Malayaite

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Malayaite
Malayaite.jpg
Malayaite found in the United Kingdom
General
Category Silicate mineral
Formula
(repeating unit)
CaSnO[SiO4]
IMA symbol Mly [1]
Strunz classification 9.AG.15
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group A2/a
Unit cell a = 7.15 Å, b = 8.90 Å,
c = 6.67 Å; β = 113.4°;
V = 389.50 Å3; Z = 4
Identification
Formula mass 266.87 g/mol
ColorColorless, greenish gray, white, light yellow, orange
Crystal habit Massive or wedge shaped
Mohs scale hardness3.5 - 4
Luster Vitreous or resinuous
Streak White
Diaphaneity Translucent
Specific gravity 4.3 - 4.55
Optical propertiesBiaxial (-)
Refractive index nα = 1.765 nβ = 1.784 nγ = 1.799
Birefringence δ=0.0340-0.0350
Pleochroism x=colorless, y=colorless, z = pale yellow
Other characteristicsFluorescent, Short UV = bright yellowish green
References [2] [3] [4] [5]

Malayaite is a calcium tin silicate mineral with formula CaSnOSiO4. [3] It is a member of the titanite group.

Contents

Discovery

Malayaite was originally found in Perak (a state in Malaysia) and was first described in literature in 1961, though it was not yet given a name. [6] In 1965, the mineral was named and recognized by the International Mineralogical Association. It was named for the locality in which it was discovered; which is the Malay Peninsula in Malaysia. [2]

Crystal structure and symmetry

This mineral is classified under the nesosilicate group for silicate minerals because the titanite group falls under this category as well. Minerals in the nesosilicate group have isolated SiO4 tetrahedra connected to cations. In malayaite, the tetrahedra are connected to the chain of distorted SnO6 octahedra, in which the octahedra are linked by vertex [trans corners] sharing and form chains parallel to the miller index of [100]. Within the SnO6-SiO4 framework, the CaO7 polyhedra form chains parallel to [101]. [7]

Malayaite belongs to the monoclinic crystal system and has a 2/m (prismatic) crystal class. According to the Hermann–Mauguin notation, the '2' refers to the two-fold axis while the 'm' refers to the presence of a single mirror plane. The '/' symbol indicates that the twofold axis is perpendicular to the mirror plane.

The space group for malayaite is A2/a. According to the Bravais lattice symbol, 'A' refers to single face centering of the motif. This means that there is one more point on the center of one face. '2' refers to the two-fold rotation axis while the '/' indicates that a mirror plane is perpendicular to the a-axis, which is the last symbol on that space group notation.

Optical properties

Malayaite exhibits anisotropy so it is doubly refractive and breaks up the light that travels through it into two distinct rays of different speeds. [8] This mineral is known to have very high optical relief and has three indices of refraction. Since it is a monoclinic mineral, Malayaite exhibits two different colors under plane polarized light making it a pleochroic mineral. Malayaite is biaxial birefringent (trirefringent).

Functions and purposes

Malayaite has excellent thermal properties and stability making its host lattice ideal for ceramic pigmentation unlike its analogous mineral, titanite that undergoes phase transition at a higher temperature. [9] This makes chromium-doped malayaite very desirable as it provides a consistent pigment for ceramics. Malayaite contains the element tin which is sometimes doped with chromium or nickel. These chromophore elements allows the mineral to produce different pigmentation. If malayaite is chromium-doped, it produces a pink-red color [10] while with nickel, it produces a purple [11] color. Pink chromium-doped malayaite Ca(Sn,Cr)SiO5 is among a few important minerals used in producing pigments for the ceramic industry, specifically for coloring glazes as it produces a resilient color. [12]

Occurrence

This mineral is generally found in tin-rich contact metamorphic skarn deposits. There is a possibility that malayaite is a hydrothermal altered form of cassiterite-quartz assemblage or some tin-bearing mineral. There have been specimens that were found with malayaite as a coating mineral on cassiterite.

Related Research Articles

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<span class="mw-page-title-main">Plumbogummite</span> Alunite supergroup, phosphate mineral

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<span class="mw-page-title-main">Fluor-liddicoatite</span>

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<span class="mw-page-title-main">Tsumebite</span>

Tsumebite is a rare phosphate mineral named in 1912 after the locality where it was first found, the Tsumeb mine in Namibia, well known to mineral collectors for the wide range of minerals found there. Tsumebite is a compound phosphate and sulfate of lead and copper, with hydroxyl, formula Pb2Cu(PO4)(SO4)(OH). There is a similar mineral called arsentsumebite, where the phosphate group PO4 is replaced by the arsenate group AsO4, giving the formula Pb2Cu(AsO4)(SO4)(OH). Both minerals are members of the brackebuschite group.

<span class="mw-page-title-main">Kröhnkite</span>

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<span class="mw-page-title-main">Vlasovite</span>

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<span class="mw-page-title-main">Guyanaite</span>

Guyanaite (CrOOH) is a chromium oxide mineral that forms as an intergrowth with other chromium oxide minerals known as bracewellite (CrOOH) and grimaldiite (CrOOH) as well as eskolaite (Cr2O3) which in early findings were nearly indistinguishable from one another. These oxides formed so closely as intergrowths with one another that they were initially, and erroneously, identified as a single definite mineral previously known as merumite. Because of its complex history and the previously undiscovered nature of these chromium oxide polymorphs, the relevance of any information found in many early experiments involving the mineral formerly known as merumite in regard to guyanaite is unknown and it is implied that in any further reference of merumite it will have been composed of a mineral assemblage including guyanaite. The rare occurrence and complexity from intergrowth of naturally occurring guyanaite hinders experimental work, leading to laboratory synthesized samples which help to better experiment with the minerals.

<span class="mw-page-title-main">Tumchaite</span>

Tumchaite, Na2(Zr,Sn)Si4O11·H2O, is a colorless to white monoclinic phyllosilicate mineral. It is associated with calcite, dolomite, and pyrite in the late dolomite-calcite carbonatites. It can be transparent to translucent; has a vitreous luster; and has perfect cleavage on {100}. Its hardness is 4.5, between fluorite and apatite. Tumchaite is isotypic with penkvilksite. The structure of the mineral is identified by silicate sheets parallel {100}, formed by alternation of clockwise and counterclockwise growing spiral chains of corner-sharing SiO4 tetrahedra. Tumchaite is named for the river Tumcha near Vuoriyarvi massif.

Cattiite is a phosphate mineral. The mineral was first found in a veins of dolomite carbonatites veins at the bottom of the Zhelezny (Iron) Mine in the Kovdor massif, Kola Peninsula, Russia. Cattiite was tentatively identified as Mg3(PO4)2•22H2O, which as a high hydrate magnesium orthophosphate. Later structural studies, revealed the existence of two polytypes named Mg3(PO4)2•22H2O-1A1 and Mg3(PO4)2•22H2O-1A2.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 Mindat
  3. 1 2 WebMineral
  4. Handbook of Mineralogy
  5. Higgins, J.B., and Ribbe, P.H., (1977) The Structure of Malayaite CaSnOSiO4, a tin analog of Titanite, American Mineralogist, 62, 801-806.
  6. Ingham, F.T., and Bradford, E.F. (1961) First description of malayaite as an unnamed mineral. American Mineralogist, 46, 768.
  7. Higgins, J.B., and Ross, F.K. (1977) The crystal structure of Malayaite: CaSnSiO5. Crystal Structure Communications, 6, 179–182.
  8. Gemology Project Retrieved 2010-10-20
  9. Heyns, A.M., and Harden, P.M. (1999) Evidence for the existence of Cr(IV) in chromium-doped malayaite Cr4+; CaSnOSiO4: a resonance Raman Study. Journal of Physics and Chemistry of Solids, 2, 2, 277-284.
  10. Lee, H.S, and Lee B.H (2008) The development of a Chromium pink glaze coloring. Journal of Ceramic Processing Research, 9, 3, 286-291.
  11. Halefoglu, Y.Z., and Kusvuran, E. (2010) Preparation of ceramic pigments by sol-gel and combustion methods. Journal of Ceramic Processing Research, 11, 1, 92-95.
  12. Costa, G., Ribeiro, M.J., Labrincha, J.A., Dondi, M., Matteucci, F and Crucian, G. (2008) Malayaite ceramic pigments prepared with galvanic sludge. Dyes and Pigments, 78, 2, 157-164.