Pyrosilicic acid

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Pyrosilicic acid
Pyrosilicic acid Pyrosilicic-acid-3D-balls.png
Pyrosilicic acid
Names
IUPAC name
Trihydroxysilyl trihydrogen orthosilicate
Other names
disilicic acid
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
26937
PubChem CID
  • InChI=1S/H6O7Si2/c1-8(2,3)7-9(4,5)6/h1-6H Yes check.svgY
    Key: KDJOAYSYCXTQGG-UHFFFAOYSA-N Yes check.svgY
  • O[Si](O)(O)O[Si](O)(O)O
Properties
H6O7Si2
Molar mass 174.211 g·mol−1
Conjugate base Pyrosilicate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Pyrosilicic acid is the chemical compound with formula H6Si2O7 or (HO)3SiOSi(OH)3. It is one of the silicic acids and has pyrosilicate as its conjugate base.

It was synthesized, using nonaqueous solutions, in 2017. [1]

H6Si2O7(aq) → 2 SiO2(s) + 3 H2O

Pyrosilicic acid may be present in sea water and other natural waters at very low concentration. [2] [3] Compounds formally derived from it, such as sodium pyrosilicate, are found in the sorosilicate minerals.

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<span class="mw-page-title-main">Silicate</span> Any polyatomic anion containing silicon and oxygen

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4−x
]
n
, where 0 ≤ x < 2. The family includes orthosilicate SiO4−4, metasilicate SiO2−3, and pyrosilicate Si2O6−7. The name is also used for any salt of such anions, such as sodium metasilicate; or any ester containing the corresponding chemical group, such as tetramethyl orthosilicate. The name "silicate" is sometimes extended to any anions containing silicon, even if they do not fit the general formula or contain other atoms besides oxygen; such as hexafluorosilicate [SiF6]2−. Most commonly, silicates are encountered as silicate minerals.

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6
N
7
H
3
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4
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2
SiO
3
, which is the main component of commercial sodium silicate solutions. It is an ionic compound consisting of sodium cations Na+
and the polymeric metasilicate anions [–SiO2−
3
–]n. It is a colorless crystalline hygroscopic and deliquescent solid, soluble in water but not in alcohols.

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4
, or any of its salts and esters. It is one of the silicate anions. It is occasionally called the silicon tetroxide anion or group.

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2
SiO
. The free acid slowly polymerises in aqueous solution even at low concentrations and cannot be isolated under normal conditions. Compounds including the conjugate base are known as metasilicates and occur widely in nature as inosilicates.

In chemistry, a silicic acid is any chemical compound containing the element silicon attached to oxide and hydroxyl groups, with the general formula [H2xSiOx+2]n or, equivalently, [SiOx(OH)4−2x]n. Orthosilicic acid is a representative example. Silicic acids are rarely observed in isolation, but are thought to exist in aqueous solutions, including seawater, and play a role in biomineralization. They are typically colorless weak acids that are sparingly soluble in water. Like the silicate anions, which are their better known conjugate bases, silicic acids are proposed to be oligomeric or polymeric. No simple silicic acid has ever been identified, since these species are primarily of theoretical interest.

References

  1. Igarashi, Masayasu; Matsumoto, Tomohiro; Yagahashi, Fujio; Yamashita, Hiroshi; Ohhara, Takashi; Hanashima, Takayasu; Nakao, Akiko; Moyosh, Taketo; Sato, Kazuhiko; Shimada, Shigeru (2017). "Non-aqueous selective synthesis of orthosilicic acid and its oligomers". Nature Communications. 8 (1): 140. Bibcode:2017NatCo...8..140I. doi:10.1038/s41467-017-00168-5. PMC   5529440 . PMID   28747652.
  2. Katsumi Goto (1956): "Effect of pH on Polymerization of Silicic Acid". Journal of Physical Chemistry, volume 60, issue 7, pages 1007–1008. doi : 10.1021/j150541a046
  3. M. F. Bechtold (1955): "Polymerization and Properties of Dilute Aqueous Silicic Acid from Cation Exchange". Journal of Physical Chemistry, volume 59, issue 6, pages 532–541. doi : 10.1021/j150528a013