Potassic-magnesio-fluoro-arfvedsonite

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Potassic-magnesio-fluoro-arfvedsonite
General
Category Silicate
Formula
(repeating unit)
[(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]
IMA symbol Pmfarf [1]
Crystal system Monoclinic
Crystal class 2/m - Prismatic
Space group C2/m
Identification
ColorBluish-Gray
Twinning Common on TL, as simple or lamellar (ll57A) on {100}
Cleavage Perfect on {110}
Fracture Splintery
Tenacity Brittle
Mohs scale hardness6
Lustre Vitreous
Streak White
Specific gravity 3.174 g/cm3
Optical propertiesBiaxial Negative
Ultraviolet fluorescence None
References [2] [3]

[4]

[1]

Potassic-magnesio-fluoro-arfvedsonite is an amphibole mineral first discovered in Quebec, Canada, [2] [3] in an area which is part of the Canadian Shield which is where some of the oldest exposed rocks are that can date back to over 4 billion years ago. Potassic-magnesio-fluoro-arfvedsonite is also the mineral with the longest name of any mineral with 34 letters and 37 characters.

Contents

Occurrence

Potassic-magnesio-fluoro-arfvedsonite is found in igneous rocks. The rocks it is found in are classified as a complex mafic ultrapotassic peralkaline igneous rock with high silica contents. Most commonly it is found with Lamproite. Potassic-magnesio-fluoro-arfvedsonite is a uniquely rare mineral, as it occurs in small amounts in very few locations around the world. [4]

Physical properties

Potassic-magnesio-fluoro-arfvedsonite is a bluish-gray mineral with a vitreous luster. It exhibits a hardness of 6 on the Mohs hardness scale. It leaves a white streak of powder behind when you rub it against another surface. Potassic-magnesio-fluoro-arfvedsonite shows perfect cleavage along the {110} plane. The calculated density is 3.174 g/cm3. [2]

Age

Potassic-magnesio-fluoro-arfvedsonite has only been found in a handful of regions. These regions are Quebec, Canada, Montepuez District, Mozambique, Troms Og Finnmark, Norway, Dakhla-Oued Ed-Dahab. Morocco, and Las Vegas, USA. One thing all these locations have in common is the rock formations are older rocks that range from the late Archean eon to the Proterozoic. This range goes from around 2.5 billion years ago to 538 million years ago.

Name

When potassic-magnesio-fluoro-arfevdsonite was first discovered in Quebec in 1985 it was named Potassium fluor-magnesio-arfvedsonite. It was seen as a potassium rich fluor-magnesio-arfvedsonite (now renamed magnesio-fluoro-arfvedsonite). In 2006 it was renamed by the IMA as fluoro-potassic-magnesio-arfvedsonite. and later in 2012 it was renamed again as potassic-magnesio-fluoro-arfvedsonite. [4] It has this name as it is an arfvedsonite that has magnesium, potassium, and fluorine. Potassic-magnesio-fluoro-arfvedsonite has 37 characters which is the longest for any approved mineral. [5]

Chemical composition

Oxidewt%
SiO254.25
TiO21.08
Al2O30.03
Cr2O3n.a.
Fe2O38.07
FeO13.23<FeOtot<14.52
MnO0.32
ZnO0.05
MgO13.99
BaO+SrOn.a.
CaO1.16
Na2O6.33
K2O5.20
H2O0.74
F2.20
–O=F-0.93
Total99.18

X-ray diffraction and Crystallography

FaceD(Å)
1108.539
1313.412
2403.298
3103.183
3312.759
1512.718
2602.551
3512.352
3312.269

The X ray diffraction of potassic-magnesio-fluoro-arfevsonite gave values of the chart above. Calculated unit cell dimensions are a = 9.9591(4), b = 17.9529(7), c = 5.2867(2) Å, β = 104.340(1)°, V = 919.73(10) Å3, Z = 2. Potassic-magnesio-fluoro-arfvedsonite is part of the monoclinic crystal system and in the space group C2/m. Potassic-magnesio-fluoro-arfvedsonite is a double chain inosilicate. [4]

Related Research Articles

<span class="mw-page-title-main">Hornblende</span> Complex inosilicate series of minerals

Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

<span class="mw-page-title-main">Orthoclase</span> Tectosilicate mineral found in igneous rock

Orthoclase, or orthoclase feldspar (endmember formula KAlSi3O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture", because its two cleavage planes are at right angles to each other. It is a type of potassium feldspar, also known as K-feldspar. The gem known as moonstone (see below) is largely composed of orthoclase.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Phlogopite</span> Member of the mica family of phyllosilicates

Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica.

<span class="mw-page-title-main">Tremolite</span> Amphibole, double chain inosilicate mineral

Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro-actinolite. Pure magnesium tremolite is creamy white, but the color grades to dark green with increasing iron content. It has a hardness on Mohs scale of 5 to 6. Nephrite, one of the two minerals known as the gemstone jade, is a green variety of tremolite.

<span class="mw-page-title-main">Riebeckite</span> Sodium-rich member of the amphibole group of silicate minerals

Riebeckite is a sodium-rich member of the amphibole group of silicate minerals, chemical formula Na2(Fe2+3Fe3+2)Si8O22(OH)2. It forms a solid solution series with magnesioriebeckite. It crystallizes in the monoclinic system, usually as long prismatic crystals showing a diamond-shaped cross section, but also in fibrous, bladed, acicular, columnar, and radiating forms. Its Mohs hardness is 5.0–6.0, and its specific gravity is 3.0–3.4. Cleavage is perfect, two directions in the shape of a diamond; fracture is uneven, splintery. It is often translucent to nearly opaque.

<span class="mw-page-title-main">Cummingtonite</span> Silicate mineral

Cummingtonite is a metamorphic amphibole with the chemical composition (Mg,Fe2+
)
2
(Mg,Fe2+
)
5
Si
8
O
22
(OH)
2
, magnesium iron silicate hydroxide.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Arfvedsonite</span> Sodium amphibole mineral

Arfvedsonite or soda hornblende (partiellement obsolète) is a sodium amphibole mineral with composition: [Na][Na2][(Fe2+)4Fe3+][(OH)2|Si8O22]. It crystallizes in the monoclinic prismatic crystal system and typically occurs as greenish black to bluish grey fibrous to radiating or stellate prisms.

<span class="mw-page-title-main">Aegirine</span> Member of the clinopyroxene group of inosilicate mineral

Aegirine is a member of the clinopyroxene group of inosilicate minerals. It is the sodium endmember of the aegirine–augite series. It has the chemical formula NaFeSi2O6, in which the iron is present as the ion Fe3+. In the aegirine–augite series, the sodium is variably replaced by calcium with iron(II) and magnesium replacing the iron(III) to balance the charge. Aluminum also substitutes for the iron(III). Acmite is a fibrous green-colored variety.

<span class="mw-page-title-main">Sperrylite</span>

Sperrylite is a platinum arsenide mineral with the chemical formula PtAs2 and is an opaque metallic tin white mineral which crystallizes in the isometric system with the pyrite group structure. It forms cubic, octahedral or pyritohedral crystals in addition to massive and reniform habits. It has a Mohs hardness of 6–7 and a very high specific gravity of 10.6.

<span class="mw-page-title-main">Ultrapotassic igneous rocks</span> Class of rare ultramafic or mafic igneous rocks rich in potassium

Ultrapotassic igneous rocks are a class of rare, volumetrically minor, generally ultramafic or mafic silica-depleted igneous rocks.

<span class="mw-page-title-main">Tschermakite</span> Amphibole, double chain inosilicate mineral

The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.

<span class="mw-page-title-main">Richterite</span> Sodium amphibole mineral

Richterite is a sodium calcium magnesium silicate mineral belonging to the amphibole group. If iron replaces the magnesium within the structure of the mineral, it is called ferrorichterite; if fluorine replaces the hydroxyl, it is called fluororichterite. Richterite crystals are long and prismatic, or prismatic to fibrous aggregate, or rock-bound crystals. Colors of richterite range from brown, grayish-brown, yellow, brownish- to rose-red, or pale to dark green. Richterite occurs in thermally metamorphosed limestones in contact metamorphic zones. It also occurs as a hydrothermal product in mafic igneous rocks, and in manganese-rich ore deposits. Localities include Mont-Saint-Hilaire, Quebec, and Wilberforce and Tory Hill, Ontario, Canada; Långban and Pajsberg, Sweden; West Kimberley, Western Australia; Sanka, Myanmar; and, in the US, at Iron Hill, Colorado; Leucite Hills, Wyoming; and Libby, Montana. The mineral was named in 1865 for the German mineralogist Hieronymous Theodor Richter (1824–1898).

<span class="mw-page-title-main">Vlasovite</span>

Vlasovite is a rare inosilicate (chain silicate) mineral with sodium and zirconium, with the chemical formula Na2ZrSi4O11. It was discovered in 1961 at Vavnbed Mountain in the Lovozero Massif, in the Northern Region of Russia. The researchers who first identified it, R P Tikhonenkova and M E Kazakova, named it for Kuzma Aleksevich Vlasov (1905–1964), a Russian mineralogist and geochemist who studied the Lovozero massif, and who was the founder of the Institute of Mineralogy, Geochemistry, and Crystal Chemistry of Rare Elements, Moscow, Russia.

This list gives an overview of the classification of minerals (silicates) and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, non-IMA approved minerals and non-named minerals are mostly excluded.

<span class="mw-page-title-main">Magnesiohastingsite</span>

Magnesiohastingsite is a calcium-containing amphibole and a member of the hornblende group. It is an inosilicate (chain silicate) with the formula NaCa2(Mg4Fe3+)(Si6Al2)O22(OH)2 and molar mass 864.69 g. In synthetic magnesiohastingsite it appears that iron occurs both as ferrous iron Fe2+ and as ferric iron Fe3+, but the ideal formula features only ferric iron. It was named in 1928 by Marland P. Billings. The name is for its relationship to hastingsite and its magnesium content. Hastingsite was named for the locality in Dungannon Township, Hastings County, Ontario, Canada.

Johnsenite-(Ce) is a very rare mineral of the eudialyte group, with the chemical formula Na12(Ce,La,Sr,Ca,[ ])3Ca6Mn3Zr3WSi(Si9O27)2(Si3O9)2(CO3)O(OH,Cl)2. The original formula was extended to show the presence of both the cyclic silicate groups and silicon at the M4 site, according to the nomenclature of the eudialyte group. It is the third eudialyte-group mineral with essential tungsten, and second with essential rare earth elements. In fact, some niobium substitutes for tungsten in johnsenite-(Ce). Other characteristic feature is the presence of essential carbonate group, shared with carbokentbrooksite, golyshevite, mogovidite and zirsilite-(Ce).

References

  1. 1 2 Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Donald D. Hogarth, George Y. Chao, Michael G. Townsend; Potassium- and fluorine-rich amphiboles from the Gatineau area, Quebec. The Canadian Mineralogist 1987; 25 (4): 739–753. doi:
  3. 1 2 Donald D. Hogarth; FLUORO-POTASSIC-MAGNESIO-ARFVEDSONITE, KNa2Mg5Si8O22F2, FROM THE OUTAOUAIS REGION, QUEBEC, CANADA. The Canadian Mineralogist 2006;; 44 (1): 289. doi: https://doi.org/10.2113/gscanmin.44.1.289
  4. 1 2 3 4 "Potassic-Magnesio-Fluoro-Arfvedsonite". Mindat.
  5. "What is the longest mineral name? – ShortInformer". short-informer.com. Retrieved 2023-12-08.