Nicholas A. Kotov

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Nicholas A. Kotov
N.kotov.2022.jpg
2021
Born (1965-08-29) August 29, 1965 (age 58)
NationalityAmerican
Alma mater Moscow State University
Known for self-assembling materials, layer-by-layer assembly, nanotechnology
Scientific career
Fields Chemistry, Chemical Engineering, Materials Science, Nanotechnology, Biomedical Engineering
Institutions University of Michigan
Thesis Photoelectrochemical Effects at the Interface of the Two Immiscible Electrolyte Solutions
Doctoral advisor Mikhail Kuzmin
Other academic advisorsJanos H. Fendler

Nicholas A. Kotov (born August 29, 1965, Moscow, USSR) is the Irving Langmuir Distinguished Professor of Chemical Sciences and Engineering at the University of Michigan in Ann Arbor, MI, USA. [1] Prof. Nicholas Kotov demonstrated that the ability to self-organize into complex structures is the unifying property of all inorganic nanostructures. [2] [3] He has developed a family of bioinspired composite materials with a wide spectrum of properties that were previously unattainable in classical materials. [4] These composite biomimetic materials are exemplified by his nacre-like ultrastrong yet transparent composites, [5] [6] enamel-like, stiff yet vibration-isolating composites, and cartilage-like membranes with both high strength and ion conductance. [6] [7] [8] [9]

Contents

Work

Kotov's research is focused on the development of biomimetic nanocomposites, the self-assembly of nanoparticles, [10] and chiral nanostructures. [11] Utilizing layer-by-layer assembly (LbL), [12] Kotov prepared a wide spectrum of nacre-like nanocomposites including those from clay [13] and graphite oxide. [14] He showed that clay-based biomimetic composites can attain mechanical properties comparable to some grades of steel while retaining transparency. [15] This discovery spurred the development of new methods for the mass-production of nacre-like materials from a large variety of inorganic nanosheets. [16] While being inspired by natural materials, these composites far exceeded the properties of their natural prototypes and add other optical, electrical, thermal, and membrane properties.

Kotov extended the concept of biomimetic nanostructures to inorganic nanoparticles. He established that, similarly to many proteins and other biomolecules, nanoparticles can self-organize into chains, [10] sheets, [17] nanowires, twisted ribbons [18] and nanohelices, [19] [20] and spherical supraparticles replicating viral capsids. [21]

Kotov's work established that the biomimetic self-assembly behavior of nanoparticles originates from interparticle interactions at the nanoscale, [22] in which chirality also plays a prominent role. [23] His studies on the self-assembly of chiral nanostructures have led to the development of nanoparticle assemblies with complexity exceeding those found in biological organisms. [24]

Education and research career

Education and early career

Kotov received his MS (1987) and PhD (1990) degrees in chemistry from Moscow State University, where his research concerned liquid-liquid interfaces imitating cell membranes for solar energy conversion. After graduation, he took up a postdoctoral position in the research group of Prof. Janos Fendler in the Department of Chemistry at Syracuse University in New York state working on nanoparticle synthesis and assembly at interfaces.

Independent research career

Kotov took up a position as assistant professor of chemistry at the Oklahoma State University in Stillwater, Oklahoma in 1996, gaining promotion to associate professor in 2001. In 2003 he moved to the University of Michigan where he is now the Irving Langmuir Distinguished Professor of Chemical Sciences and Engineering.

Awards

Personal life

Kotov married chemist Elvira Stesikova, PhD, in 1991. They have two daughters, Sophia and Nicole.

Related Research Articles

<span class="mw-page-title-main">Biomimetics</span> Imitation of biological systems for the solving of human problems

Biomimetics or biomimicry is the emulation of the models, systems, and elements of nature for the purpose of solving complex human problems. The terms "biomimetics" and "biomimicry" are derived from Ancient Greek: βίος (bios), life, and μίμησις (mīmēsis), imitation, from μιμεῖσθαι (mīmeisthai), to imitate, from μῖμος (mimos), actor. A closely related field is bionics.

<span class="mw-page-title-main">Self-assembly</span> Process in which disordered components form an organized structure or pattern

Self-assembly is a process in which a disordered system of pre-existing components forms an organized structure or pattern as a consequence of specific, local interactions among the components themselves, without external direction. When the constitutive components are molecules, the process is termed molecular self-assembly.

<span class="mw-page-title-main">Artificial enzyme</span>

An artificial enzyme is a synthetic organic molecule or ion that recreates one or more functions of an enzyme. It seeks to deliver catalysis at rates and selectivity observed in naturally occurring enzymes.

Layer-by-layer (LbL) deposition is a thin film fabrication technique. The films are formed by depositing alternating layers of oppositely charged materials with wash steps in between. This can be accomplished by using various techniques such as immersion, spin, spray, electromagnetism, or fluidics.

<span class="mw-page-title-main">Nanocellulose</span> Material composed of nanosized cellulose fibrils

Nanocellulose is a term referring to nano-structured cellulose. This may be either cellulose nanocrystal, cellulose nanofibers (CNF) also called nanofibrillated cellulose (NFC), or bacterial nanocellulose, which refers to nano-structured cellulose produced by bacteria.

<span class="mw-page-title-main">Samuel I. Stupp</span> Costa Rican-American Chemist

Samuel I. Stupp, is a Board of Trustees Professor of Materials Science, Chemistry, and Medicine at Northwestern University in Chicago, IL. He is best known for his work on self-assembling materials and supramolecular chemistry. One of his most notable discoveries is a broad class of peptide amphiphiles that self-assemble into high aspect ratio nanofibers with extensive applications in regenerative medicine. He has also made significant contributions to the fields of supramolecular chemistry, nanotechnology, and organic electronic materials. He has over 500 peer-reviewed publications and was one of the 100 most cited chemists in the 2000–2010 decade.

<span class="mw-page-title-main">Sharon Glotzer</span> American physicist

Sharon C. Glotzer is an American scientist and "digital alchemist", the Anthony C. Lembke Department Chair of Chemical Engineering, the John Werner Cahn Distinguished University Professor of Engineering and the Stuart W. Churchill Collegiate Professor of Chemical Engineering at the University of Michigan, where she is also professor of materials science and engineering, professor of physics, professor of macromolecular science and engineering, and professor of applied physics. She is recognized for her contributions to the fields of soft matter and computational science, most notably on problems in assembly science and engineering, nanoscience, and the glass transition, for which the elucidation of the nature of dynamical heterogeneity in glassy liquids is of particular significance. She is a member of the National Academy of Sciences, the National Academy of Engineering, and the American Academy of Arts and Sciences.

<span class="mw-page-title-main">Ayyappanpillai Ajayaghosh</span> Indian organic chemist (born 1962)

Ayyappanpillai Ajayaghosh is a research scientist/academician in the domain of interdisciplinary chemistry, and the former Director of the National Institute for Interdisciplinary Science and Technology. He is known for his studies on supramolecular assemblies, organogels, photoresponsive materials, chemosensory and security materials systems and is an elected fellow of all the three major Indian science academies viz. the National Academy of Sciences, India, Indian National Science Academy and the Indian Academy of Sciences as well as The World Academy of Sciences. The Council of Scientific and Industrial Research, the apex agency of the Government of India for scientific research, awarded him the Shanti Swarup Bhatnagar Prize for Science and Technology, one of the highest Indian science awards for his contributions to Chemical Sciences in 2007. He is the first chemist to receive the Infosys Science Prize for physical sciences, awarded by the Infosys Science Foundation. He received the TWAS Prize of The World Academy of Sciences in 2013 and the Goyal prize in 2019.

<span class="mw-page-title-main">Self-assembly of nanoparticles</span>

Nanoparticles are classified as having at least one of its dimensions in the range of 1-100 nanometers (nm). The small size of nanoparticles allows them to have unique characteristics which may not be possible on the macro-scale. Self-assembly is the spontaneous organization of smaller subunits to form larger, well-organized patterns. For nanoparticles, this spontaneous assembly is a consequence of interactions between the particles aimed at achieving a thermodynamic equilibrium and reducing the system’s free energy. The thermodynamics definition of self-assembly was introduced by Professor Nicholas A. Kotov. He describes self-assembly as a process where components of the system acquire non-random spatial distribution with respect to each other and the boundaries of the system. This definition allows one to account for mass and energy fluxes taking place in the self-assembly processes.

A nanosheet is a two-dimensional nanostructure with thickness in a scale ranging from 1 to 100 nm.

Stephen Mann, FRS, FRSC, is Professor of Chemistry, co-director of the Max Planck Bristol Centre for Minimal Biology, director of the Centre for Organized Matter Chemistry, director of the Centre for Protolife Research, and was principal of the Bristol Centre for Functional Nanomaterials at the University of Bristol, UK.

Niveen M. Khashab is a Lebanese chemist and an associate Professor of chemical Sciences and engineering at King Abdullah University of Science and Technology in Saudi Arabia since 2009. She is a laureate of the 2017 L'Oréal-UNESCO Awards for Women in Science "for her contributions to innovative smart hybrid materials aimed at drug delivery and for developing new techniques to monitor intracellular antioxidant activity." She is also a fellow of the Royal Chemical Society, and a member of the American Chemical Society.

<span class="mw-page-title-main">Orlin D. Velev</span>

Orlin D. Velev is the INVISTA Professor in the Department of Chemical and Biomolecular Engineering at North Carolina State University. He is best known for his work in soft matter, colloid science, and nanoscience.

<span class="mw-page-title-main">Irshad Hussain</span> Pakistani Scientist

Irshad Hussain is a Pakistani Scientist in the field of chemistry and among the few pioneers to initiate nanomaterials research in Pakistan.

Fiona C. Meldrum is a British scientist who is a Professor of Inorganic Chemistry at the University of Leeds where she works on bio-inspired materials and crystallisation processes. She won the 2017 Royal Society of Chemistry Interdisciplinary Prize.

So-Jung Park 박소정(朴昭靜) is a professor of chemistry at Ewha Womans University, Republic of Korea. Her research considers the self-assembly of nanoparticles and functional molecules for biomedical and optoelectronic devices. She serves as Associate Editor of ACS Applied Materials & Interfaces and Nanoscale.

<span class="mw-page-title-main">Roeland Nolte</span> Dutch chemist, emeritus Royal Netherlands of Arts and Sciences professor

Roeland J. M. Nolte is a Dutch chemist, known for his work in the fields of organic chemistry, biochemistry, polymer chemistry, and supramolecular chemistry. He is an emeritus Royal Netherlands of Arts and Sciences professor and an emeritus professor of Organic Chemistry at Radboud University in Nijmegen, The Netherlands. Currently, he holds a special chair, i.e. professor of Molecular Nanotechnology, at this university. Nolte is considered to be one of the pioneers of the field of supramolecular chemistry, which encompasses the design and synthesis of new chemical structures from low molecular weight compounds and biopolymers using so-called non-covalent interactions. He published many studies on supramolecular assembly and biomimetic catalysts, which find applications in the field of nanomaterials and medicine.

Stephanie Lee Brock is an American chemist who is professor of inorganic chemistry at Wayne State University. Her research considers transition metal pnictides and chalcogenide nanomaterials. She is a Fellow of the American Association for the Advancement of Science and the American Chemical Society.

Silvia Vignolini is an Italian physicist who is Director of research at the Max Planck Institute of Colloids and Interfaces and Professor of Chemistry and Bio-materials in the Yusuf Hamied Department of Chemistry at the University of Cambridge. Her research investigates natural photonics structures, the self-assembly of cellulose and light propagation through complex structures. She was awarded the KINGFA young investigator award by the American Chemical Society and the Gibson-Fawcett Award in 2018.

Christopher Bruce Murray is the Richard Perry University Professor of Chemistry and Materials Science and Engineering at the University of Pennsylvania. He is a member of the National Academy of Engineering and a Fellow of the Materials Research Society. He was a Clarivate Citation Laureate in 2020. He is known for his contributions to quantum dots and other nanoscale materials.

References

  1. "Nicholas A. Kotov | Michigan Engineering". Engin.umich.edu. Retrieved 2013-10-08.
  2. "acs.org". cen.acs.org. Retrieved 2021-02-10.
  3. "Nicholas Kotov of University of Michigan is 2020 Alpha Chi Sigma Award Recipient". www.aiche.org. 2020-10-12. Retrieved 2021-02-10.
  4. "Kotov wins the Stephanie L. Kwolek Award". Michigan Engineering. May 20, 2016. Retrieved 2021-02-10.
  5. "U-M research: New plastic is strong as steel, transparent". EurekAlert!. Retrieved 2021-02-10.
  6. 1 2 "New Plastic is Transparent and Strong as Steel". NetComposites. Retrieved 2021-02-10.
  7. "Membrane inspired by bone and cartilage efficiently produces electricity from saltwater". ScienceDaily. Retrieved 2021-02-10.
  8. "Inspired by the Tissues of Living Organisms, Researchers Take One Step Closer to Harvesting "Blue Energy"". Yale E360. Retrieved 2021-02-10.
  9. "ten15am.org".
  10. 1 2 Zhiyong Tang; Nicholas A. Kotov; Michael Giersig (2002). "Spontaneous Organization of Single CdTe Nanoparticles into Luminescent Nanowires". Science. 297 (5579): 237–40. Bibcode:2002Sci...297..237T. doi:10.1126/science.1072086. PMID   12114622. S2CID   45388619.
  11. Wei Chen; Ai Bian; Ashish Agarwal; Liqiang Liu; Hebai Shen; Libing Wang; Chuanlai Xu; Nicholas A. Kotov (2009). "Nanoparticle Superstructures Made by Polymerase Chain Reaction: Collective Interactions of Nanoparticles and a New Principle for Chiral Materials". Nano Letters. 9 (5): 2153–2159. Bibcode:2009NanoL...9.2153C. doi:10.1021/nl900726s. PMID   19320495. S2CID   35163925.
  12. G. Decher; J. D. Hong; J. Schmitt (1992). "Buildup of ultrathin multilayer films by a self-assembly process: III. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces". Thin Solid Films. 210/211: 831. Bibcode:1992TSF...210..831D. doi:10.1016/0040-6090(92)90417-A.
  13. Kotov, N. A.; Magonov, S.; Tropsha, E. (March 1998). "Layer-by-Layer Self-Assembly of Alumosilicate−Polyelectrolyte Composites: Mechanism of Deposition, Crack Resistance, and Perspectives for Novel Membrane Materials". Chemistry of Materials. 10 (3): 886–895. doi:10.1021/cm970649b. ISSN   0897-4756.
  14. Kotov, Nicholas A.; Dékány, Imre; Fendler, Janos H. (August 1996). "Ultrathin graphite oxide-polyelectrolyte composites prepared by self-assembly: Transition between conductive and non-conductive states". Advanced Materials. 8 (8): 637–641. Bibcode:1996AdM.....8..637K. doi:10.1002/adma.19960080806.
  15. Podsiadlo, Paul; Kaushik, Amit K.; Arruda, Ellen M.; Waas, Anthony M.; Shim, Bong Sup; Xu, Jiadi; Nandivada, Himabindu; Pumplin, Benjamin G.; Lahann, Joerg (2007-10-05). "Ultrastrong and Stiff Layered Polymer Nanocomposites". Science. 318 (5847): 80–83. Bibcode:2007Sci...318...80P. doi:10.1126/science.1143176. ISSN   0036-8075. PMID   17916728. S2CID   22559961.
  16. Gao, Huai-Ling; Chen, Si-Ming; Mao, Li-Bo; Song, Zhao-Qiang; Yao, Hong-Bin; Cölfen, Helmut; Luo, Xi-Sheng; Zhang, Fu; Pan, Zhao (2017-08-18). "Mass production of bulk artificial nacre with excellent mechanical properties". Nature Communications. 8 (1): 287. Bibcode:2017NatCo...8..287G. doi:10.1038/s41467-017-00392-z. ISSN   2041-1723. PMC   5562756 . PMID   28821851.
  17. Zhiyong Tang; Zhenli Zhang; Ying Wang; Sharon C. Glotzer; Nicholas A. Kotov (2006). "Self-Assembly of CdTe Nanocrystals into Free-Floating Sheets". Science. 314 (5797): 274–8. Bibcode:2006Sci...314..274T. doi:10.1126/science.1128045. PMID   17038616. S2CID   18839769.
  18. Sudhanshu Srivastava; Aaron Santos; Kevin Critchley; Ki-Sub Kim; Paul Podsiadlo; Kai Sun; Jaebeom Lee; Chuanlai Xu; G. Daniel Lilly; Sharon C. Glotzer; Nicholas A. Kotov (2010). "Light-Controlled Self-Assembly of Semiconductor Nanoparticles into Twisted Ribbons". Science. 327 (5971): 1355–9. Bibcode:2010Sci...327.1355S. doi: 10.1126/science.1177218 . PMID   20150443. S2CID   22492581.
  19. Zhou, Yunlong; Marson, Ryan L.; van Anders, Greg; Zhu, Jian; Ma, Guanxiang; Ercius, Peter; Sun, Kai; Yeom, Bongjun; Glotzer, Sharon C. (2016-03-22). "Biomimetic Hierarchical Assembly of Helical Supraparticles from Chiral Nanoparticles". ACS Nano. 10 (3): 3248–3256. doi:10.1021/acsnano.5b05983. ISSN   1936-0851. OSTI   1440921. PMID   26900920. S2CID   30561840.
  20. Feng, Wenchun; Kim, Ji-Young; Wang, Xinzhi; Calcaterra, Heather A.; Qu, Zhibei; Meshi, Louisa; Kotov, Nicholas A. (2017-03-01). "Assembly of mesoscale helices with near-unity enantiomeric excess and light-matter interactions for chiral semiconductors". Science Advances. 3 (3): e1601159. Bibcode:2017SciA....3E1159F. doi:10.1126/sciadv.1601159. ISSN   2375-2548. PMC   5332156 . PMID   28275728.
  21. Xia, Yunsheng; Nguyen, Trung Dac; Yang, Ming; Lee, Byeongdu; Santos, Aaron; Podsiadlo, Paul; Tang, Zhiyong; Glotzer, Sharon C.; Kotov, Nicholas A. (2011-08-21). "Self-assembly of self-limiting monodisperse supraparticles from polydisperse nanoparticles". Nature Nanotechnology. 6 (9): 580–587. Bibcode:2011NatNa...6..580X. doi:10.1038/nnano.2011.121. ISSN   1748-3395. PMID   21857686.
  22. Batista, Carlos A. Silvera; Larson, Ronald G.; Kotov, Nicholas A. (2015-10-09). "Nonadditivity of nanoparticle interactions". Science. 350 (6257): 1242477. doi: 10.1126/science.1242477 . ISSN   0036-8075. PMID   26450215.
  23. Ma, Wei; Xu, Liguang; de Moura, André F.; Wu, Xiaoling; Kuang, Hua; Xu, Chuanlai; Kotov, Nicholas A. (2017-06-28). "Chiral Inorganic Nanostructures". Chemical Reviews. 117 (12): 8041–8093. doi:10.1021/acs.chemrev.6b00755. ISSN   0009-2665. PMID   28426196.
  24. Jiang, Wenfeng; Qu, Zhi-bei; Kumar, Prashant; Vecchio, Drew; Wang, Yuefei; Ma, Yu; Bahng, Joong Hwan; Bernardino, Kalil; Gomes, Weverson R.; Colombari, Felippe M.; Lozada-Blanco, Asdrubal (2020-05-08). "Emergence of complexity in hierarchically organized chiral particles". Science. 368 (6491): 642–648. Bibcode:2020Sci...368..642J. doi:10.1126/science.aaz7949. ISSN   0036-8075. PMID   32273399. S2CID   215726726.
  25. David Turnbull Lectureship Recipients
  26. Nanoscale Science and Engineering Forum Award
  27. 2020 National Academy of Inventors
  28. 2020 Alpha Chi Sigma Award Recipient
  29. Recipients Newton Award
  30. Faculty Profile
  31. 2018 Vannevar Bush Fellows
  32. Soft Matter and Biophysical Chemistry Award Winners
  33. 1 2 Humboldt Foundation Fellowships
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  36. Fifth UNESCO Medals
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  38. Fellow of the Materials Research Society
  39. 2012 Stine Award for Materials Research
  40. Top 100 Materials Scientists in 2000-2010
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  42. 2008 Top 10 Discoveries of the Year
  43. Gran Prix, Materials Research Society Entrepreneurship Challenge
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