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Zeolite is a family of several microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula Mn+
1/n(AlO
2)−
(SiO
2)
x･yH
2O where Mn+
1/n is either a metal ion or H+. These positive ions can be exchanged for others in a contacting electrolyte solution. H+
exchanged zeolites are particularly useful as solid acid catalysts.
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References
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- ↑ Suib, Steven L.; Carrado, Kathleen A. (1985). "Zeolite photochemistry: energy transfer between rare-earth and actinide ions in zeolites". Inorganic Chemistry. 24 (2): 200–202. doi:10.1021/ic00196a016.
- ↑ Force, R. Ken; Fessehaie, Mebrahtu G.; Grosso, Robert; McClain, Skye; Willis, William S.; Suib, Steven L. (1990). "Photochemistry of semiconductor surfaces: in situ photoreduction of tin disulfide". Inorganic Chemistry. 29 (10): 1924–1929. doi:10.1021/ic00335a032.
- ↑ Cao, Lixin; Spiess, Franz-Josef; Huang, Aimin; Suib, Steven L.; Obee, Timothy N.; Hay, Steven O.; Freihaut, James D. (1999). "Heterogeneous Photocatalytic Oxidation of 1-Butene on SnO2 and TiO2 Films". The Journal of Physical Chemistry B. 103 (15): 2912–2917. doi:10.1021/jp983860z.
- ↑ Brimblecombe, Robin; Chen, Jun; Wagner, Pawel; Buchhorn, Timothy; Dismukes, G. Charles; Spiccia, Leone; Swiegers, Gerhard F. (2011). "Photocatalytic oxygen evolution from non-potable water by a bioinspired molecular water oxidation catalyst". Journal of Molecular Catalysis A: Chemical. 338 (1–2): 1–6. doi:10.1016/j.molcata.2011.02.006.
- ↑ Hay, Stephen; Obee, Timothy; Luo, Zhu; Jiang, Ting; Meng, Yongtao; He, Junkai; Murphy, Steven; Suib, Steven (2015). "The Viability of Photocatalysis for Air Purification". Molecules. 20 (1): 1319–1356. doi: 10.3390/molecules20011319 . PMC 6272289 . PMID 25594345.
- ↑ Dutta, Biswanath; Achola, Laura A.; Clarke, Ryan; Sharma, Vinit; He, Junkai; Kerns, Peter; Suib, Steven L. (2019). "Photocatalytic Transformation of Amines to Imines by Meso-Porous Copper Sulfides". ChemCatChem. 11 (17): 4262–4265. doi:10.1002/cctc.201900673. OSTI 1598205. S2CID 202080701.
- ↑ Ching, Stanton; Suib, Steven L. (1997). "Synthetic Routes to Microporous Manganese Oxides". Comments on Inorganic Chemistry. 19 (5): 263–282. doi:10.1080/02603599708032741.
- ↑ King'Ondu, Cecil K.; Poyraz, Altug S.; Kuo, Chung-Hao; Biswas, Sourav; Suib, Steven L. (2013). "A general approach to crystalline and monomodal pore size mesoporous materials". Nature Communications. 4: 2952. Bibcode:2013NatCo...4.2952P. doi: 10.1038/ncomms3952 . PMID 24335918.
- ↑ Thalgaspitiya, Wimalika R.K.; Kankanam Kapuge, Tharindu; Rathnayake, Dinithi; He, Junkai; Willis, William S.; Suib, Steven L. (2020). "Generalized synthesis of high surface area mesoporous metal titanates as efficient heterogeneous catalysts". Applied Materials Today. 19: 100570. doi: 10.1016/j.apmt.2020.100570 .
- ↑ Sriskandakumar, Thamayanthy; Opembe, Naftali; Chen, Chun-Hu; Morey, Aimee; King'Ondu, Cecil; Suib, Steven L. (2009). "Green Decomposition of Organic Dyes Using Octahedral Molecular Sieve Manganese Oxide Catalysts". The Journal of Physical Chemistry A. 113 (8): 1523–1530. Bibcode:2009JPCA..113.1523S. doi:10.1021/jp807631w. PMID 19178167.
- ↑ Pahalagedara, Madhavi N.; Pahalagedara, Lakshitha R.; Kriz, David; Chen, Sheng-Yu; Beaulieu, Forrest; Thalgaspitiya, Wimalika; Suib, Steven L. (2016). "Copper aluminum mixed oxide (CuAl MO) catalyst: A green approach for the one-pot synthesis of imines under solvent-free conditions". Applied Catalysis B: Environmental. 188: 227–234. Bibcode:2016AppCB.188..227P. doi: 10.1016/j.apcatb.2016.02.007 .
- ↑ Suib, Steven L. (2013). "Some grand challenges in environmental chemistry". Frontiers in Chemistry. 1: 1. doi: 10.3389/fchem.2013.00001 . PMC 3982573 . PMID 24790931. S2CID 15379841.
- ↑ "Suib Joins Elite Group of Chemical Pioneers".
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- ↑ "CSNY Excellence Award".
