Gadolinium is a chemical element with the symbol Gd and atomic number 64. Gadolinium is a silvery-white metal when oxidation is removed. It is only slightly malleable and is a ductile rare-earth element. Gadolinium reacts with atmospheric oxygen or moisture slowly to form a black coating. Gadolinium below its Curie point of 20 °C (68 °F) is ferromagnetic, with an attraction to a magnetic field higher than that of nickel. Above this temperature it is the most paramagnetic element. It is found in nature only in an oxidized form. When separated, it usually has impurities of the other rare-earths because of their similar chemical properties.
Superconductivity is a set of physical properties observed in certain materials where electrical resistance vanishes and magnetic flux fields are expelled from the material. Any material exhibiting these properties is a superconductor. Unlike an ordinary metallic conductor, whose resistance decreases gradually as its temperature is lowered, even down to near absolute zero, a superconductor has a characteristic critical temperature below which the resistance drops abruptly to zero. An electric current through a loop of superconducting wire can persist indefinitely with no power source.
Unconventional superconductors are materials that display superconductivity which does not conform to either the conventional BCS theory or Nikolay Bogolyubov's theory or its extensions.
High-temperature superconductors are defined as materials that behave as superconductors at temperatures above 77 K, the boiling point of liquid nitrogen. The adjective "high temperature" is only in respect to previously known superconductors, which function at even colder temperatures close to absolute zero. In absolute terms, these "high temperatures" are still far below ambient, and therefore require cooling. The first high-temperature superconductor was discovered in 1986, by IBM researchers Bednorz and Müller, who were awarded the Nobel Prize in Physics in 1987 "for their important break-through in the discovery of superconductivity in ceramic materials". Most high-Tc materials are type-II superconductors.
A superconducting magnet is an electromagnet made from coils of superconducting wire. They must be cooled to cryogenic temperatures during operation. In its superconducting state the wire has no electrical resistance and therefore can conduct much larger electric currents than ordinary wire, creating intense magnetic fields. Superconducting magnets can produce stronger magnetic fields than all but the strongest non-superconducting electromagnets, and large superconducting magnets can be cheaper to operate because no energy is dissipated as heat in the windings. They are used in MRI instruments in hospitals, and in scientific equipment such as NMR spectrometers, mass spectrometers, fusion reactors and particle accelerators. They are also used for levitation, guidance and propulsion in a magnetic levitation (maglev) railway system being constructed in Japan.
Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds that display high-temperature superconductivity; it includes the first material ever discovered to become superconducting above the boiling point of liquid nitrogen at about 93 K.
Superconductivity is the phenomenon of certain materials exhibiting zero electrical resistance and the expulsion of magnetic fields below a characteristic temperature. The history of superconductivity began with Dutch physicist Heike Kamerlingh Onnes's discovery of superconductivity in mercury in 1911. Since then, many other superconducting materials have been discovered and the theory of superconductivity has been developed. These subjects remain active areas of study in the field of condensed matter physics.
Niobium–tin is an intermetallic compound of niobium (Nb) and tin (Sn), used industrially as a type II superconductor. This intermetallic compound has a simple structure: A3B. It is more expensive than niobium–titanium (NbTi), but remains superconducting up to a magnetic flux density of 30 teslas [T] (300,000 G), compared to a limit of roughly 15 T for NbTi.
Bismuth strontium calcium copper oxide (BSCCO, pronounced bisko), is a type of cuprate superconductor having the generalized chemical formula Bi2Sr2Can−1CunO2n+4+x, with n = 2 being the most commonly studied compound (though n = 1 and n = 3 have also received significant attention). Discovered as a general class in 1988, BSCCO was the first high-temperature superconductor which did not contain a rare-earth element.
In superconductivity, a type-II superconductor is a superconductor that exhibits an intermediate phase of mixed ordinary and superconducting properties at intermediate temperature and fields above the superconducting phases. It also features the formation of magnetic field vortices with an applied external magnetic field. This occurs above a certain critical field strength Hc1. The vortex density increases with increasing field strength. At a higher critical field Hc2, superconductivity is destroyed. Type-II superconductors do not exhibit a complete Meissner effect.
Cuprate superconductors are a family of high-temperature superconducting materials made of layers of copper oxides (CuO2) alternating with layers of other metal oxides, which act as charge reservoirs. At ambient pressure, cuprate superconductors are the highest temperature superconductors known. However, the mechanism by which superconductivity occurs is still not understood.
Thallium barium calcium copper oxide, or TBCCO (pronounced "tibco"), is a family of high-temperature superconductors having the generalized chemical formula TlmBa2Can−1CunO2n+m+2.
In chemistry, oxypnictides are a class of materials composed of oxygen, a pnictogen and one or more other elements. Although this group of compounds has been recognized since 1995, interest in these compounds increased dramatically after the publication of the superconducting properties of LaOFeP and LaOFeAs which were discovered in 2006 and 2008. In these experiments the oxide was partly replaced by fluoride.
Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals, and is never found in nature as a free element. 89Y is the only stable isotope, and the only isotope found in the Earth's crust.
Superconducting wires are electrical wires made of superconductive material. When cooled below their transition temperatures, they have zero electrical resistance. Most commonly, conventional superconductors such as niobium-titanium are used, but high-temperature superconductors such as YBCO are entering the market.
The ARC fusion reactor is a design for a compact fusion reactor developed by the Massachusetts Institute of Technology (MIT) Plasma Science and Fusion Center (PSFC). ARC aims to achieve an engineering breakeven of three. The key technical innovation is to use high-temperature superconducting magnets in place of ITER's low-temperature superconducting magnets. The proposed device would be about half the diameter of the ITER reactor and cheaper to build.
SPARC is a tokamak under development by Commonwealth Fusion Systems (CFS) in collaboration with the Massachusetts Institute of Technology (MIT) Plasma Science and Fusion Center (PSFC). Funding has come from Eni, Breakthrough Energy Ventures, Khosla Ventures, Temasek, Equinor, Devonshire Investors, and others.
Hydrogen cryomagnetics is a term used to denote the use of cryogenic liquid hydrogen to cool the windings of an electromagnet. A key benefit of hydrogen cryomagnetics is that low temperature liquid hydrogen can be deployed simultaneously both as a cryogen to cool electromagnet windings and as an energy carrier. That is, powerful synergistic benefits are likely to arise when hydrogen is used as a fuel and as a coolant. Even without the fuel/coolant synergies, hydrogen cryomagnetics is an attractive option for the cooling of superconducting electromagnets as it eliminates dependence upon increasingly scarce and expensive liquid helium. For hydrogen cryomagnetic applications specialist hydrogen-cooled electromagnets are wound using either copper or superconductors. Liquid-hydrogen-cooled copper-wound magnets work well as pulsed field magnets. Superconductors have the property that they can operate continuously and very efficiently as electrical resistive losses are almost entirely avoided. Most commonly the term "hydrogen cryomagnetics" is used to denote the use of cryogenic liquid hydrogen directly, or indirectly, to enable high temperature superconductivity in electromagnet windings.
Lanthanum cuprate usually refers to the inorganic compound with the formula CuLa2O4. The name implies that the compound consists of a cuprate (CuOn]2n-) salt of lanthanum (La3+). In fact it is a highly covalent solid. It is prepared by high temperature reaction of lanthanum oxide and copper(II) oxide follow by annealing under oxygen.
