In physics, Dirac cones are features that occur in some electronic band structures that describe unusual electron transport properties of materials like graphene and topological insulators. [1] [2] [3] In these materials, at energies near the Fermi level, the valence band and conduction band take the shape of the upper and lower halves of a conical surface, meeting at what are called Dirac points.
Typical examples include graphene, topological insulators, bismuth antimony thin films and some other novel nanomaterials, [1] [4] [5] in which the electronic energy and momentum have a linear dispersion relation such that the electronic band structure near the Fermi level takes the shape of an upper conical surface for the electrons and a lower conical surface for the holes. The two conical surfaces touch each other and form a zero-band gap semimetal.
The name of Dirac cone comes from the Dirac equation that can describe relativistic particles in quantum mechanics, proposed by Paul Dirac. Isotropic Dirac cones in graphene were first predicted by P. R. Wallace in 1947 [6] and experimentally observed by the Nobel Prize laureates Andre Geim and Konstantin Novoselov in 2005. [7]
In quantum mechanics, Dirac cones are a kind of crossing-point which electrons avoid, [8] where the energy of the valence and conduction bands are not equal anywhere in two dimensional lattice k-space, except at the zero dimensional Dirac points. As a result of the cones, electrical conduction can be described by the movement of charge carriers which are massless fermions, a situation which is handled theoretically by the relativistic Dirac equation. [9] The massless fermions lead to various quantum Hall effects, magnetoelectric effects in topological materials, and ultra high carrier mobility. [10] [11] Dirac cones were observed in 2008-2009, using angle-resolved photoemission spectroscopy (ARPES) on the potassium-graphite intercalation compound KC8 [12] and on several bismuth-based alloys. [13] [14] [11]
As an object with three dimensions, Dirac cones are a feature of two-dimensional materials or surface states, based on a linear dispersion relation between energy and the two components of the crystal momentum kx and ky. However, this concept can be extended to three dimensions, where Dirac semimetals are defined by a linear dispersion relation between energy and kx, ky, and kz. In k-space, this shows up as a hypercone, which have doubly degenerate bands which also meet at Dirac points. [11] Dirac semimetals contain both time reversal and spatial inversion symmetry; when one of these is broken, the Dirac points are split into two constituent Weyl points, and the material becomes a Weyl semimetal. [15] [16] [17] [18] [19] [20] [21] [22] [23] [24] [25] In 2014, direct observation of the Dirac semimetal band structure using ARPES was conducted on the Dirac semimetal cadmium arsenide. [26] [27] [28]
Dirac points have been realized in many physical areas such as plasmonics, phononics, or nanophotonics (microcavities, [29] photonic crystals [30] ).
In physics, the Kondo effect describes the scattering of conduction electrons in a metal due to magnetic impurities, resulting in a characteristic change i.e. a minimum in electrical resistivity with temperature. The cause of the effect was first explained by Jun Kondo, who applied third-order perturbation theory to the problem to account for scattering of s-orbital conduction electrons off d-orbital electrons localized at impurities. Kondo's calculation predicted that the scattering rate and the resulting part of the resistivity should increase logarithmically as the temperature approaches 0 K. Experiments in the 1960s by Myriam Sarachik at Bell Laboratories provided the first data that confirmed the Kondo effect. Extended to a lattice of magnetic impurities, the Kondo effect likely explains the formation of heavy fermions and Kondo insulators in intermetallic compounds, especially those involving rare earth elements such as cerium, praseodymium, and ytterbium, and actinide elements such as uranium. The Kondo effect has also been observed in quantum dot systems.
Cadmium arsenide (Cd3As2) is an inorganic semimetal in the II-V family. It exhibits the Nernst effect.
In particle physics, a massless particle is an elementary particle whose invariant mass is zero. At present the only confirmed massless particle is the photon.
A Majorana fermion, also referred to as a Majorana particle, is a fermion that is its own antiparticle. They were hypothesised by Ettore Majorana in 1937. The term is sometimes used in opposition to a Dirac fermion, which describes fermions that are not their own antiparticles.
Tungsten ditelluride (WTe2) is an inorganic semimetallic chemical compound. In October 2014, tungsten ditelluride was discovered to exhibit an extremely large magnetoresistance: 13 million percent resistance increase in a magnetic field of 60 tesla at 0.5 kelvin. The resistance is proportional to the square of the magnetic field and shows no saturation. This may be due to the material being the first example of a compensated semimetal, in which the number of mobile holes is the same as the number of electrons. Tungsten ditelluride has layered structure, similar to many other transition metal dichalcogenides, but its layers are so distorted that the honeycomb lattice many of them have in common is in WTe2 hard to recognize. The tungsten atoms instead form zigzag chains, which are thought to behave as one-dimensional conductors. Unlike electrons in other two-dimensional semiconductors, the electrons in WTe2 can easily move between the layers.
The quantum spin Hall state is a state of matter proposed to exist in special, two-dimensional semiconductors that have a quantized spin-Hall conductance and a vanishing charge-Hall conductance. The quantum spin Hall state of matter is the cousin of the integer quantum Hall state, and that does not require the application of a large magnetic field. The quantum spin Hall state does not break charge conservation symmetry and spin- conservation symmetry.
Subir Sachdev is Herchel Smith Professor of Physics at Harvard University specializing in condensed matter. He was elected to the U.S. National Academy of Sciences in 2014, received the Lars Onsager Prize from the American Physical Society and the Dirac Medal from the ICTP in 2018, and was elected Foreign Member of the Royal Society ForMemRS in 2023. He was a co-editor of the Annual Review of Condensed Matter Physics 2017–2019, and is Editor-in-Chief of Reports on Progress in Physics 2022-.
A topological insulator is a material whose interior behaves as an electrical insulator while its surface behaves as an electrical conductor, meaning that electrons can only move along the surface of the material.
In solid-state physics, Kondo insulators are understood as materials with strongly correlated electrons, that open up a narrow band gap at low temperatures with the chemical potential lying in the gap, whereas in heavy fermion materials the chemical potential is located in the conduction band.
Piers Coleman is a British-born theoretical physicist, working in the field of theoretical condensed matter physics. Coleman is professor of physics at Rutgers University in New Jersey and at Royal Holloway, University of London.
Silicene is a two-dimensional allotrope of silicon, with a hexagonal honeycomb structure similar to that of graphene. Contrary to graphene, silicene is not flat, but has a periodically buckled topology; the coupling between layers in silicene is much stronger than in multilayered graphene; and the oxidized form of silicene, 2D silica, has a very different chemical structure from graphene oxide.
Bismuth selenide is a gray compound of bismuth and selenium also known as bismuth(III) selenide.
Valleytronics is an experimental area in semiconductors that exploits local extrema ("valleys") in the electronic band structure. Certain semiconductors have multiple "valleys" in the electronic band structure of the first Brillouin zone, and are known as multivalley semiconductors. Valleytronics is the technology of control over the valley degree of freedom, a local maximum/minimum on the valence/conduction band, of such multivalley semiconductors.
Weyl semimetals are semimetals or metals whose quasiparticle excitation is the Weyl fermion, a particle that played a crucial role in quantum field theory but has not been observed as a fundamental particle in vacuum. In these materials, electrons have a linear dispersion relation, making them a solid-state analogue of relativistic massless particles.
Chiral magnetic effect (CME) is the generation of electric current along an external magnetic field induced by chirality imbalance. Fermions are said to be chiral if they keep a definite projection of spin quantum number on momentum. The CME is a macroscopic quantum phenomenon present in systems with charged chiral fermions, such as the quark–gluon plasma, or Dirac and Weyl semimetals. The CME is a consequence of chiral anomaly in quantum field theory; unlike conventional superconductivity or superfluidity, it does not require a spontaneous symmetry breaking. The chiral magnetic current is non-dissipative, because it is topologically protected: the imbalance between the densities of left-handed and right-handed chiral fermions is linked to the topology of fields in gauge theory by the Atiyah-Singer index theorem.
The term Dirac matter refers to a class of condensed matter systems which can be effectively described by the Dirac equation. Even though the Dirac equation itself was formulated for fermions, the quasi-particles present within Dirac matter can be of any statistics. As a consequence, Dirac matter can be distinguished in fermionic, bosonic or anyonic Dirac matter. Prominent examples of Dirac matter are graphene and other Dirac semimetals, topological insulators, Weyl semimetals, various high-temperature superconductors with -wave pairing and liquid helium-3. The effective theory of such systems is classified by a specific choice of the Dirac mass, the Dirac velocity, the gamma matrices and the space-time curvature. The universal treatment of the class of Dirac matter in terms of an effective theory leads to a common features with respect to the density of states, the heat capacity and impurity scattering.
In solid-state physics, the kagome metal or kagome magnet is a type of ferromagnetic quantum material. The atomic lattice in a kagome magnet has layered overlapping triangles and large hexagonal voids, akin to the kagome pattern in traditional Japanese basket-weaving. This geometry induces a flat electronic band structure with Dirac crossings, in which the low-energy electron dynamics correlate strongly.
Magnetic topological insulators are three dimensional magnetic materials with a non-trivial topological index protected by a symmetry other than time-reversal. In contrast with a non-magnetic topological insulator, a magnetic topological insulator can have naturally gapped surface states as long as the quantizing symmetry is broken at the surface. These gapped surfaces exhibit a topologically protected half-quantized surface anomalous Hall conductivity perpendicular to the surface. The sign of the half-quantized surface anomalous Hall conductivity depends on the specific surface termination.
Alexander Avraamovitch Golubov is a doctor of physical and mathematical sciences, associate professor at the University of Twente (Netherlands). He specializes in condensed matter physics with the focus on theory of electronic transport in superconducting devices. He made key contributions to theory of Josephson effect in novel superconducting materials and hybrid structures, and to theory of multiband superconductivity.
Rahul Nandkishore is a physicist and academic. He is an Associate Professor of Physics and Director of the Center for Theory of Quantum Matter at the University of Colorado, Boulder.