Triiron ditin intermetallic

Last updated
Triiron ditin intermetallic
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/3Fe.2Sn
    Key: CQCUKVSIWYDQMI-UHFFFAOYSA-N
  • [Fe].[Fe].[Fe].[Sn].[Sn]
Properties
Fe3Sn·Sn
Structure [1]
Kagome
R3m
a = 5.338  Å, c = 19.789  Å
hexagonal
Related compounds
Related compounds
Fe3Sn
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

The compound with empirical formula Fe3Sn2 is the first known kagome magnet. It is an intermetallic compound composed of iron (Fe) and tin (Sn), with alternating planes of Fe3Sn and Sn. [1]

Contents

Preparation

The iron-tin intermetallic forms at around 750 °C (1,380 °F) and naturally assumes a kagome structure. [2] Quenching in an ice bath then cools the material to room temperature without disrupting the atomic structure. [3]

Electronic structure

The compound's band structure exhibits a double Dirac cone, enabling Dirac fermions. A 30 meV gap separates the cones, which indicates the quantum Hall effect and massive Dirac fermions. [4] Close measurement of the Fermi surface via the de Haas-van Alphen effect suggests that the massive fermions also exhibit Kane-Mele-type spin-orbit coupling. [5]

Fe3Sn2 can also host magnetic skyrmions, but these typically require high magnetic fields to nucleate. For samples with a small (but nonzero) thickness gradient, only a small-amplitude (5-10 mT), direction-variant magnetic field suffices to nucleate the quasiparticles. [6]

Related Research Articles

<span class="mw-page-title-main">Fermion</span> Type of subatomic particle

In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin 1/2, spin 3/2, etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and leptons and all composite particles made of an odd number of these, such as all baryons and many atoms and nuclei. Fermions differ from bosons, which obey Bose–Einstein statistics.

<span class="mw-page-title-main">Kondo effect</span> Physical phenomenon due to impurities

In physics, the Kondo effect describes the scattering of conduction electrons in a metal due to magnetic impurities, resulting in a characteristic change i.e. a minimum in electrical resistivity with temperature. The cause of the effect was first explained by Jun Kondo, who applied third-order perturbation theory to the problem to account for scattering of s-orbital conduction electrons off d-orbital electrons localized at impurities. Kondo's calculation predicted that the scattering rate and the resulting part of the resistivity should increase logarithmically as the temperature approaches 0 K. Experiments in the 1960s by Myriam Sarachik at Bell Laboratories provided the first data that confirmed the Kondo effect. Extended to a lattice of magnetic impurities, the Kondo effect likely explains the formation of heavy fermions and Kondo insulators in intermetallic compounds, especially those involving rare earth elements such as cerium, praseodymium, and ytterbium, and actinide elements such as uranium. The Kondo effect has also been observed in quantum dot systems.

In condensed matter physics, the Fermi surface is the surface in reciprocal space which separates occupied from unoccupied electron states at zero temperature. The shape of the Fermi surface is derived from the periodicity and symmetry of the crystalline lattice and from the occupation of electronic energy bands. The existence of a Fermi surface is a direct consequence of the Pauli exclusion principle, which allows a maximum of one electron per quantum state. The study of the Fermi surfaces of materials is called fermiology.

<span class="mw-page-title-main">Intermetallic</span> Type of metallic alloy

An intermetallic is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Intermetallics are generally hard and brittle, with good high-temperature mechanical properties. They can be classified as stoichiometric or nonstoichiometic intermetallic compounds.

Strongly correlated materials are a wide class of compounds that include insulators and electronic materials, and show unusual electronic and magnetic properties, such as metal-insulator transitions, heavy fermion behavior, half-metallicity, and spin-charge separation. The essential feature that defines these materials is that the behavior of their electrons or spinons cannot be described effectively in terms of non-interacting entities. Theoretical models of the electronic (fermionic) structure of strongly correlated materials must include electronic (fermionic) correlation to be accurate. As of recently, the label quantum materials is also used to refer to strongly correlated materials, among others.

<span class="mw-page-title-main">Majorana fermion</span> Fermion that is its own antiparticle

A Majorana fermion, also referred to as a Majorana particle, is a fermion that is its own antiparticle. They were hypothesised by Ettore Majorana in 1937. The term is sometimes used in opposition to a Dirac fermion, which describes fermions that are not their own antiparticles.

The De Haas–Van Alphen effect, often abbreviated to DHVA, is a quantum mechanical effect in which the magnetic susceptibility of a pure metal crystal oscillates as the intensity of the magnetic field B is increased. It can be used to determine the Fermi surface of a material. Other quantities also oscillate, such as the electrical resistivity, specific heat, and sound attenuation and speed. It is named after Wander Johannes de Haas and his student Pieter M. van Alphen. The DHVA effect comes from the orbital motion of itinerant electrons in the material. An equivalent phenomenon at low magnetic fields is known as Landau diamagnetism.

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<span class="mw-page-title-main">Quantum oscillations</span>

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References

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  2. Aristos Georgiou (March 20, 2018). "Kagome metal: new exotic quantum material developed by scientists". Newsweek.
  3. Chu, Jennifer (March 19, 2018). "Physicists discover new quantum electronic material". MIT News. Massachusetts Institute of Technology.
  4. "The Electronic Structure of a 'Kagome' Material". ALS . Lawrence Berkeley National Lab. 2018-06-15. Retrieved 2020-04-17.
  5. Ye, Linda; Chan Mun K.; McDonald, Ross D.; Graf, David; Kang Mingu; Liu Junwei; Suzuki Takehito; Comin, Riccardo; Fu Liang; Checkelsky, Joseph G. (2019-10-25). "De Haas-van Alphen effect of correlated Dirac states in kagome metal Fe3Sn2". Nature Communications. 10 (1): 4870. arXiv: 1809.11159 . Bibcode:2019NatCo..10.4870Y. doi: 10.1038/s41467-019-12822-1 . ISSN   2041-1723. PMC   6814717 . PMID   31653866.
  6. Wang Binbin; Wu Po-kuan; Bagués Salguero, Núria; Zheng Qiang; Yan Jiaqiang; Randeria, Mohit; McComb, David W. (2021-08-24). "Stimulated Nucleation of Skyrmions in a Centrosymmetric Magnet". ACS Nano. 15 (8): 13495–13503. doi:10.1021/acsnano.1c04053. ISSN   1936-0851. OSTI   1819517 . PMID   34374281. S2CID   236967261.