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Water desalination |
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Methods |
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Vapor-compression desalination (VC) refers to a distillation process where the evaporation of sea or saline water is obtained by the application of heat delivered by compressed vapor.
Since compression of the vapor increases both the pressure and temperature of the vapor, it is possible to use the latent heat rejected during condensation to generate additional vapor. The effect of compressing water vapor can be done by two methods.
The first method utilizes an ejector system motivated by steam at manometric pressure from an external source in order to recycle vapor from the desalination process. The form is designated ejectocompression or thermocompression.
Using the second method, water vapor is compressed by means of a mechanical device, electrically driven in most cases. This form is designated mechanical vapor compression (MVC). The MVC process comprises two different versions: vapor compression (VC) and vacuum vapor compression (VVC). VC designates those systems in which the evaporation effect takes place at manometric pressure, and VVC the systems in which evaporation takes place at sub-atmospheric pressures (under vacuum).
The compression is mechanically powered by something such as a compression turbine. As vapor is generated, it is passed over to a heat exchanging condenser which returns the vapor to water. The resulting fresh water is moved to storage while the heat removed during condensation is transmitted to the remaining feedstock.
The VVC process is the more efficient distillation process available in the market today in terms of energy consumption and water recovery ratio. [1] As the system is electrically driven, it is considered a "clean" process, it is highly reliable and simple to operate and maintain.
Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heating of solid materials to produce gaseous products ; this may involve chemical changes such as destructive distillation or cracking. Distillation may result in essentially complete separation, or it may be a partial separation that increases the concentration of selected components; in either case, the process exploits differences in the relative volatility of the mixture's components. In industrial applications, distillation is a unit operation of practically universal importance, but is a physical separation process, not a chemical reaction. An installation used for distillation, especially of distilled beverages, is a distillery. Distillation includes the following applications:
Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition.
Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in soil desalination, which is an issue for agriculture. Saltwater is desalinated to produce water suitable for human consumption or irrigation. The by-product of the desalination process is brine. Desalination is used on many seagoing ships and submarines. Most of the modern interest in desalination is focused on cost-effective provision of fresh water for human use. Along with recycled wastewater, it is one of the few rainfall-independent water resources.
A chiller is a machine that removes heat from a liquid coolant via a vapor-compression, adsorption refrigeration, or absorption refrigeration cycles. This liquid can then be circulated through a heat exchanger to cool equipment, or another process stream. As a necessary by-product, refrigeration creates waste heat that must be exhausted to ambience, or for greater efficiency, recovered for heating purposes. Vapor compression chillers may use any of a number of different types of compressors. Most common today are the hermetic scroll, semi-hermetic screw, or centrifugal compressors. The condensing side of the chiller can be either air or water cooled. Even when liquid cooled, the chiller is often cooled by an induced or forced draft cooling tower. Absorption and adsorption chillers require a heat source to function.
Vacuum distillation or Distillation under reduced pressure is a type of distillation performed under reduced pressure, which allows the purification of compounds not readily distilled at ambient pressures or simply to save time or energy. This technique separates compounds based on differences in their boiling points. This technique is used when the boiling point of the desired compound is difficult to achieve or will cause the compound to decompose. Reduced pressures decrease the boiling point of compounds. The reduction in boiling point can be calculated using a temperature-pressure nomograph using the Clausius–Clapeyron relation.
A solar still distills water with substances dissolved in it by using the heat of the Sun to evaporate water so that it may be cooled and collected, thereby purifying it. They are used in areas where drinking water is unavailable, so that clean water is obtained from dirty water or from plants by exposing them to sunlight.
Multi-stage flash distillation (MSF) is a water desalination process that distills sea water by flashing a portion of the water into steam in multiple stages of what are essentially countercurrent heat exchangers. Current MSF facilities may have as many as 30 stages.
Solar desalination is a desalination technique powered by solar energy. The two common methods are direct (thermal) and indirect (photovoltaic).
Vapour-compression refrigeration or vapor-compression refrigeration system (VCRS), in which the refrigerant undergoes phase changes, is one of the many refrigeration cycles and is the most widely used method for air conditioning of buildings and automobiles. It is also used in domestic and commercial refrigerators, large-scale warehouses for chilled or frozen storage of foods and meats, refrigerated trucks and railroad cars, and a host of other commercial and industrial services. Oil refineries, petrochemical and chemical processing plants, and natural gas processing plants are among the many types of industrial plants that often utilize large vapor-compression refrigeration systems. Cascade refrigeration systems may also be implemented using two compressors.
The solar humidification–dehumidification method (HDH) is a thermal water desalination method. It is based on evaporation of sea water or brackish water and subsequent condensation of the generated humid air, mostly at ambient pressure. This process mimics the natural water cycle, but over a much shorter time frame.
Vapor-compression evaporation is the evaporation method by which a blower, compressor or jet ejector is used to compress, and thus, increase the pressure of the vapor produced. Since the pressure increase of the vapor also generates an increase in the condensation temperature, the same vapor can serve as the heating medium for its "mother" liquid or solution being concentrated, from which the vapor was generated to begin with. If no compression was provided, the vapor would be at the same temperature as the boiling liquid/solution, and no heat transfer could take place.
Dewvaporation is a novel desalination technology developed at Arizona State University (Tempe) as an energy efficient tool for freshwater procurement and saline waste stream management. The system has relatively low installation costs and low operation and maintenance requirements.
An evaporator is a device used to turn a liquid into a gas.
A solar-powered desalination unit produces potable water from saline water through direct or indirect methods of desalination powered by sunlight. Solar energy is the most promising renewable energy source due to its ability to drive the more popular thermal desalination systems directly through solar collectors and to drive physical and chemical desalination systems indirectly through photovoltaic cells.
Mechanical vapor recompression (MVR) is an energy recovery process which can be used to recycle waste heat to improve efficiency. Typically, the compressed vapor is fed back to help heat the mother liquor in order to produce more vapor or steam.
An evaporator, distiller or distilling apparatus is a piece of ship's equipment used to produce fresh drinking water from sea water by distillation. As fresh water is bulky, may spoil in storage, and is an essential supply for any long voyage, the ability to produce more fresh water in mid-ocean is important for any ship.
Membrane distillation (MD) is a thermally driven separation process in which separation is driven by phase change. A hydrophobic membrane presents a barrier for the liquid phase, allowing the vapour phase to pass through the membrane's pores. The driving force of the process is a partial vapour pressure difference commonly triggered by a temperature difference.
Zero Liquid Discharge(ZLD) is a water treatment process designed to remove liquid waste from a system. The focus of ZLD is to reduce wastewater economically and produce clean water that is suitable for reuse (e.g. irrigation), thereby saving money and benefitting the environment. ZLD systems employ advanced wastewater/desalination treatment technologies to purify and recycle virtually all of the wastewater produced.
An evaporator is a device which turns the liquid form of a substance into its gaseous or vapour form. This is a widely used process and there are many applications for it.
The low-temperature distillation (LTD) technology is the first implementation of the direct spray distillation (DSD) process. The first large-scale units are now in operation for desalination. The process was first developed by scientists at the University of Applied Sciences in Switzerland, focusing on low-temperature distillation in vacuum conditions, from 2000 to 2005.