Refractometry is the analytical method of measuring substances' refractive index (one of their fundamental physical properties) in order to, for example, assess their composition or purity. A refractometer is the instrument used to measure refractive index ("RI"). Although refractometers are best known for measuring liquids, they are also used to measure gases and solids; such as glass and gemstones.
In optics, the refractive index or index of refraction of a material is a dimensionless number that describes how fast light travels through the material. It is defined as
A physical property is any property that is measurable, whose value describes a state of a physical system. The changes in the physical properties of a system can be used to describe its changes between momentary states. Physical properties are often referred to as observables. They are not modal properties. Quantifiable physical property is called physical quantity.
A refractometer is a laboratory or field device for the measurement of an index of refraction (refractometry). The index of refraction is calculated from Snell's law while for mixtures, the index of refraction can be calculated from the composition of the material using several mixing rules such as the Gladstone–Dale relation and Lorentz–Lorenz equation.
The RI of a substance is strongly influenced by temperature and the wavelength of light used to measure it, therefore, care must be taken to control or compensate for temperature differences and wavelength. RI measurements are usually reported at a reference temperature of 20 degrees Celsius, which is equal to 68 degrees Fahrenheit, and considered to be room temperature. A reference wavelength of 589.3 nm (the sodium D line) is most often used. Though RI is a dimensionless quantity, it is typically reported as nD20 (or n20
D ), where the "n" represents refractive index, the "D" denotes the wavelength, and the 20 denotes the reference temperature. Therefore, the refractive index of water at 20 degrees Celsius, taken at the Sodium D Line, would be reported as 1.3330 nD20.
In physics, the wavelength is the spatial period of a periodic wave—the distance over which the wave's shape repeats. It is the distance between consecutive corresponding points of the same phase on the wave, such as two adjacent crests, troughs, or zero crossings, and is a characteristic of both traveling waves and standing waves, as well as other spatial wave patterns. The inverse of the wavelength is called the spatial frequency. Wavelength is commonly designated by the Greek letter lambda (λ). The term wavelength is also sometimes applied to modulated waves, and to the sinusoidal envelopes of modulated waves or waves formed by interference of several sinusoids.
The Celsius scale, also known as the centigrade scale, is a temperature scale used by the International System of Units (SI). As an SI derived unit, it is used worldwide. In the United States, the Bahamas, Belize, the Cayman Islands and Liberia however, Fahrenheit remains the preferred scale for everyday temperature measurement. The degree Celsius can refer to a specific temperature on the Celsius scale or a unit to indicate a difference between two temperatures or an uncertainty. It is named after the Swedish astronomer Anders Celsius (1701–1744), who developed a similar temperature scale. Before being renamed to honor Anders Celsius in 1948, the unit was called centigrade, from the Latin centum, which means 100, and gradus, which means steps.
The Fahrenheit scale is a temperature scale based on one proposed in 1724 by German physicist Daniel Gabriel Fahrenheit (1686–1736). It uses the degree Fahrenheit as the unit. Several accounts of how he originally defined his scale exist. The lower defining point, 0 ℉, was established as the freezing temperature of a solution of brine made from equal parts of ice, water and a salt. Further limits were established as the melting point of ice (32 ℉) and his best estimate of the average human body temperature. The scale is now usually defined by two fixed points: the temperature at which water freezes into ice is defined as 32 ℉, and the boiling point of water is defined to be 212 ℉, a 180 ℉ separation, as defined at sea level and standard atmospheric pressure.
Refractometers are frequently used by grape growers and kiwifruit growers for Brix testing of sucrose levels in their fruit. Refractometry is also used in the gelatin industry. To convert the RI of a gelatin sol (reported in Brix) to a gelatin concentration, one need only multiply by eight-tenths (0.8). A sol with a 10.0 RI would therefore be 8% gelatin by weight. This is known to be a reliable conversion for gelatin sols as low as 1% up to over 50%.
Viticulture or winegrowing is the cultivation and harvesting of grapes. It is a branch of the science of horticulture. While the native territory of Vitis vinifera, the common grape vine, ranges from Western Europe to the Persian shores of the Caspian Sea, the vine has demonstrated high levels of adaptability to new environments; thus, viticulture can be found on every continent except Antarctica.
Kiwifruit, or Chinese gooseberry, is the edible berry of several species of woody vines in the genus Actinidia. The most common cultivar group of kiwifruit is oval, about the size of a large hen's egg. It has a thin, hair-like, fibrous, sour-but-edible light brown skin and light green or golden flesh with rows of tiny, black, edible seeds. The fruit has a soft texture with a sweet and unique flavour. China produced 50% of the world total of kiwifruit in 2017.
Degrees Brix is the sugar content of an aqueous solution. One degree Brix is 1 gram of sucrose in 100 grams of solution and represents the strength of the solution as percentage by mass. If the solution contains dissolved solids other than pure sucrose, then the °Bx only approximates the dissolved solid content. The °Bx is traditionally used in the wine, sugar, carbonated beverage, fruit juice, maple syrup and honey industries.
There are four main types of fluid refractometers: traditional handheld refractometers, digital handheld refractometers, Abbe refractometers, and inline process refractometers.
A traditional handheld refractometer is an analog instrument for measuring a liquid's refractive index. It works on the critical angle principle by which lenses and prisms project a shadow line onto a small glass reticle inside the instrument, which is then viewed by the user through a magnifying eyepiece.
A digital handheld refractometer is an instrument for measuring the refractive index of materials.
An Abbe refractometer is a bench-top device for the high-precision measurement of an index of refraction.
Colin E. Webb, Julian D. C. Jones (2004). Handbook of Laser Technology and Applications. Taylor & Francis. pp. 1738–1740. ISBN 0-7503-0966-0.
The International Standard Book Number (ISBN) is a numeric commercial book identifier which is intended to be unique. Publishers purchase ISBNs from an affiliate of the International ISBN Agency.
In optics and lens design, the Abbe number, also known as the V-number or constringence of a transparent material, is a measure of the material's dispersion, with high values of V indicating low dispersion. It is named after Ernst Abbe (1840–1905), the German physicist who defined it.
Gemology or gemmology is the science dealing with natural and artificial gemstone materials. It is considered a geoscience and a branch of mineralogy. Some jewelers are academically trained gemologists and are qualified to identify and evaluate gems.
Ultraviolet–visible spectroscopy or ultraviolet–visible spectrophotometry refers to absorption spectroscopy or reflectance spectroscopy in part of the ultraviolet and the full, adjacent visible spectral regions. This means it uses light in the visible and adjacent ranges. The absorption or reflectance in the visible range directly affects the perceived color of the chemicals involved. In this region of the electromagnetic spectrum, atoms and molecules undergo electronic transitions. Absorption spectroscopy is complementary to fluorescence spectroscopy, in that fluorescence deals with transitions from the excited state to the ground state, while absorption measures transitions from the ground state to the excited state.
In optics, dispersion is the phenomenon in which the phase velocity of a wave depends on its frequency.
Must weight is a measure of the amount of sugar in grape juice (must) and, hence, indicates the amount of alcohol that could be produced if it is all fermented to alcohol, rather than left as residual sugar. While must weight is a commonly used term among wine makers, the physically correct term would be must density.
A diamond simulant, diamond imitation or imitation diamond is an object or material with gemological characteristics similar to those of a diamond. Simulants are distinct from synthetic diamonds, which are actual diamonds having the same material properties as natural diamonds. Enhanced diamonds are also excluded from this definition. A diamond simulant may be artificial, natural, or in some cases a combination thereof. While their material properties depart markedly from those of diamond, simulants have certain desired characteristics—such as dispersion and hardness—which lend themselves to imitation. Trained gemologists with appropriate equipment are able to distinguish natural and synthetic diamonds from all diamond simulants, primarily by visual inspection.
In chemistry, specific rotation ([α]) is a property of a chiral chemical compound. It is defined as the change in orientation of monochromatic plane-polarized light, per unit distance–concentration product, as the light passes through a sample of a compound in solution. Compounds which rotate the plane of polarization of a beam of plane polarized light clockwise are said to be dextrorotary, and correspond with positive specific rotation values, while compounds which rotate the plane of polarization of plane polarized light counterclockwise are said to be levorotary, and correspond with negative values. If a compound is able to rotate the plane of polarization of plane-polarized light, it is said to be “optically active”.
The Oechsle scale is a hydrometer scale measuring the density of grape must, which is an indication of grape ripeness and sugar content used in wine-making. It is named for Ferdinand Oechsle (1774–1852) and it is widely used in the German, Swiss and Luxembourgish wine-making industries. On the Oechsle scale, one degree Oechsle corresponds to one gram of the difference between the mass of one litre of must at 20 °C and 1 kg. For example, must with a specific mass of 1084 grams per litre has 84° Oe.
A polarimeter is a scientific instrument used to measure the angle of rotation caused by passing polarized light through an optically active substance.
Inline process refractometers are a type of refractometer designed for the continuous measurement of a fluid flowing through a pipe or inside a tank. First patented by Carl A. Vossberg Jr. US2807976A - Refractometer US2549402A, these refractometers typically consist of a sensor, placed inline with the fluid flow, coupled to a control box. The control box usually provides a digital readout as well as 4-20 mA analog outputs and relay outputs for controlling pumps and valves. Instead of placing the sensor inline of the process, it can be placed in a bypass, attached by a thin tube.
Penetration depth is a measure of how deep light or any electromagnetic radiation can penetrate into a material. It is defined as the depth at which the intensity of the radiation inside the material falls to 1/e of its original value at the surface.
Diiodomethane or methylene iodide, commonly abbreviated “MI”, is an organoiodine compound. Diiodomethane is a colorless liquid; however, it decomposes upon exposure to light liberating iodine, which colours samples brownish. It is slightly soluble in water, but soluble in organic solvents. It has a relatively high refractive index of 1.741, and a surface tension of 0.0508 N·m−1.
The International Commission for Uniform Methods of Sugar Analysis (ICUMSA) is an international standards body, founded in 1897, that publishes detailed laboratory procedures for the analysis of sugar.
Nambulite is a lithium bearing manganese silicate mineral with formula: (Li,Na)Mn4Si5O14(OH). It is named after the mineralogist, Matsuo Nambu (born 1917) of Tohoko University, Japan, who is known for his research in manganese minerals. The mineral was first discovered in the Funakozawa Mine of northeastern Japan, a metasedimentary manganese ore.