A masterbatch is a concentrated mixture of pigments and / or additives blended and extruded together in a carrier matrix, such as resin or wax, that is used to add these mixed additives to a final plastic product. The additives may be used for colouring (a "colour masterbatch") or for imparting other properties (an "additive masterbatch"). The typical alternative to using a masterbatch is to compound the plastic from raw undiluted additives.
The general process for the manufacture of masterbatches involves first identifying and weighing the needed pigments and/or additives, then mixing the pigments or additives with a carrier resin or polymer. Finally, the concentrated mixture is extruded, cooled and formed into granules, powders, or other masterbatch vehicles and the final product is bagged. [1]
The carrier material of the masterbatch can be based on wax (a universal carrier) or a specific polymer that is identical to or compatible with the natural polymer used (a polymer-specific carrier). Polymers such as EVA or LDPE can be used as carriers for polyolefins and nylon, while polystyrene can be used for ABS, SAN, and sometimes polycarbonates. When a carrier other than the base plastic is used, this carrier material may modify the resulting plastic's properties. The usual ratio of masterbatch to base polymer is 1–5%. Several masterbatches (colors and various additives) can be used together. [2]
Processing machines are usually fed with premixed granules of the host polymer and the masterbatch, where the final mixing takes place in the screw and extrusion parts of the processor. Granule processing is sometimes prone to causing adverse effects, such as the separation of the masterbatch and the base material in the hopper. As an alternative, the masterbatch can be added directly to the machine's screw as a free-flowing solid or, if the masterbatch is liquid, by a peristaltic pump. Such use of liquid masterbatches allows highly accurate dosing and quick color changes between machine runs. [3] [4]
Masterbatches are highly concentrated compared to the target composition, with high "let-down ratios"; for example, often 25 kgs of a masterbatch can be used to compound one ton of base polymer. [5]
The dilutive nature of masterbatches, compared to raw additives, allows for higher accuracy in dosing small amounts of expensive additives. The use of granular solid masterbatches reduces problems with dust typically inherent to the use of finer-grained solid additives. Solid masterbatches have longer shelf lives than solutions in solvents, which evaporate over time. The masterbatch usually contains 40–65% of the additive, but the range can be as wide as 15–80% in extreme cases. [2]
The additives in a masterbatch are chosen to impart desired physical property changes to a final plastic product. They can increase volumetric output due to thermal conductivity and volumetric expansion at a given temperature as well as potentially increasing the toughness, flexural stiffness, adhesion, and printability of a final product. [6] The additives in a masterbatch can modify the permanent electrical conductivity of a plastic product, which can prevent problems caused by static electrical charges, [7] or the specific heat capacity, which can help reduce material costs by reducing energy used to run the machine. [8]
Depending on the needs of the output product, manufacturers mix primary plastic with additives in a certain amount. These raw materials are mixed through the process of casting, compression and pressing to create the masterbatch, which can be used directly as an input material or in combination with other materials to make plastic products through different forming methods. [9]
Additive masterbatches modify various properties of the base plastic: [10]
Masterbatches are used in the following areas:
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has generic name (help)Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene.
Although PET is used in several applications, as of 2022 only bottles are collected at a substantial scale. The main motivations have been either cost reduction or recycle content of retail goods. An increasing amount is recycled back into bottles, the rest goes into fibres, film, thermoformed packaging and strapping. After sorting, cleaning and grinding, 'bottle flake' is obtained, which is then processed by either:
Fibre-reinforced plastic is a composite material made of a polymer matrix reinforced with fibres. The fibres are usually glass, carbon, aramid, or basalt. Rarely, other fibres such as paper, wood, boron, or asbestos have been used. The polymer is usually an epoxy, vinyl ester, or polyester thermosetting plastic, though phenol formaldehyde resins are still in use.
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Bioplastics are plastic materials produced from renewable biomass sources, such as vegetable fats and oils, corn starch and rice starch, straw, woodchips, sawdust, recycled food waste, etc. Some bioplastics are obtained by processing directly from natural biopolymers including polysaccharides and proteins, while others are chemically synthesized from sugar derivatives and lipids from either plants or animals, or biologically generated by fermentation of sugars or lipids. In contrast, common plastics, such as fossil-fuel plastics are derived from petroleum or natural gas.
Silicone rubber is an elastomer composed of silicone—itself a polymer—containing silicon together with carbon, hydrogen, and oxygen. Silicone rubbers are widely used in industry, and there are multiple formulations. Silicone rubbers are often one- or two-part polymers, and may contain fillers to improve properties or reduce cost. Silicone rubber is generally non-reactive, stable, and resistant to extreme environments and temperatures from −55 to 300 °C while still maintaining its useful properties. Due to these properties and its ease of manufacturing and shaping, silicone rubber can be found in a wide variety of products, including voltage line insulators; automotive applications; cooking, baking, and food storage products; apparel such as undergarments, sportswear, and footwear; electronics; medical devices and implants; and in home repair and hardware, in products such as silicone sealants.
Thermoplastic elastomers (TPE), sometimes referred to as thermoplastic rubbers (TPR), are a class of copolymers or a physical mix of polymers that consist of materials with both thermoplastic and elastomeric properties.
Coated paper is paper that has been coated by a mixture of materials or a polymer to impart certain qualities to the paper, including weight, surface gloss, smoothness, or reduced ink absorbency. Various materials, including kaolinite, calcium carbonate, bentonite, and talc, can be used to coat paper for high-quality printing used in the packaging industry and in magazines.
Plastics extrusion is a high-volume manufacturing process in which raw plastic is melted and formed into a continuous profile. Extrusion produces items such as pipe/tubing, weatherstripping, fencing, deck railings, window frames, plastic films and sheeting, thermoplastic coatings, and wire insulation.
Polyethylene or polythene film biodegrades naturally, albeit over a long period of time. Methods are available to make it more degradable under certain conditions of sunlight, moisture, oxygen, and composting and enhancement of biodegradation by reducing the hydrophobic polymer and increasing hydrophilic properties.
Biodegradable plastics are plastics that can be decomposed by the action of living organisms, usually microbes, into water, carbon dioxide, and biomass. Biodegradable plastics are commonly produced with renewable raw materials, micro-organisms, petrochemicals, or combinations of all three.
Filler materials are particles added to resin or binders that can improve specific properties, make the product cheaper, or a mixture of both. The two largest segments for filler material use is elastomers and plastics. Worldwide, more than 53 million tons of fillers are used every year in application areas such as paper, plastics, rubber, paints, coatings, adhesives, and sealants. As such, fillers, produced by more than 700 companies, rank among the world's major raw materials and are contained in a variety of goods for daily consumer needs. The top filler materials used are ground calcium carbonate (GCC), precipitated calcium carbonate (PCC), kaolin, talc, and carbon black.
Polymer engineering is generally an engineering field that designs, analyses, and modifies polymer materials. Polymer engineering covers aspects of the petrochemical industry, polymerization, structure and characterization of polymers, properties of polymers, compounding and processing of polymers and description of major polymers, structure property relations and applications.
Plastics are a wide range of synthetic or semi-synthetic materials that use polymers as a main ingredient. Their plasticity makes it possible for plastics to be molded, extruded or pressed into solid objects of various shapes. This adaptability, plus a wide range of other properties, such as being lightweight, durable, flexible, and inexpensive to produce, has led to their widespread use. Plastics typically are made through human industrial systems. Most modern plastics are derived from fossil fuel-based chemicals like natural gas or petroleum; however, recent industrial methods use variants made from renewable materials, such as corn or cotton derivatives.
The term liquid color or liquid color concentrate describes to a system consisting of a liquid binder (carrier), dyes or pigments and other additives such as process additives, stabilisers or similar. The liquid colors are mixed into the plastic for coloring or changing the properties.
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The economics of plastics processing is determined by the type of process. Plastics can be processed with the following methods: machining, compression molding, transfer molding, injection molding, extrusion, rotational molding, blow molding, thermoforming, casting, forging, and foam molding. Processing methods are selected based on equipment cost, production rate, tooling cost, and build volume. High equipment and tooling cost methods are typically used for large production volumes whereas low - medium equipment cost and tooling cost methods are used for low production volumes. Compression molding, transfer molding, injection molding, forging, and foam molding have high equipment and tooling cost. Lower cost processes are machining, extruding, rotational molding, blow molding, thermoforming, and casting. A summary of each process and its cost is displayed in figure 1.
Material extrusion-based additive manufacturing (EAM) represents one of the seven categories of 3d printing processes, defined by the ISO international standard 17296-2. While it is mostly used for plastics, under the name of FDM or FFF, it can also be used for metals and ceramics. In this AM process category, the feedstock materials are mixtures of a polymeric binder and a fine grain solid powder of metal or ceramic materials. Similar type of feedstock is also used in the Metal Injection Molding (MIM) and in the Ceramic Injection Molding (CIM) processes. The extruder pushes the material towards a heated nozzle thanks to