QQ-C-390 (C3)C-2229 Gr7
Tin bronze903B143-903903620QQ-C-390 (D5)C-2229 Gr1
905B143-90590562QQ-C-390 (D6)
90790765
Leaded tin bronze922B143-922922622QQ-C-390 (D4)B-16541
923B143-923923621QQ-C-390 (D3)C-15345 Gr10
926926
92792763
High-leaded tin bronze932B144-932932660QQ-C-390 (E7)C-15345 Gr12
934QQ-C-390 (E8)C-22229 Gr3
935B144-93593566QQ-C-390 (E9)
937B144-93793764QQ-C-390 (E10)
938B144-93893867QQ-C-390 (E6)
943B144-943943QQ-C-390 (E1)
Aluminium bronze952B148-95295268AQQ-C-390 (G6)C-22229 Gr5
953B148-95395368BQQ-C-390 (G7)
954B148-954954QQ-C-390 (G5)C-15345 Gr13
955B148-955955QQ-C-390 (G3)C-22229 Gr8
958QQ-C-390 (G8)
Silicon bronze878B30878

The following table outlines the chemical composition of various grades of copper alloys.

Chemical composition of copper alloys [6] [7]
FamilyCDAAMSUNSCu [%]Sn [%]Pb [%]Zn [%]Ni [%]Fe [%]Al [%]Other [%]
Red brass833C83300931.51.54
C83400 [8] 9010
8364855BC8360085555
838C8380083467
Semi-red brass844C8440081379
845C84500783712
848C84800763615
Manganese bronzeC86100 [9] 670.52135Mn 4
862C86200642634Mn 3
8634862BC86300632536Mn 3
8654860AC86500580.539.511Mn 0.25
Tin bronze903C903008884
9054845DC9050088100.3 max2
907C9070089110.5 max0.5 max
Leaded tin bronze922C922008861.54.5
923C923008781 max4
9264846AC92600871012
927C92700881020.7 max
High-leaded tin bronze932C9320083773
934C9340084880.7 max
935C93500855910.5 max
9374842AC937008010100.7 max
938C93800787150.75 max
9434840AC94300705250.7 max
Aluminium bronze952C952008839
953C9520089110
9544870B
4872B
C9540085411
C95410 [10] 85411Ni 2
955C95500814411
C95600 [11] 917Si 2
C95700 [12] 75238Mn 12
958C9580081549Mn 1
Silicon bronzeC87200 [13] 89Si 4
C87400 [14] 8314Si 3
C87500 [15] 8214Si 4
C87600 [16] 905.5Si 4.5
878C87800 [17] 8014Si 4
C87900 [18] 6534Si 1
Chemical composition may vary to yield mechanical properties

Brasses

Binary Cu Si phase diagram, the base phase diagram for silicon bronzes Section 23 2D CU-SI.png
Binary Cu Si phase diagram, the base phase diagram for silicon bronzes
Binary Cu Al phase diagram, the base phase diagram for aluminium bronzes, generated using NIMS Open databases https://cpddb.nims.go.jp/cpddb/al-elem/alcu/alcu.htm - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/ Section 1 2D AL-CU.png
Binary Cu Al phase diagram, the base phase diagram for aluminium bronzes, generated using NIMS Open databases https://cpddb.nims.go.jp/cpddb/al-elem/alcu/alcu.htm - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/
Binary Cu Sn phase diagram, the base phase diagram for bronzes, generated using NIMS Open databases https://cpddb.nims.go.jp/cpddb/cu-elem/cusn/cusn.htm - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/ Binary Cu Sn phase diagram, generated using NIMS Open database Cu-Sn and Computherm Pandat https---computherm.com-.png
Binary Cu Sn phase diagram, the base phase diagram for bronzes, generated using NIMS Open databases https://cpddb.nims.go.jp/cpddb/cu-elem/cusn/cusn.htm - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/
Binary Cu Zn phase diagram, the base phase diagram for brasses, generated using NIMS Open database https://cpddb.nims.go.jp/cpddb/cu-elem/cu_index.htm Cu-Zn - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/ Cu Zn phase diagram.png
Binary Cu Zn phase diagram, the base phase diagram for brasses, generated using NIMS Open database https://cpddb.nims.go.jp/cpddb/cu-elem/cu_index.htm  Cu-Zn - DOI https://doi.org/10.48505/nims.3060 and Computherm Pandat https://computherm.com/

A brass is an alloy of copper with zinc. Brasses are usually yellow in colour. The zinc content can vary between few % to about 40%; as long as it is kept under 15%, it does not markedly decrease corrosion resistance of copper.

Brasses can be sensitive to selective leaching corrosion under certain conditions, when zinc is leached from the alloy (dezincification), leaving behind a spongy copper structure.

Bronzes

A bronze is an alloy of copper and other metals, most often tin, but also aluminium and silicon.

Precious metal alloys

Copper is often alloyed with precious metals like gold (Au) and silver (Ag).

NameCu [%]Au [%]Ag [%]Other [%]
Auricupride
Ashtadhatu Fe†, Hg†, Sn†, Zn†
Billon Hg†
Chinese silver 58217.5 Zn, 11.5 Ni,
Corinthian bronze
CuSil 2872
Dymalloy 2080C (type I diamond)
Electrum, Green gold 6-2375-800-150-4 Cd
Grey gold Mn†
Guanín 255618
Hepatizon tracetrace
Niello Pb sulfides†
Panchaloha Fe†, Sn†, Pb†, Zn†,
Rose, red, and pink gold 20-5050-750-5
Spangold 18-19765-6 Al
Shakudō 90-964-10
Shibuichi 40-770-123-60
Tibetan silver Ni†, Sn†
Tumbaga 3-973-97
White gold Ni†, Zn†

† amount unspecified

See also

Related Research Articles

<span class="mw-page-title-main">Alloy</span> Mixture or metallic solid solution composed of two or more elements

An alloy is a mixture of chemical elements of which in most cases at least one is a metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Most alloys are metallic and show good electrical conductivity, ductility, opacity, and luster, and may have properties that differ from those of the pure elements such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties such as corrosion resistance or mechanical strength.

<span class="mw-page-title-main">Brass</span> Alloy of copper and zinc

Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally 66% copper and 34% zinc. In use since prehistoric times, it is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure.

<span class="mw-page-title-main">Bronze</span> Alloy of copper and tin

Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals and sometimes non-metals, such as phosphorus, or metalloids, such as arsenic or silicon. These additions produce a range of alloys that may be harder than copper alone, or have other useful properties, such as strength, ductility, or machinability.

<span class="mw-page-title-main">Cupronickel</span> Alloy of copper containing nickel

Cupronickel or copper–nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other elements added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent.

<span class="mw-page-title-main">Nickel silver</span> Shiny alloy of copper, nickel, and zinc

Nickel silver, maillechort, German silver, argentan, new silver, nickel brass, albata, or alpacca is a copper alloy with nickel, and often zinc. The usual formulation is 60% copper, 20% nickel and 20% zinc. Nickel silver does not contain the element silver. It is named for its silvery appearance, which can make it attractive as a cheaper and more durable substitute. It is also well suited for being plated with silver.

<span class="mw-page-title-main">Brazing</span> Metal-joining technique

Brazing is a metal-joining process in which two or more metal items are joined by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.

<span class="mw-page-title-main">Phosphor bronze</span> Bronze where the oxygen is removed with phosphorus

Phosphor bronze is a member of the family of copper alloys. It is composed of copper that is alloyed with 0.5–11% of tin and 0.01–0.35% phosphorus, and may contain other elements to confer specific properties. The tin increases the corrosion resistance and strength of the alloy, while the phosphorus increases its wear resistance and stiffness.

<span class="mw-page-title-main">Tombac</span> Copper-zinc alloy

Tombac, or tombak, is a brass alloy with high copper content and 5–20% zinc content. Tin, lead or arsenic may be added for colouration. It is a cheap malleable alloy mainly used for medals, ornament, decoration and some munitions. In older use, the term may apply to brass alloy with a zinc content as high as 28–35%.

Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.

<span class="mw-page-title-main">Gunmetal</span> Alloy of copper, tin, and zinc

Gun metal, also known as red brass in the United States, is a type of bronze – an alloy of copper, tin, and zinc. Proportions vary but 88% copper, 8–10% tin, and 2–4% zinc is an approximation. Originally used chiefly for making guns, it has largely been replaced by steel for that purpose. Gunmetal casts and machines well, and is resistant to corrosion from steam and salt water. It is used to make steam and hydraulic castings, valves, gears, statues, and various small objects, such as buttons. It has a tensile strength of 221 megapascals (32,100 psi) to 310 megapascals (45,000 psi), a specific gravity of 8.7, a Brinell hardness of 65 to 74, and a melting point of around 1,000 degrees Celsius.

<span class="mw-page-title-main">Aluminium bronze</span> Alloy of copper and aluminum

Aluminium bronze is a type of bronze in which aluminium is the main alloying metal added to copper, in contrast to standard bronze or brass. A variety of aluminium bronzes of differing compositions have found industrial use, with most ranging from 5% to 11% aluminium by weight, the remaining mass being copper; other alloying agents such as iron, nickel, manganese, and silicon are also sometimes added to aluminium bronzes.

<span class="mw-page-title-main">Architectural metals</span>

Metals used for architectural purposes include lead, for water pipes, roofing, and windows; tin, formed into tinplate; zinc, copper and aluminium, in a range of applications including roofing and decoration; and iron, which has structural and other uses in the form of cast iron or wrought iron, or made into steel. Metal alloys used in building include bronze ; brass ; monel metal and nickel silver, mainly consisting of nickel and copper; and stainless steel, with important components of nickel and chromium.

<span class="mw-page-title-main">Colored gold</span> Various colors of gold obtained by alloying gold with other elements

Colored gold is the name given to any gold that has been treated using techniques to change its natural color. Pure gold is slightly reddish yellow in color, but colored gold can come in a variety of different colors by alloying it with different elements.

The coinage metals comprise those metallic chemical elements and alloys which have been used to mint coins. Historically, most coinage metals are from the three nonradioactive members of group 11 of the periodic table: copper, silver and gold. Copper is usually augmented with tin or other metals to form bronze. Gold, silver and bronze or copper were the principal coinage metals of the ancient world, the medieval period and into the late modern period when the diversity of coinage metals increased. Coins are often made from more than one metal, either using alloys, coatings (cladding/plating) or bimetallic configurations. While coins are primarily made from metal, some non-metallic materials have also been used.

C41100 Lubaloy is a wrought copper alloy that is composed mainly of copper and zinc. Lubaloy possesses many favorable characteristics making it, and other types of brass, a popular choice in manufacturing. It is a source material in many processes including the creation of electrical components and bullet-making. There are both positive and negative health effects that are associated with the use of this material.

<span class="mw-page-title-main">Copper alloys in aquaculture</span>

Copper alloys are important netting materials in aquaculture. Various other materials including nylon, polyester, polypropylene, polyethylene, plastic-coated welded wire, rubber, patented twine products, and galvanized steel are also used for netting in aquaculture fish enclosures around the world. All of these materials are selected for a variety of reasons, including design feasibility, material strength, cost, and corrosion resistance.

<span class="mw-page-title-main">Materials for use in vacuum</span>

Materials for use in vacuum are materials that show very low rates of outgassing in vacuum and, where applicable, are tolerant to bake-out temperatures. The requirements grow increasingly stringent with the desired degree of vacuum to be achieved in the vacuum chamber. The materials can produce gas by several mechanisms. Molecules of gases and water can be adsorbed on the material surface. Materials may sublimate in vacuum. Or the gases can be released from porous materials or from cracks and crevices. Traces of lubricants, residues from machining, can be present on the surfaces. A specific risk is outgassing of solvents absorbed in plastics after cleaning.

<span class="mw-page-title-main">Copper in architecture</span> Material for building and design

Copper has earned a respected place in the related fields of architecture, building construction, and interior design. From cathedrals to castles and from homes to offices, copper is used for a variety of architectural elements, including roofs, flashings, gutters, downspouts, domes, spires, vaults, wall cladding, and building expansion joints.

Aluminium brass is a technically rather uncommon term for high-strength and partly seawater-resistant copper-zinc cast and wrought alloys with 55–66% copper, up to 7% aluminium, up to 4.5% iron, and 5% manganese. Aluminium bronze is technically correct as bronze, a zinc-free copper-tin casting alloy with aluminium content.

References

  1. British Museum, "Scope Note" for "copper alloy"
  2. Lyons, William C. and Plisga, Gary J. (eds.) Standard Handbook of Petroleum & Natural Gas Engineering, Elsevier, 2006
  3. National Bronze & Metals | Beryllium Copper
  4. Lewis Brass & Company | Copper Alloy Data Archived 2021-05-12 at the Wayback Machine
  5. Cast copper alloy C83600 (Ounce Metal) substech.com
  6. 1 2 3 Industrial Investment Castings - Franklin Bronze , retrieved 2009-09-07.
  7. Brass and Bronze Alloys, archived from the original on 2009-08-25, retrieved 2009-09-08.
  8. UNS C83400 , retrieved 2009-09-08.
  9. UNS C86100 , retrieved 2009-09-08.
  10. UNS C95410 , retrieved 2009-09-08.
  11. UNS C95600 , retrieved 2009-09-08.
  12. UNS C95700 , retrieved 2009-09-08.
  13. UNS C87200 , retrieved 2009-09-08.
  14. UNS C87400 , retrieved 2009-09-08.
  15. UNS C87500 , retrieved 2009-09-08.
  16. UNS C87600 , retrieved 2009-09-08.
  17. UNS C87800 , retrieved 2009-09-08.
  18. UNS C87900 , retrieved 2009-09-08.
  19. "Doehler-Jarvis Company Collection, MSS-202".
  20. Woldman’s Engineering Alloys, 9th Edition 1936, American Society for Metals, ISBN   978-0-87170-691-1

Bibliography