Malhmoodite | |
---|---|
General | |
Category | Phosphate |
Formula (repeating unit) | Fe Zr(P O 4)·4H 2 O |
IMA symbol | Mmo [1] |
Strunz classification | 7/C.09-35 |
Crystal system | Monoclinic |
Unit cell | a = 9.12 Å b = 5.42 Å c = 19.17 Å β= 94.81° |
Identification | |
Formula mass | 409.07 |
Color | Creamy-white |
Crystal habit | Spherules |
Tenacity | Radiating fibers |
Mohs scale hardness | 3 |
Luster | Silky |
Density | 2.877 g/cm3 |
Optical properties | Biaxial negative |
Refractive index | nα = 1.640 nβ = 1.652 nγ = 1.652 |
Birefringence | δ = 0.012 |
Dispersion | Relatively weak |
References | [2] [3] |
Malhmoodite is a phosphate mineral first discovered at a mine called Union Carbide in Wilson Springs, Arkansas, United States. This mine is 10 km west of Magnet Cove, an alkaline igneous complex, and Union Carbide is in a contact region of alkalic igneous rocks and surrounding sedimentary rocks. The mineral has been approved by the Commission on New Minerals and Mineral Names, IMA, to be named for the late Bertha K. Malhmood, the Administrative Assistant of the Branch of Analytical Laboratories, U.S. Geological Survey. [2]
Malhmoodite occurs perched on kolbeckite plates and seems to be the last deposited in the cavities it occurs. [2] The mineral is very rare, with the only common place to find it in Wilson Springs. However, a few other specimens have been found in Belgium and England. [3]
Malhmoodite is a creamy-white mineral with a silky luster. It exhibits a 3 on the Mohs hardness scale. [3] The spherules of Malhmoodite are made up of thin, flat, radiating, optically homogeneous crystals and seem to form in a parallel extinction and positive elongation. The cores of the spherules appear to be loose material, making up about one-third to one-half of the radius of the spherule. However, the core seems to show higher amounts of Si than the rest of the spherule by using X-ray spectra. The fibers of the mineral are soft and the density could not be directly measured. It was instead calculated using the unit-cell content of four formula units and determined to be 2.877 g/cm3. In the crystal structure work of Malhmoodite, it was found that there was a common [Zr(PO4)2]2- layer. It is considered a pseudohexagonal with orthorhombic dimensions. [2]
Malhmoodite is biaxial negative. The refractive indices are: α = 1.640, β = 1.652, and γ = 1.652 (Na). Dispersion is relatively weak. [2]
Malhmoodite was examined using energy-dispersive X-ray spectra from a scanning electron microscope to show that the mineral contained major amounts of Zr and P, a moderate amount of Fe, but also some minute amounts of Ca, Si, and Ti. However, because of malhmoodite's small size and rarity, it could not be determined chemically by macroscopic tools. X-ray powder data brought the most information about the formulation and then was combined with the elemental information from the scanning electron microscope. The mineral has been attempted to be synthesized in a lab multiple times, but there has been no success. The average composition from the examined malhmoodite grains are listed in the table below. It was collected from 25 analyses. The H2O was by difference and likely reduced by the vacuum when examining the samples. The numbers in the parentheses after the weight percent is the standard deviation. [2]
Oxide | Wt% | Mole Ratios |
---|---|---|
P2O5 | 36.2(9) | 2.01 |
ZrO2 | 28.7(6) | 0.91 |
TiO2 | 0.7(1) | 0.03 |
Al2O3 | 0.3(1) | 0.02 |
FeO | 16.1(8) | 0.88 |
MnO | 0.8(2) | 0.04 |
CaO | 1.3(5) | 0.09 |
MgO | 0.26(6) | 0.3 |
Na2O | 0.11(5) | 0.03 |
SiO2 | 0.3(2) | 0.02 |
F | 0.5(2) | |
H2O | (14.7) | 3.2 |
Total | (100.0) | --- |
A single bundle of fibers was examined with a Gandolfi camera with CrKα radiation to detect reflections. Malhmoodite is in the monoclinic crystal system. The result was recorded as d = 1.52 Å. When compared with everything in the known database, there was no match. However, there was a resemblance to a number of other compounds with the type of formula of MZr(P O 4)•4H 2 O where M was equal to Mn, Ni, Co, Cu, and Zn. However, in that grouping before examining Malhmoodite, there was never Fe in the M spot. [2]
Eudialyte, whose name derives from the Greek phrase Εὖ διάλυτος, eu dialytos, meaning "well decomposable", is a somewhat rare, nine member ring cyclosilicate mineral, which forms in alkaline igneous rocks, such as nepheline syenites. Its name alludes to its ready solubility in acid.
Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4. It is a member of the triphylite group and forms a complete solid solution series with the lithium manganese(II) phosphate, lithiophilite. Triphylite crystallizes in the orthorhombic crystal system. It rarely forms prismatic crystals and is more frequently found in hypidiomorphic rock. It is bluish- to greenish-gray in color, but upon alteration becomes brown to black.
Whitlockite is a mineral, an unusual form of calcium phosphate. Its formula is Ca9(MgFe)(PO4)6PO3OH. It is a relatively rare mineral but is found in granitic pegmatites, phosphate rock deposits, guano caves and in chondrite meteorites. It was first described in 1941 and named for Herbert Percy Whitlock (1868–1948), American mineralogist and curator at the American Museum of Natural History in New York City.
Phosphophyllite (from Ancient Greek phyllon 'leaf', and phosphate) is a rare mineral with the chemical formula Zn2Fe(PO4)2·4H2O, composed of hydrated zinc phosphate. It is highly prized by collectors for its rarity and for its delicate bluish green colour. Phosphophyllite is rarely cut because it is fragile and brittle, and large crystals are too valuable to be broken up.
Panethite, chemical formula (Na,Ca)2(Mg,Fe)2(PO4)2, is a rare phosphate mineral that was only found in one meteorite on Earth. It was originally found in the Dayton meteorite in Ohio. It is classified as H-M symbol (2/m) with space group of P21/n. It is amber in color. It was named in the honor of Friedrich Adolf Paneth (1887–1958), a German chemist who made many contributions toward the discovery of the origin of the universe, and especially studies of meteorites.
Arthurite is a mineral composed of divalent copper and iron ions in combination with trivalent arsenate, phosphate and sulfate ions with hydrogen and oxygen. Initially discovered by Sir Arthur Russell in 1954 at Hingston Down Consols mine in Calstock, Cornwall, England, arthurite is formed as a resultant mineral in the oxidation region of some copper deposits by the variation of enargite or arsenopyrite. The chemical formula of Arthurite is CuFe23+(AsO4,PO4,SO4)2(O,OH)2·4H2O.
Igneous petrology is the study of igneous rocks—those that are formed from magma. As a branch of geology, igneous petrology is closely related to volcanology, tectonophysics, and petrology in general. The modern study of igneous rocks utilizes a number of techniques, some of them developed in the fields of chemistry, physics, or other earth sciences. Petrography, crystallography, and isotopic studies are common methods used in igneous petrology.
Beraunite is an iron phosphate mineral. It was first described by August Breithaupt for an occurrence in Beraun currently in the Czech Republic. Beraunite occurs as a secondary mineral in iron ore deposits, and as an alteration product of primary phosphate minerals in granite pegmatites.
Hureaulite is a manganese phosphate with the formula Mn2+5(PO3OH)2(PO4)2·4H2O. It was discovered in 1825 and named in 1826 for the type locality, Les Hureaux, Saint-Sylvestre, Haute-Vienne, Limousin, France. It is sometimes written as huréaulite, but the IMA does not recommend this for English language text.
This list gives an overview of the classification of non-silicate minerals and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, not IMA approved minerals, not named minerals are mostly excluded. Mostly major groups only, or groupings used by New Dana Classification and Mindat.
Ludlamite is a rare phosphate mineral with chemical formula (Fe,Mn,Mg)3(PO4)2·4H2O. It was first described in 1877 for an occurrence in Wheal Jane mine in Cornwall, England and named for English mineralogist Henry Ludlam (1824–1880).
Maricite or marićite is a sodium iron phosphate mineral (NaFe2+PO4), that has two metal cations connected to a phosphate tetrahedron. It is structurally similar to the much more common mineral olivine. Maricite is brittle, usually colorless to gray, and has been found in nodules within shale beds often containing other minerals.
Perhamite is a phosphate mineral with the formula Ca3Al7(SiO4)3(PO4)4(OH)3·16.5(H2O). It occurs in rare isolated masses in amblygonite-rich pegmatite deposits throughout the world. It was discovered in platy sheed form of 1mm hexagonal crystals. It was first described in 1977 by P.J. Dunn and D.E. Appleman from pegmatite collected from Bell Pit, Newry, Maine. Other specimens have been found in Kapunda, South Australia, in Silver Coin mine near Humboldt County, Nevada and various locations throughout Europe.
Satterlyite is a hydroxyl bearing iron phosphate mineral. The mineral can be found in phosphatic shales and was first discovered in the Big Fish River area in Yukon Territory, Canada.
Penikisite was discovered by Alan Kulan and Gunar Penikis near Rapid Creek, Yukon Territory. The mineral is a member of the bjarebyite group along with kulanite, ideally BaFe2+2Al2(PO4)3(OH)3, and bjarebyite, ideally BaMn2+2Al2(PO4)3(OH)3. It is among several new minerals that have been discovered in the Rapid Creek and Big Fish areas of Yukon Territory. Kulanite is similar in many ways to penikisite in appearance and properties. The chemical formula for penikisite is Ba(Mg,Fe,Ca)Al2(PO4)2(OH)3. It has a hardness of about 4 and a density of 3.79 g/cm3. Penikisite is unique among the bjarebyite group in being monoclinic and has a biaxial optical class. It comes in shades of blue and green and, when rubbed on a streak plate, is pale green to white in color. Although penikisite and kulanite both range from blue to green, penikisite zones are easily distinguishable from kulanite zones in kulanite-penikisite crystals because they are lighter than the darker kulanite in color. Penikisite is a phosphate and is different from kulanite in that it is a magnesium-rich phosphate whereas kulanite is an iron-rich phosphate.
Zigrasite is a phosphate mineral with the chemical formula of MgZr(PO4)2(H2O)4. Zigrasite was discovered and is only known to occur in the Dunton Quarry at Oxford County, Maine. Zigrasite was specifically found in the giant 1972 gem tourmaline-bearing pocket at the Dunton Quarry. Zigrasite is named after James Zigras who originally discovered and brought the mineral to attention.
Kosnarite is an alkali zirconium phosphate mineral (KZr2(PO4)3) named after an expert of pegmatites Richard A. Kosnar. Kosnarite contains potassium, oxygen, phosphorus, and zirconium with sodium, rubidium, hafnium, manganese and fluorine (Na, Rb, Hf, Mn, and F) being common impurities found in kosnarite. It was discovered in nature for the first time in 1991 by Vandall T. King. Samples that were found in granitic pegmatites from the Mount Mica Quarry, Paris, Oxford County, Maine, US were sent to Eugene E. Foord for study. This became the first recorded case of naturally occurring kosnarite.
Cattiite is a phosphate mineral. The mineral was first found in a veins of dolomite carbonatites veins at the bottom of the Zhelezny (Iron) Mine in the Kovdor massif, Kola Peninsula, Russia. Cattiite was tentatively identified as Mg3(PO4)2·22H2O, which as a high hydrate magnesium orthophosphate. Later structural studies, revealed the existence of two polytypes named Mg3(PO4)2·22H2O-1A1 and Mg3(PO4)2·22H2O-1A2.
Zincoberaunite is an iron and zinc phosphate mineral, the Zn analogue of beraunite. It was first described by Chukanov et al. for an occurrence in Hagendorf Sud pegmatite in Germany. Zincoberaunite occurs as a secondary mineral as an alteration product of primary phosphate minerals in granite pegmatites.
The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.