Quantum defect

Last updated

The term quantum defect refers to two concepts: energy loss in lasers and energy levels in alkali elements. Both deal with quantum systems where matter interacts with light.

Contents

In laser science

In laser science, the term "quantum defect" refers to the fact that the energy of a pump photon is generally higher than that of a signal photon (photon of the output radiation). The energy difference is lost to heat, which may carry away the excess entropy delivered by the multimode incoherent pump.

The quantum defect of a laser can be defined as part of the energy of the pumping photon, which is lost (not turned into photons at the lasing wavelength) in the gain medium at the lasing. [1] At given frequency of pump and given frequency of lasing, the quantum defect . Such quantum defect has dimension of energy; for the efficient operation, the temperature of the gain medium (measured in units of energy) should be small compared to the quantum defect.

Some colleagues define the quantum defect in a different way. At given frequency of pump and given frequency of lasing, the quantum defect ; according to this definition, quantum defect is dimensionless.[ citation needed ] At a fixed pump frequency, the higher the quantum defect, the lower is the upper bound for the power efficiency.

In hydrogenic atoms

In an idealized Bohr model alkali atom (such as sodium, pictured here), the single outer-shell electron stays outside the ionic core and it would be expected to behave just as if in the same orbital of a hydrogen atom. Atom-sodium.png
In an idealized Bohr model alkali atom (such as sodium, pictured here), the single outer-shell electron stays outside the ionic core and it would be expected to behave just as if in the same orbital of a hydrogen atom.

The quantum defect of an alkali atom refers to a correction to the energy levels predicted by the classic calculation of the hydrogen wavefunction. A simple model of the potential experienced by the single valence electron of an alkali atom is that the ionic core acts as a point charge with effective charge e and the wavefunctions are hydrogenic. However, the structure of the ionic core alters the potential at small radii. [2]

The 1/r potential in the hydrogen atom leads to an electron binding energy given by

where is the Rydberg constant, is Planck's constant, is the speed of light and is the principal quantum number.

For alkali atoms with small orbital angular momentum, the wavefunction of the valence electron is non-negligible in the ion core where the screened Coulomb potential with an effective charge of e no longer describes the potential. The spectrum is still described well by the Rydberg formula with an angular momentum dependent quantum defect, :

The largest shifts occur when the orbital angular momentum is equal to 0 (normally labeled 's') and these are shown in the table for the alkali metals: [3]

ElementConfiguration
Li2s1.590.41
Na3s1.631.37
K4s1.772.23
Rb5s1.813.19
Cs6s1.874.13

See also

Related Research Articles

<span class="mw-page-title-main">Bohr model</span> Atomic model introduced by Niels Bohr in 1913

In atomic physics, the Bohr model or Rutherford–Bohr model of the atom, presented by Niels Bohr and Ernest Rutherford in 1913, consists of a small, dense nucleus surrounded by orbiting electrons. It is analogous to the structure of the Solar System, but with attraction provided by electrostatic force rather than gravity. In the history of atomic physics, it followed, and ultimately replaced, several earlier models, including Joseph Larmor's solar system model (1897), Jean Perrin's model (1901), the cubical model (1902), Hantaro Nagaoka's Saturnian model (1904), the plum pudding model (1904), Arthur Haas's quantum model (1910), the Rutherford model (1911), and John William Nicholson's nuclear quantum model (1912). The improvement over the 1911 Rutherford model mainly concerned the new quantum mechanical interpretation introduced by Haas and Nicholson, but forsaking any attempt to explain radiation according to classical physics.

<span class="mw-page-title-main">Hydrogen atom</span> Atom of the element hydrogen

A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the baryonic mass of the universe.

<span class="mw-page-title-main">Nonlinear optics</span> Branch of physics

Nonlinear optics (NLO) is the branch of optics that describes the behaviour of light in nonlinear media, that is, media in which the polarization density P responds non-linearly to the electric field E of the light. The non-linearity is typically observed only at very high light intensities (when the electric field of the light is >108 V/m and thus comparable to the atomic electric field of ~1011 V/m) such as those provided by lasers. Above the Schwinger limit, the vacuum itself is expected to become nonlinear. In nonlinear optics, the superposition principle no longer holds.

Spontaneous emission is the process in which a quantum mechanical system transits from an excited energy state to a lower energy state and emits a quantized amount of energy in the form of a photon. Spontaneous emission is ultimately responsible for most of the light we see all around us; it is so ubiquitous that there are many names given to what is essentially the same process. If atoms are excited by some means other than heating, the spontaneous emission is called luminescence. For example, fireflies are luminescent. And there are different forms of luminescence depending on how excited atoms are produced. If the excitation is affected by the absorption of radiation the spontaneous emission is called fluorescence. Sometimes molecules have a metastable level and continue to fluoresce long after the exciting radiation is turned off; this is called phosphorescence. Figurines that glow in the dark are phosphorescent. Lasers start via spontaneous emission, then during continuous operation work by stimulated emission.

The quantum Hall effect is a quantized version of the Hall effect which is observed in two-dimensional electron systems subjected to low temperatures and strong magnetic fields, in which the Hall resistance Rxy exhibits steps that take on the quantized values

<span class="mw-page-title-main">Energy level</span> Different states of quantum systems

A quantum mechanical system or particle that is bound—that is, confined spatially—can only take on certain discrete values of energy, called energy levels. This contrasts with classical particles, which can have any amount of energy. The term is commonly used for the energy levels of the electrons in atoms, ions, or molecules, which are bound by the electric field of the nucleus, but can also refer to energy levels of nuclei or vibrational or rotational energy levels in molecules. The energy spectrum of a system with such discrete energy levels is said to be quantized.

<span class="mw-page-title-main">Wavenumber</span> Spatial frequency of a wave

In the physical sciences, the wavenumber is the spatial frequency of a wave, measured in cycles per unit distance or radians per unit distance. It is analogous to temporal frequency, which is defined as the number of wave cycles per unit time or radians per unit time.

In spectroscopy, the Rydberg constant, symbol for heavy atoms or for hydrogen, named after the Swedish physicist Johannes Rydberg, is a physical constant relating to the electromagnetic spectra of an atom. The constant first arose as an empirical fitting parameter in the Rydberg formula for the hydrogen spectral series, but Niels Bohr later showed that its value could be calculated from more fundamental constants according to his model of the atom.

In atomic physics, a dark state refers to a state of an atom or molecule that cannot absorb photons. All atoms and molecules are described by quantum states; different states can have different energies and a system can make a transition from one energy level to another by emitting or absorbing one or more photons. However, not all transitions between arbitrary states are allowed. A state that cannot absorb an incident photon is called a dark state. This can occur in experiments using laser light to induce transitions between energy levels, when atoms can spontaneously decay into a state that is not coupled to any other level by the laser light, preventing the atom from absorbing or emitting light from that state.

The old quantum theory is a collection of results from the years 1900–1925 which predate modern quantum mechanics. The theory was never complete or self-consistent, but was rather a set of heuristic corrections to classical mechanics. The theory is now understood as the semi-classical approximation to modern quantum mechanics. The main and final accomplishments of the old quantum theory were the determination of the modern form of the periodic table by Edmund Stoner and the Pauli Exclusion Principle which were both premised on the Arnold Sommerfeld enhancements to the Bohr model of the atom.

Tunnel ionization is a process in which electrons in an atom pass through the potential barrier and escape from the atom. In an intense electric field, the potential barrier of an atom (molecule) is distorted drastically. Therefore, as the length of the barrier that electrons have to pass decreases, the electrons can escape from the atom's potential more easily. Tunneling Ionization is a quantum mechanical phenomenon, since in the classical picture an electron does not have sufficient energy to overcome the potential barrier of the atom.

<span class="mw-page-title-main">Rydberg atom</span> Excited atomic quantum state with high principal quantum number (n)

A Rydberg atom is an excited atom with one or more electrons that have a very high principal quantum number, n. The higher the value of n, the farther the electron is from the nucleus, on average. Rydberg atoms have a number of peculiar properties including an exaggerated response to electric and magnetic fields, long decay periods and electron wavefunctions that approximate, under some conditions, classical orbits of electrons about the nuclei. The core electrons shield the outer electron from the electric field of the nucleus such that, from a distance, the electric potential looks identical to that experienced by the electron in a hydrogen atom.

Quantum noise is noise arising from the indeterminate state of matter in accordance with fundamental principles of quantum mechanics, specifically the uncertainty principle and via zero-point energy fluctuations. Quantum noise is due to the apparently discrete nature of the small quantum constituents such as electrons, as well as the discrete nature of quantum effects, such as photocurrents.

Photon polarization is the quantum mechanical description of the classical polarized sinusoidal plane electromagnetic wave. An individual photon can be described as having right or left circular polarization, or a superposition of the two. Equivalently, a photon can be described as having horizontal or vertical linear polarization, or a superposition of the two.

The theoretical and experimental justification for the Schrödinger equation motivates the discovery of the Schrödinger equation, the equation that describes the dynamics of nonrelativistic particles. The motivation uses photons, which are relativistic particles with dynamics described by Maxwell's equations, as an analogue for all types of particles.

In spectroscopy, the Autler–Townes effect, is a dynamical Stark effect corresponding to the case when an oscillating electric field is tuned in resonance to the transition frequency of a given spectral line, and resulting in a change of the shape of the absorption/emission spectra of that spectral line. The AC Stark effect was discovered in 1955 by American physicists Stanley Autler and Charles Townes.

A hydrogen-like atom (or hydrogenic atom) is any atom or ion with a single valence electron. These atoms are isoelectronic with hydrogen. Examples of hydrogen-like atoms include, but are not limited to, hydrogen itself, all alkali metals such as Rb and Cs, singly ionized alkaline earth metals such as Ca+ and Sr+ and other ions such as He+, Li2+, and Be3+ and isotopes of any of the above. A hydrogen-like atom includes a positively charged core consisting of the atomic nucleus and any core electrons as well as a single valence electron. Because helium is common in the universe, the spectroscopy of singly ionized helium is important in EUV astronomy, for example, of DO white dwarf stars.

The Kapitza–Dirac effect is a quantum mechanical effect consisting of the diffraction of matter by a standing wave of light. The effect was first predicted as the diffraction of electrons from a standing wave of light by Paul Dirac and Pyotr Kapitsa in 1933. The effect relies on the wave–particle duality of matter as stated by the de Broglie hypothesis in 1924.

The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalence, the relationship between mass and frequency. Specifically, a photon's energy is equal to its frequency multiplied by the Planck constant. The constant is generally denoted by . The reduced Planck constant, or Dirac constant, equal to the constant divided by , is denoted by .

In ion trapping and atomic physics experiments, the Lamb Dicke regime is a quantum regime in which the coupling between an ion or atom's internal qubit states and its motional states is sufficiently small so that transitions that change the motional quantum number by more than one are strongly suppressed.

References

  1. T.Y.Fan (1993). "Heat generation in Nd:YAG and Yb:YAG". IEEE Journal of Quantum Electronics . 29 (6): 1457–1459. Bibcode:1993IJQE...29.1457F. doi:10.1109/3.234394.
  2. http://www.phy.davidson.edu/StuHome/joesten/IntLab/final/rydberg.htm, Rydberg Atoms and the Quantum Defect at the site of Davidson College, Physics department
  3. C.J.Foot, Atomic Physics, Oxford University Press, ISBN   978-0-19-850695-9