Olmiite | |
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General | |
Category | Mineral |
Formula (repeating unit) | CaMn2+[SiO3(OH)](OH) |
IMA symbol | Olm |
Strunz classification | 09.AF.90 |
Dana classification | 78.01.08.02 |
Crystal system | Orthorhombic |
Crystal class | Dipyramidal H-M symbol: mmm (2/m 2/m 2/m) |
Space group | Pbca |
Unit cell | 868 |
Identification | |
Formula mass | 203.44 |
Color | White, brown, pale to intense reddish pink |
Cleavage | None |
Fracture | Irregular, uneven |
Tenacity | Brittle |
Mohs scale hardness | 5 - 5.5 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent, translucent |
Specific gravity | 3.05 |
Density | Measured: 3.05 Calculated: 3.102 |
Optical properties | Biaxial (+) |
Refractive index | nα = 1.663(1) nβ = 1.672(1) nγ = 1.694(1) |
Birefringence | 0.031 |
Pleochroism | Non-pleochroic |
2V angle | Measured: 71° Calculated: 66° |
Dispersion | r > v Distinct |
Ultraviolet fluorescence | May be deep red fluorescent in shortwave ultraviolet light |
Olmiite is a rare calcium-manganese silicate that was named after an Italian mineralogist called Filippo Olmi. It was approved by the IMA in 2006, being first published in 2007, [1] which makes it a relatively newly discovered mineral. [2] Around 2001, a large amount of specimens believed to be poldervaartite was discovered at the N'Chwaning II mine, which is near the Wessels mine, where the latter was discovered. Only later were the researchers able to determine through their investigations that the two minerals are different, as they are visually indistinguishable. Until Renato Pagano acquired and examined the specimens, seemingly no specific investigation was carried out. [3] Olmiite has been misidentified not only once, but twice. The cream-colored specimens were at first thought to be baryte by the mine geologist. [4]
Olmiite is the Mn2+ dominant analogue of poldervaartite. [1] It typically has a pinkish core color, caused by manganese coloration, and it typically has a colorless outer rim. [5] Olmiite shows a wide variety of crystal habits. It can crystallize in radiating spheres, meaning it grows into an orb-like shape, forming slender crystals which grow from a central point. It can grow as botryoidal, which are hemispherical masses; acicular, which is a needle-like crystal habit; in stacked crystal plates, and wheat sheaf crystal groups. It can also form individual pyramidal crystals, however, those are uncommon. [2] The aggregates are made of minute crystals. [6] Olmiite aggregates on the market typically reach a few centimeters, and an individual crystal can reach up to 7mms. [7] In nature, specimens can range from thumbnail- to museum-sized slabs covered in olmiite crystals. However, most of the minerals only occur as tiny grains in rocks, which have to be found using a microscope. [5] Olmiite mainly consists of oxygen (39.32%), manganese (22.95%) and calcium (22.65%), but otherwise contains silicon (13.81%), and has a negligible amount of hydrogen (0.99%) and iron (0.27%) in its formula as well. It shows no signs of radioactivity. [8]
Olmiite forms a solid solution series with the much rarer mineral poldervaartite, meaning they have the same basic chemical formula, but there's an element substitution in one or more atomic sites. [7] As mentioned before, the atomic arrangement of the two are similar, the only difference being is in the case of olmiite, all the Mn cations are ordered on the M2 site, while poldervaartite is Ca dominant at the M2 site, hence the poldervaartite name stays reserved. [6] One would think that its type locality would help in the identification, however, they both can be found in the Wessels mine in South Africa.
A way to differentiate them is that olmiite shows more variety both in color, and in crystal habits. [3] One way to identify it more easily is that the cream-colored olmiite specimens have a deep red fluorescence under shortwave UV light. [4] However, without examining its chemical composition, it is near impossible to identify whether the specimen is an olmiite or a poldervaartite. [2] Hence it must be tested by electron microprobe analysis, as they can only be differentiated by the percentage of calcium versus manganese they contain. Due to the similarities these minerals have, the discovery that most of the poldervaartites on the market are olmiites in fact is quite recent. National Gem Lab further argues that due to the mislabeling of olmiites, it is possible that there's no faceted poldervaartite gemstones in existence. [7] Later analyses also revealed that the two minerals can be intimately intergrown and thus both can occur within one specimen. [4]
Olmiite is a product of hydrothermal alteration. [1] As such, it grows in manganese-rich hydrothermal replacement deposits. [2] The crystals form by going though metamorphosis due to the hot hydrothermal fluids passing through a manganese deposit, adding silicon and calcium to the pre-existing elements. [5] To this day, the only known locality of this mineral is in the Kalahari Manganese Field of South Africa. It has been found in both the Wessels Mine in Hotazel and in the N'Chwaning Mines in Kuruman within the Manganese Field's region. It is associated with calcite, manganite, bultfonteinite, oyelite, [2] hematite, celestine, sturmanite, and poldervaartite, [6] baryte, datolite,andradite, thaumasite, caryopilite and gageite. [4] Not only is it a rare mineral, but rare as a gem as well, since most of the crystals are unsuitable for faceting. [7] Due to its softness, it cannot be used in jewelries, so the faceted specimens are made for the collectors. [5]
A gemstone is a piece of mineral crystal which, when cut or polished, is used to make jewelry or other adornments. Certain rocks and occasionally organic materials that are not minerals may also be used for jewelry and are therefore often considered to be gemstones as well. Most gemstones are hard, but some softer minerals such as brazilianite may be used in jewelry because of their color or luster or other physical properties that have aesthetic value. However, generally speaking, soft minerals are not typically used as gemstones by virtue of their brittleness and lack of durability.
Topaz is a silicate mineral made of aluminum and fluorine with the chemical formula Al2SiO4(F, OH)2. It is used as a gemstone in jewelry and other adornments. Common topaz in its natural state is colorless, though trace element impurities can make it pale blue or golden brown to yellow-orange. Topaz is often treated with heat or radiation to make it a deep blue, reddish-orange, pale green, pink, or purple.
Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
Baryte, barite or barytes ( BARR-eyet, BAIR- or bə-RYTE-eez) is a mineral consisting of barium sulfate (BaSO4). Baryte is generally white or colorless, and is the main source of the element barium. The baryte group consists of baryte, celestine (strontium sulfate), anglesite (lead sulfate), and anhydrite (calcium sulfate). Baryte and celestine form a solid solution (Ba,Sr)SO4.
Axinite is a brown to violet-brown, or reddish-brown bladed group of minerals composed of calcium aluminium boro-silicate, (Ca,Fe,Mn)3Al2BO3Si4O12OH. Axinite is pyroelectric and piezoelectric.
Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its pure form (rare), it is typically a rose-red colour, but it can also be shades of pink to pale brown. It streaks white, and its Mohs hardness varies between 3.5 and 4.5. Its specific gravity is between 3.45 and 3.6. The crystal system of rhodochrosite is trigonal, with a structure and cleavage in the carbonate rhombohedral system. The carbonate ions (CO2−
3) are arranged in a triangular planar configuration, and the manganese ions (Mn2+) are surrounded by six oxygen ions in an octahedral arrangement. The MnO6 octahedra and CO3 triangles are linked together to form a three-dimensional structure. Crystal twinning is often present. It can be confused with the manganese silicate rhodonite, but is distinctly softer. Rhodochrosite is formed by the oxidation of manganese ore, and is found in South Africa, China, and the Americas. It is one of the national symbols of Argentina and the state of Colorado.
Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from Ancient Greek ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).
Phenakite or phenacite is a fairly rare nesosilicate mineral consisting of beryllium orthosilicate, Be2SiO4. Occasionally used as a gemstone, phenakite occurs as isolated crystals, which are rhombohedral with parallel-faced hemihedrism, and are either lenticular or prismatic in habit: the lenticular habit is determined by the development of faces of several obtuse rhombohedra and the absence of prism faces. There is no cleavage, and the fracture is conchoidal. The Mohs hardness is high, being 7.5–8; the specific gravity is 2.96. The crystals are sometimes perfectly colorless and transparent, but more often they are greyish or yellowish and only translucent; occasionally they are pale rose-red. In general appearance the mineral is not unlike quartz, for which indeed it has been mistaken. Its name comes from Ancient Greek: φέναξ, romanized: phénax, meaning "deceiver" due to its close visual similarity to quartz, named by Nils Gustaf Nordenskiöld in 1833.
Tsavorite or tsavolite is a variety of the garnet group species grossular, a calcium-aluminium garnet with the formula Ca3Al2Si3O12. Trace amounts of vanadium or chromium provide the green color.
Clinohumite is an uncommon member of the humite group, a magnesium silicate according to the chemical formula (Mg, Fe)9(SiO4)4(F,OH)2. The formula can be thought of as four olivine (Mg2SiO4), plus one brucite (Mg(OH)2). Indeed, the mineral is essentially a hydrated olivine and occurs in altered ultramafic rocks and carbonatites. Most commonly found as tiny indistinct grains, large euhedral clinohumite crystals are sought by collectors and occasionally fashioned into bright, yellow-orange gemstones. Only two sources of gem-quality material are known: the Pamir Mountains of Tajikistan, and the Taymyr region of northern Siberia. It is one of two humite group minerals that have been cut into gems, the other being the much more common chondrodite.
Hausmannite is a complex oxide, or a mixed oxide, of manganese containing both di- and tri-valent manganese. Its chemical formula can be represented as MnIIMnIII2O4, or more simply noted as MnO·Mn2O3, or Mn3O4, as commonly done for magnetite, the corresponding iron oxide. It belongs to the spinel group and forms tetragonal crystals. Hausmannite is a brown to black metallic mineral with Mohs hardness of 5.5 and a specific gravity of 4.8.
Bixbyite is a manganese iron oxide mineral with chemical formula: (Mn,Fe)2O3. The iron/manganese ratio is quite variable and many specimens have almost no iron. It is a metallic dark black with a Mohs hardness of 6.0 – 6.5. It is a somewhat rare mineral sought after by collectors as it typically forms euhedral isometric crystals exhibiting various cubes, octahedra, and dodecahedra.
Jeremejevite is an aluminium borate mineral with variable fluoride and hydroxide ions. Its chemical formula is Al6B5O15(F,OH)3. It is considered as one of the rarest, thus one of the most expensive stones. For nearly a century, it was considered as one of the rarest gemstones in the world.
Manganvesuvianite is a rare mineral with formula Ca19Mn3+(Al,Mn3+,Fe3+)10(Mg,Mn2+)2(Si2O7)4(SiO4)10O(OH)9. The mineral is red to nearly black in color. Discovered in South Africa and described in 2002, it was so named for the prevalence of manganese in its composition and its relation to vesuvianite.
The N'chwaning mine are located in the Northern Cape Province of South Africa. N'chwaning has one of the largest manganese reserves in South Africa having estimated reserves of 323.2 million tonnes of manganese ore grading 42.5% manganese. There are three shafts, designated as N'Chwaning, N'Chwaning II and N'Chwaning III. The majority of the major mineral finds documented originate from the N'Chwaning II shaft.
Charlesite is a sulfate mineral of the ettringite group. Charlesite was named in 1945 after Dr. Charles Palache mineralogist and professor at Harvard University for his work on minerals. This mineral is extremely rare, and when it is found it is often in crystal form. Its crystals are soft hexagonal, that can vary in color. Colors can range from clear to white, or even a pale yellow or pink. The brittle mineral's Mohs hardness is 2.5 with a specific gravity of 1.79. Though transparent to the eye the mineral has a white streak.
Sturmanite is a rare sulfate mineral with the chemical formula Ca6Fe3+2(SO4)2.5(B(OH)4)(OH)12 · 25 H2O. It crystallises in the tetragonal system and it has a Moh's hardness of 2.5. Sturmanite has a bright yellow to amber colour and falls in the ettringite group. It was named after Bozidar Darko Sturman (born 1937), Croatian-Canadian mineralogist and Curator Emeritus of Mineralogy, Royal Ontario Museum.
Inesite is a hydrous calcium manganese silicate mineral. Its chemical formula is Ca2Mn7Si10O28(OH)2•5(H2O). Inesite is an inosilicate with a triclinic crystal system. It has a Mohs hardness of 5.5 to 6, and a specific gravity of 3.0. Its name originates from the Greek Ίνες (ines), "fibers" in allusion to its color and habit.
Red beryl, formerly known as bixbite and marketed as red emerald or scarlet emerald, is an extremely rare variety of beryl as well as one of the rarest minerals on Earth. The gem gets its red color from manganese ions embedded inside of beryllium aluminium cyclosilicate crystals. The color of red beryl is stable up to 1,000 °C (1,830 °F). Red beryl can come in various tints like strawberry, bright ruby, cherry, and orange.
Queitite is a lead zinc silicate sulphate that was named after the mineral dealer Clive S. Queit, who collected the first specimens. It got approved by the IMA in 1979, and it is an extremely rare secondary mineral.
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