Olmiite

Last updated
Olmiite
Olmiite-122298.jpg
General
Category Mineral
Formula
(repeating unit)
CaMn2+[SiO3(OH)](OH)
IMA symbol Olm
Strunz classification 09.AF.90
Dana classification78.01.08.02
Crystal system Orthorhombic
Crystal class Dipyramidal
H-M symbol: mmm
(2/m 2/m 2/m)
Space group Pbca
Unit cell 868
Identification
Formula mass 203.44
ColorWhite, brown, pale to intense reddish pink
Cleavage None
Fracture Irregular, Uneven
Tenacity Brittle
Mohs scale hardness5 - 5.5
Luster Vitreous
Streak White
Diaphaneity Transparent, Translucent
Specific gravity 3.05
Density Measured: 3.05
Calculated: 3.102
Optical propertiesBiaxial (+)
Refractive index nα = 1.663(1)
nβ = 1.672(1)
nγ = 1.694(1)
Birefringence 0.031
Pleochroism Non-pleochroic
2V angle Measured: 71°
Calculated: 66°
Dispersion r > v
Distinct
Ultraviolet fluorescence May be deep red fluorescent in shortwave ultraviolet light

Olmiite is a rare calcium-manganese silicate that was named after an Italian mineralogist called Filippo Olmi. It was approved by the IMA in 2006, being first published in 2007, [1] which makes it a relatively newly discovered mineral. [2] Around 2001, a large amount of specimens believed to be poldervaartite was discovered at the N'Chwaning II mine, which is near the Wessels mine, where the latter was discovered. Only later were the researchers able to determine though their investigations that the two minerals are different, as they are visually indistinguishable. Until Renato Pagano acquired and examined the specimens, seemingly no specific investigation was carried out. [3] Olmiite has been misidentified not only once, but twice. The cream-colored specimens were at first thought to be baryte by the mine geologist. [4]

Contents

Properties

Olmiite is the Mn2+ dominant analogue of poldervaartite. [1] It typically has a pinkish core color, caused by manganese coloration, and it typically has a colorless outer rim. [5] Olmiite shows a wide variety of crystal habits. It can crystallize in radiating spheres, meaning it grows into an orb-like shape, forming slender crystals which grow from a central point. It can grow as botryoidal, which are hemispherical masses; acicular, which is a needle-like crystal habit; in stacked crystal plates, and wheat sheaf crystal groups. It can also form individual pyramidal crystals, however, those are uncommon. [2] The aggregates are made of minute crystals. [6] Olmiite aggregates on the market typically reach a few centimeters, and an individual crystal can reach up to 7mms. [7] In nature, specimens can range from thumbnail- to museum-sized slabs covered in olmiite crystals. However, most of the minerals only occur as tiny grains in rocks, which have to be found using a microscope. [5] Olmiite mainly consists of oxygen (39.32%), manganese (22.95%) and calcium (22.65%), but otherwise contains silicon (13.81%), and has a negligible amount of hydrogen (0.99%) and iron (0.27%) in its formula as well. It shows no signs of radioactivity. [8]

Identification

Olmiite forms a solid solution series with the much rarer mineral poldervaartite, meaning they have the same basic chemical formula, but there's an element substitution in one or more atomic sites. [7] As mentioned before, the atomic arrangement of the two are similar, the only difference being is in the case of olmiite, all the Mn cations are ordered on the M2 site, while poldervaartite is Ca dominant at the M2 site, hence the poldervaartite name stays reserved. [6] One would think that its type locality would help in the identification, however, they both can be found in the Wessels mine in South Africa.

A way to differentiate them is that olmiite shows more variety both in color, and in crystal habits. [3] One way to identify it more easily is that the cream-collored olmiite specimens have a deep red fluorescence under shortwave UV light. [4] However, without examining its chemical composition, it is near impossible to identify whether the specimen is an olmiite or a poldervaartite. [2] Hence it must be tested by electron microprobe analysis, as they can only be differentiated by the percentage of calcium versus manganese they contain. Due to the similarities these minerals have, the discovery that most of the poldervaartites on the market are olmiites in fact is quite recent. National Gem Lab further argues that due to the mislabeling of olmiites, it is possible that there's no faceted poldervaartite gemstones in existence. [7] Later analyses also revealed that the two minerals can be intimately intergrown and thus both can occur within one specimen. [4]

Occurences and localities

Olmiite is a product of hydrothermal alteration. [1] As such, it grows in manganese-rich hydrothermal replacement deposits. [2] The crystals form by going though metamorphosis due to the hot hydrothermal fluids passing through a manganese deposit, adding silicon and calcium to the pre-existing elements. [5] To this day, the only known locality of this mineral is in the Kalahari Manganese Field of South Africa. It has been found in both the Wessels Mine in Hotazel and in the N'Chwaning Mines in Kuruman within the Manganese Field's region. It is associated with calcite, manganite, bultfonteinite, oyelite, [2] hematite, celestine, sturmanite, and poldervaartite, [6] baryte, datolite,andradite, thaumasite, caryopilite and gageite. [4] Not only is it a rare mineral, but rare as a gem as well, since most of the crystals are unsuitable for faceting. [7] Due to its softness, it cannot be used in jewelries, so the faceted specimens are made for the collectors. [5]

Notes

    Related Research Articles

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    Tourmaline is a crystalline silicate mineral group in which boron is compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is a gemstone and can be found in a wide variety of colors.

    <span class="mw-page-title-main">Garnet</span> Mineral, semi-precious stone

    Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.

    Prehnite

    Prehnite is an inosilicate of calcium and aluminium with the formula: Ca2Al(AlSi3O10)(OH)2. Limited Fe3+ substitutes for aluminium in the structure. Prehnite crystallizes in the orthorhombic crystal system, and most often forms as stalactitic or botryoidal aggregates, with only just the crests of small crystals showing any faces, which are almost always curved or composite. Very rarely will it form distinct, well-individualized crystals showing a square-like cross-section, including those found at the Jeffrey Mine in Asbestos, Quebec, Canada. Prehnite is brittle with an uneven fracture and a vitreous to pearly luster. Its hardness is 6-6.5, its specific gravity is 2.80-2.90 and its color varies from light green to yellow, but also colorless, blue, pink or white. In April 2000, rare orange prehnite was discovered in the Kalahari Manganese Fields, South Africa. Prehnite is mostly translucent, and rarely transparent.

    <span class="mw-page-title-main">Baryte</span> Barium sulfate mineral

    Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (BaSO4). Baryte is generally white or colorless, and is the main source of the element barium. The baryte group consists of baryte, celestine (strontium sulfate), anglesite (lead sulfate), and anhydrite (calcium sulfate). Baryte and celestine form a solid solution (Ba,Sr)SO4.

    Axinite

    Axinite is a brown to violet-brown, or reddish-brown bladed group of minerals composed of calcium aluminium boro-silicate, (Ca,Fe,Mn)3Al2BO3Si4O12OH. Axinite is pyroelectric and piezoelectric.

    Rhodochrosite Mineral of manganese carbonate

    Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its (rare) pure form, it is typically a rose-red color, but impure specimens can be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4. Its specific gravity is between 3.5 and 3.7. It crystallizes in the trigonal system, and cleaves with rhombohedral carbonate cleavage in three directions. Crystal twinning often is present. It is transparent to translucent with refractive indices of =1.814 to 1.816, =1.596 to 1.598. It is often confused with the manganese silicate, rhodonite, but is distinctly softer. It is officially listed as one of the National symbols of Argentina.

    Rhodonite Single chain manganese inosilicate (MnSiO3)

    Rhodonite is a manganese inosilicate, (Mn, Fe, Mg, Ca)SiO3 and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (the name comes from the Greek ῥόδος rhodos, rosy), often tending to brown because of surface oxidation.

    <span class="mw-page-title-main">Phenakite</span>

    Phenakite or phenacite is a fairly rare nesosilicate mineral consisting of beryllium orthosilicate, Be2SiO4. Occasionally used as a gemstone, phenakite occurs as isolated crystals, which are rhombohedral with parallel-faced hemihedrism, and are either lenticular or prismatic in habit: the lenticular habit is determined by the development of faces of several obtuse rhombohedra and the absence of prism faces. There is no cleavage, and the fracture is conchoidal. The Mohs hardness is high, being 7.5 – 8; the specific gravity is 2.96. The crystals are sometimes perfectly colorless and transparent, but more often they are greyish or yellowish and only translucent; occasionally they are pale rose-red. In general appearance the mineral is not unlike quartz, for which indeed it has been mistaken. Its name comes from Ancient Greek: φέναξ, romanized: phénax, meaning "deceiver" due to its close visual similarity to quartz, named by Nils Gustaf Nordenskiöld in 1833.

    Tsavorite Variety of grossular

    Tsavorite or tsavolite is a variety of the garnet group species grossular, a calcium-aluminium garnet with the formula Ca3Al2Si3O12. Trace amounts of vanadium or chromium provide the green color.

    Clinohumite Nesosilicate mineral

    Clinohumite is an uncommon member of the humite group, a magnesium silicate according to the chemical formula (Mg, Fe)9(SiO4)4(F,OH)2. The formula can be thought of as four olivine (Mg2SiO4), plus one brucite (Mg(OH)2). Indeed, the mineral is essentially a hydrated olivine and occurs in altered ultramafic rocks and carbonatites. Most commonly found as tiny indistinct grains, large euhedral clinohumite crystals are sought by collectors and occasionally fashioned into bright, yellow-orange gemstones. Only two sources of gem-quality material are known: the Pamir Mountains of Tajikistan, and the Taymyr region of northern Siberia. It is one of two humite group minerals that have been cut into gems, the other being the much more common chondrodite.

    Hausmannite

    Hausmannite is a complex oxide of manganese containing both di- and tri-valent manganese. The formula can be represented as Mn2+Mn3+2O4. It belongs to the spinel group and forms tetragonal crystals. Hausmannite is a brown to black metallic mineral with Mohs hardness of 5.5 and a specific gravity of 4.8.

    Bixbyite Manganese iron oxide mineral

    Bixbyite is a manganese iron oxide mineral with chemical formula: (Mn,Fe)2O3. The iron/manganese ratio is quite variable and many specimens have almost no iron. It is a metallic dark black with a Mohs hardness of 6.0 - 6.5. It is a somewhat rare mineral sought after by collectors as it typically forms euhedral isometric crystals exhibiting various cubes, octahedra, and dodecahedra.

    Todorokite Hydrous manganese oxide mineral

    Todorokite is a rare complex hydrous manganese oxide mineral with the chemical formula (Na,Ca,K,Ba,Sr)
    1-x
    (Mn,Mg,Al)
    6
    O
    12
    ·3-4H
    2
    O
    . It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but the angle β between the a and c axes is close to 90°, making it seem orthorhombic. It is a brown to black mineral which occurs in massive or tuberose forms. It is quite soft with a Mohs hardness of 1.5, and a specific gravity of 3.49 - 3.82. It is a component of deep ocean basin manganese nodules.

    <span class="mw-page-title-main">Bromellite</span>

    Bromellite, whose name derives from the Swedish chemist Magnus von Bromell (1670–1731), is a white oxide mineral, found in complex pegmatitic manganese-iron deposits, but is more frequently made synthetically. This is a rare mineral to encounter in its natural state, but it has been made synthetically for over 40 years.

    Jeremejevite

    Jeremejevite is an aluminium borate mineral with variable fluoride and hydroxide ions. Its chemical formula is Al6B5O15(F,OH)3. It is considered as one of the rarest, thus one of the most expensive stones. For nearly a century, it was considered as one of the rarest gemstones in the world.

    Nambulite

    Nambulite is a lithium bearing manganese silicate mineral with the chemical formula (Li,Na)Mn4Si5O14(OH). It is named after the mineralogist, Matsuo Nambu (born 1917) of Tohoko University, Japan, who is known for his research in manganese minerals. The mineral was first discovered in the Funakozawa Mine of northeastern Japan, a metasedimentary manganese ore.

    Manganvesuvianite

    Manganvesuvianite is a rare mineral with formula Ca19Mn3+(Al,Mn3+,Fe3+)10(Mg,Mn2+)2(Si2O7)4(SiO4)10O(OH)9. The mineral is red to nearly black in color. Discovered in South Africa and described in 2002, it was so named for the prevalence of manganese in its composition and its relation to vesuvianite.

    Charlesite

    Charlesite is a sulfate mineral of the ettringite group. Charlesite was named in 1945 after Dr. Charles Palache mineralogist and professor at Harvard University for his work on minerals. This mineral is extremely rare, and when it is found it is often in crystal form. Its crystals are soft hexagonal, that can vary in color. Colors can range from clear to white, or even a pale yellow or pink. The brittle mineral's Mohs hardness is 2.5 with a specific gravity of 1.79. Though transparent to the eye the mineral has a white streak.

    <span class="mw-page-title-main">Sturmanite</span>

    Sturmanite is a rare sulfate mineral with the chemical formula Ca6Fe3+2(SO4)2.5(B(OH)4)(OH)12 · 25 H2O. It crystallises in the tetragonal system and it has a Moh's hardness of 2.5. Sturmanite has a bright yellow to amber colour and falls in the ettringite group. It was named after Bozidar Darko Sturman (born 1937), Croatian-Canadian mineralogist and Curator Emeritus of Mineralogy, Royal Ontario Museum.

    Inesite

    Inesite is a hydrous calcium manganese silicate mineral. Its chemical formula is Ca2Mn7Si10O28(OH)2•5(H2O). Inesite is an inosilicate with a triclinic crystal system. It has a Mohs hardness of 5.5 to 6, and a specific gravity of 3.0. Its name originates from the Greek Ίνες (ines), "fibers" in allusion to its color and habit.

    References

    1. 1 2 3 "Olmiite". www.mindat.org. Retrieved 2022-08-29.
    2. 1 2 3 4 5 "Olmiite: The mineral olmiite information and pictures". www.minerals.net. Retrieved 2022-08-29.
    3. 1 2 Pagano, Renato; Guastoni, Alessandro; Pezzotta, Federico (2008-09-01). "Olmiite and poldervaartite from the Kalahari manganese field northern cape province republic of South Africa". The Mineralogical Record. 39 (5): 373–382.
    4. 1 2 3 4 Cairncross, Bruce (2022-06-01). Minerals & Gemstones of Southern Africa. Penguin Random House South Africa. ISBN   978-1-77584-754-0.
    5. 1 2 3 4 "The Earth Story". The Earth Story. Retrieved 2022-08-29.
    6. 1 2 3 "Olmiite, CaMn[SiO3(OH)](OH), the Mn-dominant analogue of poldervaartite, a new mineral species from Kalahari manganese fields (Republic of South Africa)". pubs.geoscienceworld.org. Retrieved 2022-08-29.
    7. 1 2 3 4 "Olmiite". National Gem Lab. 2017-03-18. Retrieved 2022-08-29.
    8. "Olmiite Mineral Data". webmineral.com. Retrieved 2022-08-29.