Aluminium bronze

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The large plates in the background are made of aluminium bronze Fauteuil et decors de porte de Peter Behrens (Musee de la colonie d'artistes, Darmstadt) (8729765938).jpg
The large plates in the background are made of aluminium bronze

Aluminium bronze is a type of bronze in which aluminium is the main alloying metal added to copper, in contrast to standard bronze (copper and tin) or brass (copper and zinc). A variety of aluminium bronzes of differing compositions have found industrial use, with most ranging from 5% to 11% aluminium by weight, the remaining mass being copper; other alloying agents such as iron, nickel, manganese, and silicon are also sometimes added to aluminium bronzes.

Contents

Compositions

5 franc coins made of aluminium bronze from 1940 5 francs francais 1940.jpg
5 franc coins made of aluminium bronze from 1940
Aluminium bronze with 20% aluminium at 500x magnification AlubronzeCuAl20v500.png
Aluminium bronze with 20% aluminium at 500× magnification

The following table lists the most common standard aluminium bronze wrought alloy compositions, by ISO 428 designations. The percentages show the proportional composition of the alloy by weight. Copper is the remainder by weight and is not listed:

Alloy Aluminium Iron Nickel Manganese Zinc Arsenic
CuAl54.0–6.5%0.5% max.0.8% max.0.5% max.0.5% max.0.4% max.
CuAl87.0–9.0%0.5% max.0.8% max.0.5% max.0.5% max.
CuAl8Fe36.5–8.5%1.5–3.5%1.0% max.0.8% max.0.5% max.
CuAl9Mn28.0–10.0%1.5% max.0.8% max.1.5–3.0%0.5% max.
CuAl10Fe38.5–11.0%2.0–4.0%1.0% max.2.0% max.0.5% max.
CuAl10Fe5Ni58.5–11.5%2.0–6.0%4.0–6.0%2.0% max.0.5% max.

Material properties

Aluminium bronzes are most valued for their higher strength and corrosion resistance as compared to other bronze alloys. These alloys are tarnish-resistant and show low rates of corrosion in atmospheric conditions, low oxidation rates at high temperatures, and low reactivity with sulfurous compounds and other exhaust products of combustion. They are also resistant to corrosion in sea water. Aluminium bronzes' resistance to corrosion results from the aluminium in the alloys, which reacts with atmospheric oxygen to form a thin, tough surface layer of alumina (aluminium oxide) which acts as a barrier to corrosion of the copper-rich alloy. The addition of tin can improve corrosion resistance. [1]

Another notable property of aluminium bronzes are their biostatic effects. The copper component of the alloy prevents colonization by marine organisms including algae, lichens, barnacles, and mussels, and therefore can be preferable to stainless steel or other non-cupric alloys in applications where such colonization would be unwanted.

Aluminium bronzes tend to have a golden color.

Applications

Aluminium bronzes are most commonly used in applications where their resistance to corrosion makes them preferable to other engineering materials. These applications include plain bearings and landing gear components on aircraft, guitar strings, valve components, engine components (especially for seagoing ships), underwater fastenings in naval architecture, and ship propellers. [2] Aluminium bronze is also used to fulfil the ATEX directive for Zones 1, 2, 21, and 22. The attractive gold-toned coloration of aluminium bronzes has also led to their use in jewellery.

Aluminium bronzes are in the highest demand from the following industries and areas:

Aluminium bronze can be welded using the MIG welding technique with an aluminium bronze core and pure argon gas.

Aluminium bronze is used to replace gold for the casting of dental crowns. The alloys used are chemically inert and have the appearance of gold.

Italy pioneered the use for coinage of an aluminium-bronze alloy called bronzital (literally "Italian bronze") in its 5- and 10-centesimi from 1939. Its alloy was finalized in 1967 to 92% copper, 6% aluminium, and 2% nickel, [3] and was since used in the 20, 200 and 500 Italian Lira coins until 2001. Bronzital has since been used for the Australian and New Zealand 1- and 2-dollar coins, the pre-2009 Mexican 20- and 50-centavo coins, the inner cores of the bi-metallic Mexican 1-, 2- and 5-peso coins, the pre-2017 Philippine 10-peso coin, the Canadian 2 dollar coin (a.k.a. the 'toonie'), and the outer rings of the Mexican 10-, 20-, 50- and 100-peso coins.

Nordic Gold, composed of 89% copper, 5% aluminium, 5% zinc, and 1% tin, is a more recently developed aluminium-bronze alloy for coinage. It was first used for the Swedish 10-kronor coin in 1991, and became widespread after the introduction of Nordic gold 10, 20 and 50-cent Euro coins in 2002.

Related Research Articles

<span class="mw-page-title-main">Brass</span> Alloy of copper and zinc

Brass is an alloy of copper (Cu) and zinc (Zn), in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic, and chemical properties, but copper typically has the larger proportion. In use since prehistoric times, it is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure.

<span class="mw-page-title-main">Metal</span> Type of material

A metal is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typically ductile and malleable. These properties are the result of the metallic bond between the atoms or molecules of the metal.

<span class="mw-page-title-main">Metallurgy</span> Field of science that studies the physical and chemical behavior of metals

Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals; that is, the way in which science is applied to the production of metals, and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist.

<span class="mw-page-title-main">Solder</span> Alloy used to join metal pieces

Solder is a fusible metal alloy used to create a permanent bond between metal workpieces. Solder is melted in order to wet the parts of the joint, where it adheres to and connects the pieces after cooling. Metals or alloys suitable for use as solder should have a lower melting point than the pieces to be joined. The solder should also be resistant to oxidative and corrosive effects that would degrade the joint over time. Solder used in making electrical connections also needs to have favorable electrical characteristics.

Cupronickel or copper-nickel (CuNi) is an alloy of copper with nickel, usually along with small quantities of other elements added for strength, such as iron and manganese. The copper content typically varies from 60 to 90 percent.

<span class="mw-page-title-main">Nordic Gold</span> Copper alloy used in many coins

Nordic Gold is the gold-coloured copper alloy from which many coins are made. The alloy is a type of aluminium brass. It has been used for a number of coins in many currencies, most notably in euro 50, 20, and 10 cents, in the Swedish 5 and 10 kronor coins, as well as the Polish 2 złoty commemorative coins. Its composition is 89% copper, 5% aluminium, 5% zinc, and 1% tin.

<span class="mw-page-title-main">Brazing</span> Metal-joining technique

Brazing is a metal-joining process in which two or more metal items are joined by melting and flowing a filler metal into the joint, with the filler metal having a lower melting point than the adjoining metal.

<span class="mw-page-title-main">Flux (metallurgy)</span> Chemical used in metallurgy for cleaning or purifying molten metal

In metallurgy, a flux is a chemical cleaning agent, flowing agent, or purifying agent. Fluxes may have more than one function at a time. They are used in both extractive metallurgy and metal joining.

Plating is a finishing process in which a metal is deposited on a surface. Plating has been done for hundreds of years; it is also critical for modern technology. Plating is used to decorate objects, for corrosion inhibition, to improve solderability, to harden, to improve wearability, to reduce friction, to improve paint adhesion, to alter conductivity, to improve IR reflectivity, for radiation shielding, and for other purposes. Jewelry typically uses plating to give a silver or gold finish.

<span class="mw-page-title-main">Magnesium alloy</span> Mixture of magnesium with other metals

Magnesium alloys are mixtures of magnesium with other metals, often aluminium, zinc, manganese, silicon, copper, rare earths and zirconium. Magnesium alloys have a hexagonal lattice structure, which affects the fundamental properties of these alloys. Plastic deformation of the hexagonal lattice is more complicated than in cubic latticed metals like aluminium, copper and steel; therefore, magnesium alloys are typically used as cast alloys, but research of wrought alloys has been more extensive since 2003. Cast magnesium alloys are used for many components of modern automobiles and have been used in some high-performance vehicles; die-cast magnesium is also used for camera bodies and components in lenses.

<span class="mw-page-title-main">Architectural metals</span>

Metals used for architectural purposes include lead, for water pipes, roofing, and windows; tin, formed into tinplate; zinc, copper and aluminium, in a range of applications including roofing and decoration; and iron, which has structural and other uses in the form of cast iron or wrought iron, or made into steel. Metal alloys used in building include bronze ; brass ; monel metal and nickel silver, mainly consisting of nickel and copper; and stainless steel, with important components of nickel and chromium.

<span class="mw-page-title-main">Group 11 element</span> Group of elements in the periodic table

Group 11, by modern IUPAC numbering, is a group of chemical elements in the periodic table, consisting of copper (Cu), silver (Ag), gold (Au), and roentgenium (Rg), although no chemical experiments have yet been carried out to confirm that roentgenium behaves like the heavier homologue to gold. Group 11 is also known as the coinage metals, due to their usage in minting coins—while the rise in metal prices mean that silver and gold are no longer used for circulating currency, remaining in use for bullion, copper remains a common metal in coins to date, either in the form of copper clad coinage or as part of the cupronickel alloy. They were most likely the first three elements discovered. Copper, silver, and gold all occur naturally in elemental form.

The coinage metals comprise those metallic chemical elements and alloys which have been used to mint coins. Historically, most coinage metals are from the three nonradioactive members of group 11 of the periodic table: copper, silver and gold. Copper is usually augmented with tin or other metals to form bronze. Gold, silver and bronze or copper were the principal coinage metals of the ancient world, the medieval period and into the late modern period when the diversity of coinage metals increased. While coins are primarily made from metal, some non-metallic materials have also been used.

<span class="mw-page-title-main">Materials for use in vacuum</span>

Materials for use in vacuum are materials that show very low rates of outgassing in vacuum and, where applicable, are tolerant to bake-out temperatures. The requirements grow increasingly stringent with the desired degree of vacuum to be achieved in the vacuum chamber. The materials can produce gas by several mechanisms. Molecules of gases and water can be adsorbed on the material surface. Materials may sublimate in vacuum. Or the gases can be released from porous materials or from cracks and crevices. Traces of lubricants, residues from machining, can be present on the surfaces. A specific risk is outgassing of solvents absorbed in plastics after cleaning.

2195 aluminium alloy is an alloy in the wrought aluminium-copper family. It is one of the Weldalite family of Aluminium–lithium alloys. It is one of the most complex grades in the 2000 series, with at least 91.9% aluminium by weight. 2195 aluminium can be alternately referred to by the UNS designation A92195.

2218 aluminium alloy is an alloy in the wrought aluminium-copper family. It is one of the most complex grades in the 2000 series, with at least 88.4% aluminium by weight. Unlike most other aluminium-copper alloys, 2218 is a high work-ability alloy, with relatively low for 2xxx series alloy yield strength of 255 MPa. Despite being highly alloyed, it have a good corrosion and oxidation resistance due sacrificial anode formed by magnesium inclusions, similar to marine-grade 5xxx series alloys. Although 2218 is wrought alloy, owing to granular structure it can be used in casting and been precisely machined after casting. It is easy to weld, coat, or glue.

Aluminium brass is a technically rather uncommon term for high-strength and partly seawater-resistant copper-zinc cast and wrought alloys with 55–66% copper, up to 7% aluminium, up to 4.5% iron, and 5% manganese. Aluminium bronze is technically correct as bronze, a zinc-free copper-tin casting alloy with aluminium content.

AlSi10Mg is a lightweight, high-strength aluminium alloy that is widely used in the aerospace, automotive, and medical industries. Its unique combination of aluminium, silicon, and magnesium makes it an ideal material for additive manufacturing processes, such as 3D printing.

References

  1. "Emerald | Anti-Corrosion Methods and Materials | Effect of tin addition on the corrosion resistance of aluminium bronze". Archived from the original on 2014-02-02. Retrieved 2011-01-11.
  2. "Typical Alloys Used - Accurate Specialties Inc". Accurate Specialties Inc. Retrieved 2018-08-28.
  3. "20 Lire, Italy". en.numista.com.