Villiaumite | |
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General | |
Category | Halide mineral |
Formula (repeating unit) | NaF |
Strunz classification | 3.AA.20 |
Crystal system | Cubic |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Fd3m |
Unit cell | a = 4.63 Å; Z = 4 |
Identification | |
Color | Carmine-red, lavender-pink to light orange |
Crystal habit | Cubic crystals rare, commonly granular, massive |
Cleavage | {001}, perfect |
Tenacity | Brittle |
Mohs scale hardness | 2 – 2.5 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent |
Specific gravity | 2.79 |
Optical properties | Isotropic; weak anomalous anisotropism, then uniaxial (–) |
Refractive index | n = 1.327–1.328 |
Pleochroism | Strong E = yellow; O = pink to deep carmine |
Ultraviolet fluorescence | dark red to orange and yellow fluorescence under SW and LW UV |
Solubility | Soluble in water |
References | [1] [2] [3] |
Villiaumite is a rare halide mineral composed of sodium fluoride, Na F. It is very soluble in water and some specimens fluoresce under long and short wave ultraviolet light. It has a Mohs hardness of 2.5 and is usually red, pink, or orange in color. It is toxic to humans. [2]
The red color is due to a broad absorption peaking at 512 nm. It is a result of radiation damage to the crystal. [4]
It occurs in nepheline syenite intrusives and in nepheline syenite pegmatites. It occurs associated with aegirine, sodalite, nepheline, neptunite, lamprophyllite, pectolite, serandite, eudialyte, ussingite, chkalovite and zeolites. [1] It has been reported from Minas Gerais, Brazil; Mont Saint-Hilaire, Quebec, Canada; the Ilimaussaq complex of Greenland; Lake Magadi, Kenya; Windhoek District, Namibia; the Fen Complex, Telemark, Norway; the Khibiny and Lovozero Massifs, Kola Peninsula, Russia; Porphyry Mountain, Boulder County, Colorado and Point of Rocks Mesa, Colfax County, New Mexico, US. [2]
It was first described in 1908 for an occurrence in Los Islands, Guinea and named after the French explorer, Maxime Villiaume. [2]
Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations. It is considered a granitoid. Some syenites contain larger proportions of mafic components and smaller amounts of felsic material than most granites; those are classed as being of intermediate composition.
Kogarkoite is a sodium sulfate fluoride mineral with formula Na3(SO4)F. It has a pale blue color, a specific gravity of about 2.67 and a hardness of 3.5. The crystal is monoclinic and is a type of naturally occurring antiperovskite. Kogarkoite is named after the Russian petrologist Lia Nikolaevna Kogarko (born 1936) who discovered the mineral.
Phonolite is an uncommon shallow intrusive or extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous rock trachyte that contains nepheline or leucite rather than quartz. It has an unusually high (12% or more) Na2O + K2O content, defining its position in the TAS classification of igneous rocks. Its coarse grained (phaneritic) intrusive equivalent is nepheline syenite. Phonolite is typically fine grained and compact. The name phonolite comes from the Ancient Greek meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name clinkstone is given as a synonym.
The feldspathoids are a group of tectosilicate minerals which resemble feldspars but have a different structure and much lower silica content. They occur in rare and unusual types of igneous rocks, and are usually not found in rocks containing primary quartz. A notable exception where feldspathoids and quartz-bearing rocks are found together is the Red Hill Syenite.
Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.
Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.
Kassite is a rare mineral whose chemical formula is CaTi2O4(OH)2. It crystallizes in the orthorhombic crystal system and forms radiating rosettes and pseudo-hexagonal tabular crystals which are commonly twinned. Kassite crystals are brownish pink to pale yellow in color, are translucent, and have an adamantine luster. Cleavage is distinctly visible, and the crystals are very brittle.
Natrolite is a tectosilicate mineral species belonging to the zeolite group. It is a hydrated sodium and aluminium silicate with the formula Na2Al2Si3O10·2H2O. The type locality is Hohentwiel, Hegau, Germany.
Eudialyte, whose name derives from the Greek phrase Εὖ διάλυτος, eu dialytos, meaning "well decomposable", is a somewhat rare, nine member ring cyclosilicate mineral, which forms in alkaline igneous rocks, such as nepheline syenites. Its name alludes to its ready solubility in acid.
Arfvedsonite is a sodium amphibole mineral with composition: [Na][Na2][(Fe2+)4Fe3+][(OH)2|Si8O22]. It crystallizes in the monoclinic prismatic crystal system and typically occurs as greenish black to bluish grey fibrous to radiating or stellate prisms.
Borolanite is an historical petrological name for a pyroxene-melanite bearing nepheline syenite variety which contains nepheline-alkali feldspar pseudomorphs interpreted to be after leucite which occur as conspicuous white spots in the dark rock matrix. The rock occurs in the Borralan Igneous Complex or Loch Borralan Complex which is an alkalic igneous complex near Loch Borralan in northwest Scotland.
Leucitite or leucite rock is an igneous rock containing leucite. It is scarce, many countries such as England being entirely without them. However, they are of wide distribution, occurring in every quarter of the globe. Taken collectively, they exhibit a considerable variety of types and are of great interest petrographically. For the presence of this mineral it is necessary that the silica percentage of the rock should be low, since leucite is incompatible with free quartz and reacts with it to form potassium feldspar. Because it weathers rapidly, leucite is most common in lavas of recent and Tertiary age, which have a fair amount of potassium, or at any rate have potassium equal to or greater than sodium; if sodium is abundant nepheline occurs rather than leucite.
An agpaitic rock is a peralkaline igneous rock, typically nepheline syenite or phonolite. Characteristic minerals in these rocks include complex silicates containing zirconium, titanium, sodium, calcium, the rare-earth elements, and fluorine. Agpaites are unusually rich in rare and obscure minerals such as eudialyte, wöhlerite, loparite, astrophyllite, lorenzenite, catapleiite, lamprophyllite, and villiaumite (NaF). Sodalite is typically present, but not diagnostic. Less alkaline igneous rocks in which zircon, titanite, and ilmenite are characteristic are called miaskitic.
Kvanefjeld, in Greenland, is the site of a mineral deposit, which is claimed to be the world's second-largest deposit of rare-earth oxides, and the sixth-largest deposit of uranium. There are also substantial sodium fluoride deposits, and Kvanefjeld is thought to be one of the largest multi-element deposits of its kind in the world.
Kochite is a rare silicate mineral with chemical formula of (Na,Ca)3Ca2(Mn,Ca)ZrTi[(F,O)4(Si2O7)2] or double that. Kochite is a member of the rosenbuschite group.
Serandite is a mineral with formula Na(Mn2+,Ca)2Si3O8(OH). The mineral was discovered in Guinea in 1931 and named for J. M. Sérand. Serandite is generally red, brown, black or colorless. The correct name lacks an accent.
Rutan Hill is the local name for a hill on the United States Geological Survey Branchville 7.5-minute map. It is located about 2.46 miles (3.96 km) south-southwest of Colesville, New Jersey in Wantage Township, of Sussex County, New Jersey in the United States. Rutan Hill rises about 270 feet (82 m) above the adjacent creek valley to an elevation of just over 1,020 feet (310 m). This hill lies entirely within private, posted property. This nondescript hill is the surface expression of a diatreme that is the northern part of the Late Ordovician Beemerville Alkaline Complex.
The Red Hill Syenite is a layered igneous rock complex in central New Hampshire, about 20 mi (32 km) east of Plymouth. The Red Hill Syenite is part of the White Mountain magma series, which underlays the White Mountains of New Hampshire. Red Hill is roughly oval-shaped, covers just under 7.7 square miles (20 km2), and has a summit elevation of 2,028 feet (618 m).
Wöhlerite, also known as wöehlerite is a member of the amphibole supergroup, and the wöhlerite subgroup within it. It was named after German chemist Friedrich Wöhler. It was first described by Scheerer in 1843, but the crystal structure was later solved by Mellino & Merlino in 1979. Once approved, it was grandfathered by the IMA.