Nichromite | |
---|---|
General | |
Category | Spinel group |
Formula (repeating unit) | (Ni,Co,Fe)(Cr,Fe,Al) 2O 4 |
Strunz classification | 4.BB.05 |
Crystal system | Isometric |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Fd3m |
Unit cell | a = 8.32 Å; V = 573.86 Å3; Z = 8 |
Identification | |
Color | Dark green, black |
Crystal habit | Granular, anhedral to subhedral |
Fracture | Conchoidal |
Mohs scale hardness | 6-6+1⁄2 |
Luster | Metallic |
Streak | Greyish green |
Diaphaneity | Opaque |
Specific gravity | 5.10 |
Optical properties | Isotropic |
References | [1] [2] [3] [4] |
Nichromite(Ni,Co,Fe)(Cr,Fe,Al)
2O
4 [1] is a black cubic metallic mineral and member of the spinel group. [5] Nichromite was originally reported from the Bon Accord nickel deposit in Barberton District, South Africa. [1] Occurring naturally in a nickel deposit, nichromite is named for chromite with dominant nickel. [2]
The atomic arrangement of the spinel group is a commonly studied structure and characteristically has four closely packed oxygen atoms. The nickel atoms are organized corresponding to a "normal" spinel arrangement. [6]
The mineral has only been found in the Bon Accord Nickel Deposit in South Africa where it is formed by replacing chromite and rimmed by trevorite. [4]
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit. Ore is extracted from the earth through mining and treated or refined, often via smelting, to extract the valuable metals or minerals. The grade of ore refers to the concentration of the desired material it contains. The value of the metals or minerals a rock contains must be weighed against the cost of extraction to determine whether it is of sufficiently high grade to be worth mining, and is therefore considered an ore.
Spinel is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl
2O
4 in the cubic crystal system. Its name comes from the Latin word spinella, which means spine in reference to its pointed crystals.
Kimberlite is an igneous rock, which sometimes contains diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an 83.5-carat (16.70 g) diamond called the Star of South Africa in 1869 spawned a diamond rush and the digging of the open-pit mine called the Big Hole. Previously, the term kimberlite has been applied to olivine lamproites as Kimberlite II, however this has been in error.
Pentlandite is an iron–nickel sulfide, (Fe,Ni)9S8. Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of weight.
Chalcopyrite ( KAL-ko-PY-ryt) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mohs scale. Its streak is diagnostic as green tinged black.
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite (MgCr2O4). A substitution of the element aluminium can also occur, leading to hercynite (FeAl2O4). Chromite today is mined particularly to make stainless steel through the production of ferrochrome (FeCr), which is an iron-chromium alloy.
Peridotite is a dense, coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic, as the rock contains less than 45% silica. It is high in magnesium (Mg2+), reflecting the high proportions of magnesium-rich olivine, with appreciable iron. Peridotite is derived from Earth's mantle, either as solid blocks and fragments, or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely, reflecting the relative proportions of pyroxenes, chromite, plagioclase, and amphibole.
Trevorite is a rare nickel iron oxide mineral belonging to the spinel group. It has the chemical formula NiFe3+2O4. It is a black mineral with the typical spinel properties of crystallising in the cubic system, black streaked, infusible and insoluble in most acids.
Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic.
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. The minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately.
The Bushveld Igneous Complex (BIC) is the largest layered igneous intrusion within the Earth's crust. It has been tilted and eroded forming the outcrops around what appears to be the edge of a great geological basin: the Transvaal Basin. It is approximately 2 billion years old and is divided into four different limbs: the northern, southern, eastern, and western limbs. The Bushveld Complex comprises the Rustenburg Layered suite, the Lebowa Granites and the Rooiberg Felsics, that are overlain by the Karoo sediments. The site was first discovered around 1897 by Gustaaf Molengraaff.
The Great Dyke is a linear geological feature that trends nearly north-south through the centre of Zimbabwe passing just to the west of the capital, Harare. It consists of a band of short, narrow ridges and hills spanning for approximately 550 kilometres (340 mi). The hills become taller as the range goes north, and reach up to 460 metres (1,510 ft) above the Mvurwi Range. The range is host to vast ore deposits, including gold, silver, chromium, platinum, nickel and asbestos.
Carrollite, CuCo2S4, is a sulfide of copper and cobalt, often with substantial substitution of nickel for the metal ions, and a member of the linnaeite group. It is named after the type locality in Carroll County, Maryland, US, at the Patapsco mine, Sykesville.
Penroseite is a rare selenide mineral with formula (Ni,Co,Cu)Se2. It has a gray-steel color and black streak with a hardness of 3. It is an isometric mineral, 2/m3. Penroseite was first discovered in 1925 in a Bolivian rhyolite. It was named for Richard Penrose (1863–1931), an economic geologist.
Bonaccordite is a rare mineral discovered in 1974. Its chemical formula is Ni2FeBO5 and it is a mineral of the ludwigite group. It usually crystallizes in long, cylindrical prisms that form within another source. It is named after the area of Bon Accord, where it was first found. There have also been findings of bonaccordite within nuclear plants at multiple companies. It builds up a deposit within the machines and is a very hard mineral to clean out because it is resistant to ordinary techniques.
Coloradoite, also known as mercury telluride (HgTe), is a rare telluride ore associated with metallic deposit. Gold usually occurs within tellurides, such as coloradoite, as a high-finess native metal.
Awaruite is a naturally occurring alloy of nickel and iron with a composition from Ni2Fe to Ni3Fe.
In chemistry the term chromite has been used in two contexts. Under IUPAC naming conventions, chromate(III) is preferred to chromite.
The spinels are any of a class of minerals of general formulation AB
2X
4 which crystallise in the cubic (isometric) crystal system, with the X anions arranged in a cubic close-packed lattice and the cations A and B occupying some or all of the octahedral and tetrahedral sites in the lattice. Although the charges of A and B in the prototypical spinel structure are +2 and +3, respectively, other combinations incorporating divalent, trivalent, or tetravalent cations, including magnesium, zinc, iron, manganese, aluminium, chromium, titanium, and silicon, are also possible. The anion is normally oxygen; when other chalcogenides constitute the anion sublattice the structure is referred to as a thiospinel.
Djerfisherite is an alkali copper–iron sulfide mineral and a member of the djerfisherite group.