Tin(II) 2-ethylhexanoate

Last updated
Tin(II) 2-ethylhexanoate
Tin(II) 2-ethylhexanoate.svg
Names
IUPAC name
Tin(2+) bis(2-ethylhexanoate)
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.005.554 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/2C8H16O2.Sn/c2*1-3-5-6-7(4-2)8(9)10;/h2*7H,3-6H2,1-2H3,(H,9,10);/q;;+2/p-2
  • CCCCC(CC)C(=O)[O-].CCCCC(CC)C(=O)[O-].[Sn+2]
Properties
C16H30O4Sn
Molar mass 405.122 g·mol−1
AppearanceYellow liquid
Density 1.251 g/cm3
Melting point <0 °C (32 °F; 273 K)
Boiling point ~130 to 150 °C (266 to 302 °F; 403 to 423 K) at 30 mTorr
Degrades in water to form Sn(IV)
Hazards
Flash point 113 °C (235 °F; 386 K) closed cup
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tin(II) 2-ethylhexanoate or tin(II) octoate or stannous octoate (Sn(Oct)2) [1] is a compound of tin. Produced by the reaction of tin(II) oxide and 2-ethylhexanoic acid, it is a clear colorless liquid at room temperature, though often appears yellow due to impurities, likely resulting from oxidation of Sn(II) to Sn(IV). [2]

It is sometimes used as a catalyst for ring-opening polymerization, such as for the production of polylactic acid. [3]

Related Research Articles

<span class="mw-page-title-main">Tin</span> Chemical element, symbol Sn and atomic number 50

Tin is a chemical element with the symbol Sn and atomic number 50. Tin is a silvery-coloured metal.

Aqua regia Mixture of nitric acid and hydrochloric acid in a 1:3 molar ratio

Aqua regia is a mixture of nitric acid and hydrochloric acid, optimally in a molar ratio of 1:3. Aqua regia is a fuming liquid. Freshly prepared aqua regia is colorless, but it turns yellow, orange or red within seconds due to the formation of nitrosyl chloride and nitrogen dioxide. It was named by alchemists because it can dissolve the noble metals gold and platinum, though not all metals.

In chemistry, an amphoteric compound is a molecule or ion that can react both as an acid and as a base. What exactly this can mean depends on which definitions of acids and bases are being used. The prefix of the word 'amphoteric' is derived from a Greek prefix amphi which means "both".

Sodium triphosphate Chemical compound

Sodium triphosphate (STP), also sodium tripolyphosphate (STPP), or tripolyphosphate (TPP),) is an inorganic compound with formula Na5P3O10. It is the sodium salt of the polyphosphate penta-anion, which is the conjugate base of triphosphoric acid. It is produced on a large scale as a component of many domestic and industrial products, especially detergents. Environmental problems associated with eutrophication are attributed to its widespread use.

Tin(IV) chloride, also known as tin tetrachloride or stannic chloride, is an inorganic compound with the formula SnCl4. It is a colorless hygroscopic liquid, which fumes on contact with air. It is used as a precursor to other tin compounds. It was first discovered by Andreas Libavius (1550–1616) and was known as spiritus fumans libavii.

Polyglycolide Chemical compound

Polyglycolide or poly(glycolic acid) (PGA), also spelled as polyglycolic acid, is a biodegradable, thermoplastic polymer and the simplest linear, aliphatic polyester. It can be prepared starting from glycolic acid by means of polycondensation or ring-opening polymerization. PGA has been known since 1954 as a tough fiber-forming polymer. Owing to its hydrolytic instability, however, its use has initially been limited. Currently polyglycolide and its copolymers are widely used as a material for the synthesis of absorbable sutures and are being evaluated in the biomedical field.

In chemistry the term stannate refers to compounds of tin (Sn). Stannic acid (Sn(OH)4), the formal precursor to stannates, does not exist and is actually a hydrate of SnO2. The term is also used in naming conventions as a suffix; for example the hexachlorostannate ion is SnCl2−
6
.

Organotin chemistry Branch of organic chemistry

Organotin compounds or stannanes are chemical compounds based on tin with hydrocarbon substituents. Organotin chemistry is part of the wider field of organometallic chemistry. The first organotin compound was diethyltin diiodide, discovered by Edward Frankland in 1849. The area grew rapidly in the 1900s, especially after the discovery of the Grignard reagents, which are useful for producing Sn–C bonds. The area remains rich with many applications in industry and continuing activity in the research laboratory.

Tin(II) chloride Chemical compound

Tin(II) chloride, also known as stannous chloride, is a white crystalline solid with the formula SnCl2. It forms a stable dihydrate, but aqueous solutions tend to undergo hydrolysis, particularly if hot. SnCl2 is widely used as a reducing agent (in acid solution), and in electrolytic baths for tin-plating. Tin(II) chloride should not be confused with the other chloride of tin; tin(IV) chloride or stannic chloride (SnCl4).

<span class="mw-page-title-main">Tin(II) oxide</span> Chemical compound, stannous oxide (SnO)

Tin(II) oxide is a compound with the formula SnO. It is composed of tin and oxygen where tin has the oxidation state of +2. There are two forms, a stable blue-black form and a metastable red form.

<span class="mw-page-title-main">Tin(IV) oxide</span> Chemical compound known as stannic oxide, cassiterite and tin ore

Tin(IV) oxide, also known as stannic oxide, is the inorganic compound with the formula SnO2. The mineral form of SnO2 is called cassiterite, and this is the main ore of tin. With many other names, this oxide of tin is an important material in tin chemistry. It is a colourless, diamagnetic, amphoteric solid.

Tin(II) hydroxide Chemical compound

Tin(II) hydroxide, Sn(OH)2, also known as stannous hydroxide, is an inorganic compound tin(II). The only related material for which definitive information is available is the oxy hydroxide Sn6O4(OH)4, but other related materials are claimed. They are all white solids that are insoluble in water.

Tin oxide may refer to:

<span class="mw-page-title-main">Rhenium(VII) oxide</span> Chemical compound

Rhenium(VII) oxide is the inorganic compound with the formula Re2O7. This yellowish solid is the anhydride of HOReO3. Perrhenic acid, Re2O7·2H2O, is closely related to Re2O7. Re2O7 is the raw material for all rhenium compounds, being the volatile fraction obtained upon roasting the host ore.

Tin(II) bromide is a chemical compound of tin and bromine with a chemical formula of SnBr2. Tin is in the +2 oxidation state. The stability of tin compounds in this oxidation state is attributed to the inert pair effect.

Tin(II) fluoride Chemical compound

Tin(II) fluoride, commonly referred to commercially as stannous fluoride (from Latin stannum, 'tin'), is a chemical compound with the formula SnF2. It is a colourless solid used as an ingredient in toothpastes.

Tin(II) iodide Chemical compound

Tin(II) iodide, also known as stannous iodide, is an ionic tin salt of iodine with the formula SnI2. It has a formula weight of 372.519 g/mol. It is a red to red-orange solid. Its melting point is 320 °C, and its boiling point is 714 °C.

<span class="mw-page-title-main">Photo-oxidation of polymers</span>

In polymer chemistry photo-oxidation is the degradation of a polymer surface due to the combined action of light and oxygen. It is the most significant factor in the weathering of plastics. Photo-oxidation causes the polymer chains to break, resulting in the material becoming increasingly brittle. This leads to mechanical failure and, at an advanced stage, the formation of microplastics. In textiles the process is called phototendering.

Stannosis is an occupational, non-fibrotic pneumoconiosis caused by chronic exposure and inhalation of tin. Pneumoconiosis is essentially when inorganic dust is found on the lung tissue; in this case, caused by tin oxide minerals. Dust particles and fumes from tin industries, stannous oxide (SnO) and stannic oxide (SnO2), are specific to stannosis diagnoses. Hazardous occupations such as, tinning, tin-working, and smelting are where most cases of stannosis are documented. When melted tin ions are inhaled as a fume, the tin oxides deposit onto the lung nodules and immune response cells. If a worker is exposed to tin oxides over multiple events for an extended time, they are at risk of developing stannosis.

Tin(II) oxalate Chemical compound

Tin(II) oxalate is an inorganic compound, a salt of tin and oxalic acid with the chemical formula SnC
2
O
4
. The compound looks like colorless crystals, does not dissolve in water, and forms crystalline hydrates.

References

  1. Sometimes misleadingly tin(II) octanoate.
  2. Kumar Suri, Ashok; Banerjee, Srikuman (2006). "Tin". Materials Science and Technology. doi:10.1002/9783527603978.mst0079. ISBN   9783527603978.
  3. Schwach, G.; Coudane, J.; Engel, R.; Vert, M. (1997). "More about the polymerization of lactides in the presence of stannous octoate". Journal of Polymer Science Part A: Polymer Chemistry. 35 (16): 3431–3440. Bibcode:1997JPoSA..35.3431S. doi:10.1002/(SICI)1099-0518(19971130)35:16<3431::AID-POLA10>3.0.CO;2-G.