Satterlyite

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Satterlyite
Satterlyite - Rapid Creek.jpg
Satterlyite from the Rapid Creek area of northern Yukon, Canada
General
Category Phosphate minerals
Formula
(repeating unit)
(Fe2+,Mg,Fe3+)2(PO4)(OH)
IMA symbol Sly [1]
Strunz classification 8.BB.20
Crystal system Trigonal
Crystal class Ditrigonal pyramidal (3m)
H-M symbol: (3m)
Space group P31m (no. 162), P31m (no. 157), or P312 (no. 149)
Unit cell a = 11.35, c = 5.04 [Å]; Z = 6
Identification
ColorLight brown to light yellow
Crystal habit Aggregate, nodular and radial
Cleavage None
Mohs scale hardness4.5–5
Luster Vitreous
Streak Pale yellow
Diaphaneity Transparent
Specific gravity 3.68
Optical propertiesUniaxial (−)
Refractive index nω = 1.721 nε = 1.719
Birefringence δ = 0.002
References [2] [3] [4]

Satterlyite is a hydroxyl bearing iron phosphate mineral. The mineral can be found in phosphatic shales and was first discovered in the Big Fish River area in Yukon Territory, Canada.

Contents

Satterlyite is part of the phosphate mineral group. Satterlyite is a transparent, light brown to light yellow mineral with a density of 3.68 g/cm3. The structure of satterlyite is made up of two pairs of face shared, distorted (Fe,Mg)O6 octahedra, linked together by sharing edges to form double chains along the [001] plain.

The first satterlyite mineral was discovered in the Big Fish River area in Yukon Territory, westernmost of Canada; by a geologist at Ontario Department of Mines in Canada, Jack Satterly, and the mineral was also named after him (Kolitsch, 2002).

Composition

Satterlyite has a formula of (Fe2+,Mg,Fe3+)2(PO4)(OH). Studies using the optical absorption spectra show that satterlyite has similar features to different iron bearing minerals with Fe(III) and Fe(II) impurities. Electron paramagnetic resonance studies were also made on the mineral first by turning the satterlyite mineral fine powder then putting it into an electron paramagnetic resonance quartz tube for measurements. The results showed a strong line on g = 2.0 and another line on g = 8.0, thus also showing a presence of ferrous and ferric ions in satterlyite.

Structure

Satterlyite is hydroxyl bearing iron phosphate with a space group P31m. The structure of satterlyite is made up of two pairs of face shared, distorted (Fe,Mg)O6 octahedra, the two faces are linked together by sharing edges to form double chains along the [001] plain. The double chains share ligands with six other double chains to make a 3D network holding three PO4 tetrahedra, linked by the corners to the (Fe,Mg)O6 octahedra (Kolitsch, 2002). The two (Fe,Mg)O6 oOctahedra have different occupancies; the Fe to Mg ratio of the M sites are 0.838(2):0.162(2) for the M(1) site and 0.706(2):0.294(2) for the M(2) site (Kolitsch, 2002). The structure contains three H atoms; two are share ligands with two (Fe,Mg)O6 octahedra and the third strongly disordered H atom is bonded to O of the PO4 tetrahedron (Kolitsch, 2002).

Holtedahlite, a mineral that was found in Tingelstadtjern quarry in Norway, with the formula (Mg12PO4)5(PO3OH,CO3)(OH,O)6 is isostructural with satterlyite (Raade, 1979). Infrared absorption powder spectra show that satterlyite is different from natural haltedahlite in that there is no carbonate for phosphate substitution (Kolitsch, 2002). Satterlyite is also structurally related to phosphoellenbergerite, a mineral that was discovered in Modum, Norway; near San Giocomo Vallone Di Gilba, in Western Alps of Italy (Palache, 1951); the minerals formula is Mg14(PO4)5(PO3OH)2(OH)6 (Kolitsch, 2002).

Electron paramagnetic resonance and optical absorption studies have investigated the iron phosphate mineral satterlyite and gormanite. Results of the optical studies show that both minerals have ferrous and ferric ions (Chandrasekhar, 2003). These studies also show that the site symmetry of Fe(III) in satterlyite is tetragonally distorted. However, the Fe(II) ions is tetragonally distorted octahedral (Chandrasekhar, 2003). The complex structure of satterlyite is made up of two pairs of face shared, distorted (Fe,Mg)O6 octahedra, linked together by sharing edges to form double chains along [001].

Physical properties

Satterlyite has a light brown to light yellow color with a light yellow streak and a hardness of 4.5 to 5. It has no trigonal (ditrigonal pyramidal) crystal symmetry with a space group P3*1m and no cleavage (Mandarino, 1978). The parameters of the mineral are a = 11.35 Å and c = 5.04 Å and the ratio of a to c is 1:0.444 and a cell volume 562.28 Å3 (Mindat, 2011). The mineral is found as one of three habits; aggregated (when the mineral is made up of many individual crystals or clusters), nodular (grows as a circle around the center) or radial (the crystal radiates outwards from the center of a common point on the mineral; Mineralogy Database, 2011).

Geologic occurrence

Jack Satterly, a geologist at Ontario Department of Mines in Canada, discovered satterlyite in nodules in shale in the Big Fish River (Mandarino, 1978). These nodules were about 10 cm in diameter, some would consist of satterlyite only and others would show satterlyite with quartz, pyrite, wolfeite or maricite. The Commission on New Minerals and Mineral Names approved the name of the mineral (Mandarino, 1978). The type specimen is now preserved at the Royal Ontario Museum (Mandarino, 1978).

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Penikisite was discovered by Alan Kulan and Gunar Penikis near Rapid Creek, Yukon Territory. The mineral is a member of the bjarebyite group along with kulanite, ideally BaFe2+2Al2(PO4)3(OH)3, and bjarebyite, ideally BaMn2+2Al2(PO4)3(OH)3. It is among several new minerals that have been discovered in the Rapid Creek and Big Fish areas of Yukon Territory. Kulanite is similar in many ways to penikisite in appearance and properties. The chemical formula for penikisite is Ba(Mg,Fe,Ca)Al2(PO4)2(OH)3. It has a hardness of about 4 and a density of 3.79 g/cm3. Penikisite is unique among the bjarebyite group in being monoclinic and has a biaxial optical class. It comes in shades of blue and green and, when rubbed on a streak plate, is pale green to white in color. Although penikisite and kulanite both range from blue to green, penikisite zones are easily distinguishable from kulanite zones in kulanite-penikisite crystals because they are lighter than the darker kulanite in color. Penikisite is a phosphate and is different from kulanite in that it is a magnesium-rich phosphate whereas kulanite is an iron-rich phosphate.

<span class="mw-page-title-main">Collinsite</span>

Collinsite is a mineral with chemical formula Ca
2
(Mg,Fe2+
)(PO
4
)
2
•2H
2
O
. It was discovered in British Columbia, Canada, and formally described in 1927. It was named in honor of William Henry Collins (1878–1937), director of the Geological Survey of Canada. There are three varieties of the mineral: magnesian collinsite, zincian collinsite, and strontian collinsite. The crystal structure consists of polyhedral chains linked by weak hydrogen bonds.

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<span class="mw-page-title-main">Serrabrancaite</span>

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Rockbridgeite is an anhydrous phosphate mineral in the "Rockbridgeite" supergroup with the chemical formula Fe2+Fe3+4(PO4)3(OH)5. It was discovered at the since-shut-down Midvale Mine in Rockbridge County, Virginia, United States. The researcher who first identified it, Clifford Frondel, named it in 1949 for its region of discovery, Rockbridge County.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Satterlyite data on Webmineral
  3. Satterlyite on Mindat.org
  4. Satterlyite in the Handbook of Mineralogy

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