An Oxyliquit, also called liquid air explosive or liquid oxygen explosive, is an explosive material which is a mixture of liquid oxygen (LOX) with a suitable fuel, such as carbon (as lampblack), or an organic chemical (e.g. a mixture of soot and naphthalene), wood meal, or aluminium powder or sponge. It is a class of Sprengel explosives.
Oxyliquits have numerous advantages. They are inexpensive to make, can be initiated by a safety fuse, and in case of a misfire, the oxygen evaporates quickly, rendering the charge quite safe in a short period of time. The first large scale deployment took place in 1899 during the building of the Simplon Tunnel, in the form of cartridges filled with diatomaceous earth soaked with petroleum, or an absorbent cork charcoal, dipped in liquid oxygen immediately before use. In another modification, the cartridge is filled with liquid oxygen after placement in the borehole.
One of the disadvantages of oxyliquits is that, once mixed, they are sensitive to sparks, shock, and heat, in addition to reported cases of spontaneous ignition. The power relative to weight is high, but the density is low, so the brisance is low as well. Ignition by a fuse alone is sometimes unreliable. The charge should be detonated within 5 minutes of soaking, but even after 15 minutes it may be capable of exploding, even though weaker and with production of carbon dioxide.
An oxyliquit explosion can be accidentally produced while filling high-altitude aircraft systems. When liquid oxygen is spilled on tarmac (asphalt) the pavement can become sufficiently explosive to be set off simply by walking on it, even though the oxygen evaporates shortly after it is spilled.[ citation needed ]
At first, liquid air, self-enriched by standing (nitrogen has a lower boiling point and evaporates preferentially) was used, but pure liquid oxygen gives better results.
A mixture of lampblack and liquid oxygen was measured to have a detonation velocity of 3,000 m/s, and 4 to 12% more explosive power than dynamite. The long duration of the flame it produced, however, made it unsafe for use in the presence of explosive gases. Therefore, oxyliquits were mostly used in open quarries and strip mines.
The explosive properties of these mixtures were discovered in Germany in 1895 by Prof. Carl von Linde, a developer of a successful machine for liquefaction of gases, who named them oxyliquits.
In 1930, over 3 million pounds (1.4×10 6 kg) of liquid oxygen were used for this purpose in Germany alone, and additional 201,466 lb (91,383 kg) were consumed by British quarries. The accident rate was lower than with conventional explosives. However, the Dewar flasks the LOX was stored in occasionally exploded, which was caused by iron impurities in the activated carbon serving as trace gas absorbent in the insulation vacuum layer in the flask, which caused spontaneous ignition in case of LOX leak into the enclosed space.
Use of oxyliquits during World War II was low, as there was a plentiful supply of nitrates obtained from synthetic ammonia.
Due to the complicated machinery required for manufacture of liquid oxygen, oxyliquit explosives were used mostly only where their consumption was high. In the United States, some such locations were the strip mines in coal mining areas of the Midwest. Its consumption peaked in 1953 with 10,190 tons[ vague ], but then decreased to zero in 1968, when it was entirely replaced with the cheaper ANFO.
Oxyliquit explosive was prepared ad hoc from sugar and liquid oxygen from an oxygen bottle to blast a hole in a collapsed cave in Stanisław Lem's 1951 novel The Astronauts . The same device was used in Andy Weir's novel The Martian and the movie adaptation to cause the intentional depressurization of a spaceship by blasting the airlock door.
In physics, cryogenics is the production and behaviour of materials at very low temperatures.
An explosive is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances.
Thermite is a pyrotechnic composition of metal powder and metal oxide. When ignited by heat or chemical reaction, thermite undergoes an exothermic reduction-oxidation (redox) reaction. Most varieties are not explosive, but can create brief bursts of heat and high temperature in a small area. Its form of action is similar to that of other fuel-oxidizer mixtures, such as black powder.
Liquid hydrogen (LH2 or LH2) is the liquid state of the element hydrogen. Hydrogen is found naturally in the molecular H2 form.
A detonator, frequently a blasting cap, is a device used to trigger an explosive device. Detonators can be chemically, mechanically, or electrically initiated, the last two being the most common.
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other.
A rebreather is a breathing apparatus that absorbs the carbon dioxide of a user's exhaled breath to permit the rebreathing (recycling) of the substantially unused oxygen content, and unused inert content when present, of each breath. Oxygen is added to replenish the amount metabolised by the user. This differs from open-circuit breathing apparatus, where the exhaled gas is discharged directly into the environment. The purpose is to extend the breathing endurance of a limited gas supply, and, for covert military use by frogmen or observation of underwater life, eliminating the bubbles produced by an open circuit system and in turn not scaring wildlife being filmed. A rebreather is generally understood to be a portable unit carried by the user. The same technology on a vehicle or non-mobile installation is more likely to be referred to as a life-support system.
Potassium chlorate is a compound containing potassium, chlorine and oxygen, with the molecular formula KClO3. In its pure form, it is a white crystalline substance. After sodium chlorate, it is the second most common chlorate in industrial use. It is a strong oxidizing agent and its most important application is in safety matches. In other applications it is mostly obsolete and has been replaced by safer alternatives in recent decades. It has been used
Liquid oxygen—abbreviated LOx, LOX or Lox in the aerospace, submarine and gas industries—is the liquid form of molecular oxygen. It was used as the oxidizer in the first liquid-fueled rocket invented in 1926 by Robert H. Goddard, an application which has continued to the present.
The autoignition temperature or kindling point of a substance is the lowest temperature in which it spontaneously ignites in a normal atmosphere without an external source of ignition, such as a flame or spark. This temperature is required to supply the activation energy needed for combustion. The temperature at which a chemical ignites decreases as the pressure is increased.
RP-1 (alternatively, Rocket Propellant-1 or Refined Petroleum-1) is a highly refined form of kerosene outwardly similar to jet fuel, used as rocket fuel. RP-1 provides a lower specific impulse than liquid hydrogen (LH2), but is cheaper, is stable at room temperature, and presents a lower explosion hazard. RP-1 is far denser than LH2, giving it a higher energy density (though its specific energy is lower). RP-1 also has a fraction of the toxicity and carcinogenic hazards of hydrazine, another room-temperature liquid fuel.
A liquid-propellant rocket or liquid rocket utilizes a rocket engine that uses liquid propellants. Liquids are desirable because they have a reasonably high density and high specific impulse (Isp). This allows the volume of the propellant tanks to be relatively low. It is also possible to use lightweight centrifugal turbopumps to pump the rocket propellant from the tanks into the combustion chamber, which means that the propellants can be kept under low pressure. This permits the use of low-mass propellant tanks that do not need to resist the high pressures needed to store significant amounts of gasses, resulting in a low mass ratio for the rocket.
Bottled gas is a term used for substances which are gaseous at standard temperature and pressure (STP) and have been compressed and stored in carbon steel, stainless steel, aluminum, or composite bottles known as gas cylinders.
The fire triangle or combustion triangle is a simple model for understanding the necessary ingredients for most fires.
The highest specific impulse chemical rockets use liquid propellants. They can consist of a single chemical or a mix of two chemicals, called bipropellants. Bipropellants can further be divided into two categories; hypergolic propellants, which ignite when the fuel and oxidizer make contact, and non-hypergolic propellants which require an ignition source.
Mixtures of dispersed combustible materials and oxygen in the air will burn only if the fuel concentration lies within well-defined lower and upper bounds determined experimentally, referred to as flammability limits or explosive limits. Combustion can range in violence from deflagration through detonation.
Panclastites are a class of Sprengel explosives similar to oxyliquits. They were first suggested in 1881 by Eugène Turpin, a French chemist. They are a mixture of liquid dinitrogen tetroxide serving as oxidizer with a suitable fuel, e.g. carbon disulfide, in the 3:2 volume ratio. Other fuel being used is nitrobenzene. Possible alternative fuels are e.g. nitrotoluene, gasoline, nitromethane, or halocarbons.
The YF-75 is a liquid cryogenic rocket engine burning liquid hydrogen and liquid oxygen in a gas generator cycle. It is China's second generation of cryogenic propellant engine, after the YF-73, which it replaced. It is used in a dual engine mount in the H-18 third stage of the Long March 3A, Long March 3B and Long March 3C launch vehicles. Within the mount, each engine can gimbal individually to enable thrust vectoring control. The engine also heats hydrogen and helium to pressurize the stage tanks and can control the mixture ratio to optimize propellant consumption.
Rocket propellant is the reaction mass of a rocket. This reaction mass is ejected at the highest achievable velocity from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines.
A Diving rebreather is an underwater breathing apparatus that absorbs the carbon dioxide of a diver's exhaled breath to permit the rebreathing (recycling) of the substantially unused oxygen content, and unused inert content when present, of each breath. Oxygen is added to replenish the amount metabolised by the diver. This differs from open-circuit breathing apparatus, where the exhaled gas is discharged directly into the environment. The purpose is to extend the breathing endurance of a limited gas supply, and, for covert military use by frogmen or observation of underwater life, to eliminate the bubbles produced by an open circuit system. A diving rebreather is generally understood to be a portable unit carried by the user, and is therefore a type of self-contained underwater breathing apparatus (scuba). A semi-closed rebreather carried by the diver may also be known as a gas extender. The same technology on a submersible or surface installation is more likely to be referred to as a life-support system.