Melt blowing

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Melt blowing process

Melt blowing is a conventional fabrication method of micro- and nanofibers where a polymer melt is extruded through small nozzles surrounded by high speed blowing gas. The randomly deposited fibers form a nonwoven sheet product applicable for filtration, sorbents, apparels and drug delivery systems. The substantial benefits of melt blowing are simplicity, high specific productivity[ jargon ] and solvent-free operation. Choosing an appropriate combination of polymers with optimized rheological and surface properties, scientists have been able to produce melt-blown fibers with an average diameter as small as 36 nm. [1]

Contents

History

During volcanic activity a fibrous material may be drawn by vigorous wind from molten basaltic magma called Pele's hair. [2] The same phenomenon applies for melt blowing of polymers. The first research on melt blowing was a naval attempt in the US to produce fine filtration materials for radiation measurements on drone aircraft in the 1950s. [3] Later on, Exxon Corporation developed the first industrial process based on the melt blowing principle with high throughput levels. [4] China produces 40% of the non-woven fabric in the world with the majority produced in Hebei province (2018). [5]

Polymers

Polymers with thermoplastic behavior are applicable for melt blowing. The main polymer types commonly processed with melt blowing: [6]

Process

Melt blowing is a manufacturing process used to create nonwoven fabrics and materials. It is particularly known for its ability to produce fine fibers, which can be used in various applications. Here's an overview of how melt blowing works: [7]

Uses

Microscopic image of the outer layer of a surgical mask, made from melt blown polymer filaments Vneshnii sloi meditsinskoi maski (poliarizatsiia).jpg
Microscopic image of the outer layer of a surgical mask, made from melt blown polymer filaments

The main uses of melt-blown nonwovens and other innovative approaches are as follows. [8]

Filtration

Nonwoven melt-blown fabrics are porous. As a result, they can filter liquids and gases. Their applications include water treatment, masks, and air-conditioning filters. During the COVID-19 pandemic, the price of meltblown spiked from few thousand USD per ton to approximately 100 thousand USD per ton.

Sorbents

Nonwoven materials can retain liquids several times their own weight. Thus, those made from polypropylene are ideal for collecting oil contamination. [9] [10]

Hygiene products

The high absorption of melt-blown fabrics is exploited in disposable diapers and feminine hygiene products. [11]

Apparels

Melt-blown fabrics have three qualities that help make them useful for clothing, especially in harsh environments: thermal insulation, relative moisture resistance and breathability.

Drug delivery

Melt blowing can produce drug-loaded fibers for controlled drug delivery. [12] The high drug throughput rate (extrusion feeding), solvent-free operation and increased surface area of the product make melt blowing a promising new formulation technique.

Related Research Articles

<span class="mw-page-title-main">Polypropylene</span> Thermoplastic polymer

Polypropylene (PP), also known as polypropene, is a thermoplastic polymer used in a wide variety of applications. It is produced via chain-growth polymerization from the monomer propylene.

<span class="mw-page-title-main">Wood–plastic composite</span> Composite materials made of wood fiber and thermoplastics

Wood–plastic composites (WPCs) are composite materials made of wood fiber/wood flour and thermoplastic(s) such as polyethylene (PE), polypropylene (PP), polyvinyl chloride (PVC), or polylactic acid (PLA).

<span class="mw-page-title-main">Electrospinning</span> Fiber production method

Electrospinning is a fiber production method that uses electrical force to draw charged threads of polymer solutions for producing nanofibers with diameters ranging from nanometers to micrometers. Electrospinning shares characteristics of both electrospraying and conventional solution dry spinning of fibers. The process does not require the use of coagulation chemistry or high temperatures to produce solid threads from solution. This makes the process particularly suited to the production of fibers using large and complex molecules. Electrospinning from molten precursors is also practiced; this method ensures that no solvent can be carried over into the final product.

<span class="mw-page-title-main">Blow molding</span> Manufacturing process for forming and joining together hollow plastic parts

Blow molding is a manufacturing process for forming hollow plastic parts. It is also used for forming glass bottles or other hollow shapes.

<span class="mw-page-title-main">Sorbent</span> Material that absorbs or adsorbs

A sorbent is an insoluble material that either absorbs or adsorbs liquids or gases. They are frequently used to remove pollutants and in the cleanup of chemical accidents and oil spills. Besides their uses in industry, sorbents are used in commercial products such as diapers and odor absorbents, and are researched for applications in environmental air analysis, particularly in the analysis of volatile organic compounds. The name sorbent is derived from sorption, which is itself a derivation from adsorption and absorption.

<span class="mw-page-title-main">Nonwoven fabric</span> Sheet of fibers

Nonwoven fabric or non-woven fabric is a fabric-like material made from staple fibre (short) and long fibres, bonded together by chemical, mechanical, heat or solvent treatment. The term is used in the textile manufacturing industry to denote fabrics, such as felt, which are neither woven nor knitted. Some non-woven materials lack sufficient strength unless densified or reinforced by a backing. In recent years, non-wovens have become an alternative to polyurethane foam.

<span class="mw-page-title-main">Nanofiber</span> Natural or synthetic fibers with diameters in the nanometer range

Nanofibers are fibers with diameters in the nanometer range. Nanofibers can be generated from different polymers and hence have different physical properties and application potentials. Examples of natural polymers include collagen, cellulose, silk fibroin, keratin, gelatin and polysaccharides such as chitosan and alginate. Examples of synthetic polymers include poly(lactic acid) (PLA), polycaprolactone (PCL), polyurethane (PU), poly(lactic-co-glycolic acid) (PLGA), poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), and poly(ethylene-co-vinylacetate) (PEVA). Polymer chains are connected via covalent bonds. The diameters of nanofibers depend on the type of polymer used and the method of production. All polymer nanofibers are unique for their large surface area-to-volume ratio, high porosity, appreciable mechanical strength, and flexibility in functionalization compared to their microfiber counterparts.

<span class="mw-page-title-main">Plastic extrusion</span> Melted plastic manufacturing process

Plastics extrusion is a high-volume manufacturing process in which raw plastic is melted and formed into a continuous profile. Extrusion produces items such as pipe/tubing, weatherstripping, fencing, deck railings, window frames, plastic films and sheeting, thermoplastic coatings, and wire insulation.

Olefin fiber is a synthetic fiber made from a polyolefin, such as polypropylene or polyethylene. It is used in wallpaper, carpeting, ropes, and vehicle interiors.

<span class="mw-page-title-main">Nanofabrics</span> Textiles engineered with small particles that give ordinary materials advantageous properties

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<span class="mw-page-title-main">Filler (materials)</span> Particles added to improve its properties

Filler materials are particles added to resin or binders that can improve specific properties, make the product cheaper, or a mixture of both. The two largest segments for filler material use is elastomers and plastics. Worldwide, more than 53 million tons of fillers are used every year in application areas such as paper, plastics, rubber, paints, coatings, adhesives, and sealants. As such, fillers, produced by more than 700 companies, rank among the world's major raw materials and are contained in a variety of goods for daily consumer needs. The top filler materials used are ground calcium carbonate (GCC), precipitated calcium carbonate (PCC), kaolin, talc, and carbon black. Filler materials can affect the tensile strength, toughness, heat resistance, color, clarity, etc. A good example of this is the addition of talc to polypropylene. Most of the filler materials used in plastics are mineral or glass based filler materials. Particulates and fibers are the main subgroups of filler materials. Particulates are small particles of filler that are mixed in the matrix where size and aspect ratio are important. Fibers are small circular strands that can be very long and have very high aspect ratios.

Spinning is a manufacturing process for creating polymer fibers. It is a specialized form of extrusion that uses a spinneret to form multiple continuous filaments.

<span class="mw-page-title-main">Melt electrospinning</span>

Melt electrospinning is a processing technique to produce fibrous structures from polymer melts for applications that include tissue engineering, textiles and filtration. In general, electrospinning can be performed using either polymer melts or polymer solutions. However, melt electrospinning is distinct in that the collection of the fiber can very focused; combined with moving collectors, melt electrospinning writing is a way to perform 3D printing. Since volatile solvents are not used, there are benefits for some applications where solvent toxicity and accumulation during manufacturing are a concern.

A die in polymer processing is a metal restrictor or channel capable of providing a constant cross sectional profile to a stream of liquid polymer. This allows for continuous processing of shapes such as sheets, films, pipes, rods, and other more complex profiles. This is a continuous process, allowing for constant production, as opposed to a sequential (non-constant) process such as injection molding.

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<span class="mw-page-title-main">Medical textiles</span> Textiles for medical and healthcare use

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References

  1. Soltani, Iman; Macosko, Christopher W. (2018). "Influence of rheology and surface properties on morphology of nanofibers derived from islands-in-the-sea meltblown nonwovens". Polymer. 145: 21–30. doi: 10.1016/j.polymer.2018.04.051 . S2CID   139262140.
  2. Shimozuru, D. (1994). "Physical parameters governing the formation of Pele's hair and tears". Bulletin of Volcanology. 56 (3): 217–219. Bibcode:1994BVol...56..217S. doi:10.1007/s004450050030.
  3. Shaumbaugh, R.L. (1988). "A macroscopic view of the melt-blowing process for producing microfibers". Ind. Eng. Chem. Res. 27 (12): 2363–2372. doi:10.1021/ie00084a021.
  4. Ellison CJ, Phatak A, Giles DW, Macosko CW, Bates FS (2007). "Melt blown nanofibers: Fiber diameter distributions and onset of fiber breakup". Polymer. 48 (11): 3306–3316. doi:10.1016/j.polymer.2007.04.005.
  5. "China export credit insurance company releases domestic mask supply and demand risk analysis and outlook". Textile Net China. February 17, 2020.
  6. Dutton, Kathryn C. (2008). "Overview and analysis of the meltblown process and parameters". Journal of Textile and Apparel, Technology and Management. 6.
  7. melt blown nonwoven process Retrieved 7 June 2016.
  8. McCulloch, John G. (1999). "The history of the development of melt blowing technology". International Nonwovens Journal. 8: 1558925099OS–80. doi: 10.1177/1558925099os-800123 .
  9. Wei, Q. F.; Mather, R. R.; Fotheringham, A. F. & Yang, R. D. (2003). "Evaluation of nonwoven polypropylene oil sorbents in marine oil-spill recovery". Marine Pollution Bulletin. 46 (6): 780–783. doi:10.1016/s0025-326x(03)00042-0. PMID   12787586.
  10. Sarbatly R.; Kamin, Z. & Krishnaiah D. (2016). "A review of polymer nanofibres by electrospinning and their application in oil-water separation for cleaning up marine oil spills". Marine Pollution Bulletin. 106 (1–2): 8–16. doi:10.1016/j.marpolbul.2016.03.037. PMID   27016959.
  11. Wehmann, Michael; McCulloch, W. John G. (2012). "Melt blowing technology". In Karger-Kocsis, J. (ed.). Polypropylene: an A-Z reference. Polymer Science and Technology Series. Vol. 2. Springer Science & Business Media. pp. 415–420. doi:10.1007/978-94-011-4421-6_58. ISBN   978-94-010-5899-5.
  12. Balogh, A.; Farkas, B.; Faragó, K.; Farkas, A.; Wagner, I.; Van Assche, I.; et al. (2015). "Melt-blown and electrospun drug-loaded polymer fiber mats for dissolution enhancement: A comparative study" (PDF). Journal of Pharmaceutical Sciences. 104 (5): 1767–1776. doi:10.1002/jps.24399. PMID   25761776.