Cerium(III) fluoride

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Cerium(III) fluoride
Cerium(III) fluoride.jpg
Cerium(III)-fluoride-xtal-3D-bs-17.png
Names
IUPAC name
Cerium(III) fluoride
Other names
Cerium trifluoride
Identifiers
ECHA InfoCard 100.028.947 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
Properties
CeF3
Molar mass 197.12 g/mol
Density 6.16 g/cm3 (at 20 °C)
Melting point 1,460 °C (2,660 °F; 1,730 K) [1]
Related compounds
Related compounds
Lanthanum trifluoride
Hazards
GHS labelling:
GHS-pictogram-exclam.svg GHS-pictogram-pollu.svg
NFPA 704 (fire diamond)
NFPA 704.svgHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
3
0
0
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Cerium(III) fluoride (or cerium trifluoride), CeF3, is an ionic compound of the rare earth metal cerium and fluorine.

It appears as a mineral in the form of fluocerite-(Ce) - a very rare mineral species related mainly to pegmatites and rarely to oxidation zones of some polymetallic ore deposits. [2] [3] CeF3 may be used as a Faraday rotator material in the visible, near-infrared and mid-infrared spectral range. [4] [5]

Structure

The crystal structure of cerium(III) fluoride is described as the LaF3 or tysonite structure. [6] It contains 9-coordinate cerium ions that adopt an approximately tricapped trigonal prismatic coordination geometry, [7] although it can be considered 11-coordinate if two more distant fluorides are considered part of the cerium coordination environment. [6] The three crystallographically independent fluoride ions are 3-coordinate and range in geometry from trigonal planar to pyramidal. [6]

Coordination in cerium(III) fluoride [8]
Cerium coordinationFluorine F1 coordinationFluorine F2 coordinationFluorine F3 coordination
Cerium(III)-fluoride-xtal-Ce-coord-3D-bs-17.png Cerium(III)-fluoride-xtal-F1-coord-3D-bs-17.png Cerium(III)-fluoride-xtal-F2-coord-3D-bs-17.png Cerium(III)-fluoride-xtal-F3-coord-3D-bs-17.png

Related Research Articles

<span class="mw-page-title-main">Optical isolator</span> Optical component allowing the transmission of light in only one direction

An optical isolator, or optical diode, is an optical component which allows the transmission of light in only one direction. It is typically used to prevent unwanted feedback into an optical oscillator, such as a laser cavity.

The Faraday effect or Faraday rotation, sometimes referred to as the magneto-optic Faraday effect (MOFE), is a physical magneto-optical phenomenon. The Faraday effect causes a polarization rotation which is proportional to the projection of the magnetic field along the direction of the light propagation. Formally, it is a special case of gyroelectromagnetism obtained when the dielectric permittivity tensor is diagonal. This effect occurs in most optically transparent dielectric materials under the influence of magnetic fields.

The Verdet constant is an optical property named after the French physicist Émile Verdet. It describes the strength of the Faraday effect for a particular material. For a constant magnetic field parallel to the path of the light, it can be calculated by:

<span class="mw-page-title-main">Faraday rotator</span>

A Faraday rotator is a polarization rotator based on the Faraday effect, a magneto-optic effect involving transmission of light through a material when a longitudinal static magnetic field is present. The state of polarization is rotated as the wave traverses the device, which is explained by a slight difference in the phase velocity between the left and right circular polarizations. Thus it is an example of circular birefringence, as is optical activity, but involves a material only having this property in the presence of a magnetic field.

Neodymium(III) chloride or neodymium trichloride is a chemical compound of neodymium and chlorine with the formula NdCl3. This anhydrous compound is a mauve-colored solid that rapidly absorbs water on exposure to air to form a purple-colored hexahydrate, NdCl3·6H2O. Neodymium(III) chloride is produced from minerals monazite and bastnäsite using a complex multistage extraction process. The chloride has several important applications as an intermediate chemical for production of neodymium metal and neodymium-based lasers and optical fibers. Other applications include a catalyst in organic synthesis and in decomposition of waste water contamination, corrosion protection of aluminium and its alloys, and fluorescent labeling of organic molecules (DNA).

Fluocerite, also known as tysonite, is a mineral consisting of cerium and lanthanum fluorides, with the chemical formula (Ce,La)F3. The end members are classified as two different mineral types depending on the cation, fluocerite-(Ce) and fluocerite-(La), corresponding respectively to lanthanum trifluoride and cerium trifluoride. Both crystallize in the trigonal system.

<span class="mw-page-title-main">Cobalt(III) fluoride</span> Chemical compound

Cobalt(III) fluoride is the inorganic compound with the formula CoF3. Hydrates are also known. The anhydrous compound is a hygroscopic brown solid. It is used to synthesize organofluorine compounds.

<span class="mw-page-title-main">Iron(III) fluoride</span> Chemical compound

Iron(III) fluoride, also known as ferric fluoride, are inorganic compounds with the formula FeF3(H2O)x where x = 0 or 3. They are mainly of interest by researchers, unlike the related iron(III) chloride. Anhydrous iron(III) fluoride is white, whereas the hydrated forms are light pink.

<span class="mw-page-title-main">Yttrium iron garnet</span> Synthetic garnet

Yttrium iron garnet (YIG) is a kind of synthetic garnet, with chemical composition Y3Fe2(FeO4)3, or Y3Fe5O12. It is a ferrimagnetic material with a Curie temperature of 560 K. YIG may also be known as yttrium ferrite garnet, or as iron yttrium oxide or yttrium iron oxide, the latter two names usually associated with powdered forms.

<span class="mw-page-title-main">Selenium tetrafluoride</span> Chemical compound

Selenium tetrafluoride (SeF4) is an inorganic compound. It is a colourless liquid that reacts readily with water. It can be used as a fluorinating reagent in organic syntheses (fluorination of alcohols, carboxylic acids or carbonyl compounds) and has advantages over sulfur tetrafluoride in that milder conditions can be employed and it is a liquid rather than a gas.

<span class="mw-page-title-main">Phosphorus pentafluoride</span> Chemical compound

Phosphorus pentafluoride, PF5, is a phosphorus halide. It is a colourless, toxic gas that fumes in air.

<span class="mw-page-title-main">Dysprosium(III) oxide</span> Chemical compound

Dysprosium oxide (Dy2O3) is a sesquioxide compound of the rare earth metal dysprosium. It is a pastel yellowish-greenish, slightly hygroscopic powder having specialized uses in ceramics, glass, phosphors, lasers, as a Faraday rotator and dysprosium metal halide lamps.

<span class="mw-page-title-main">Bismuth trifluoride</span> Chemical compound

Bismuth(III) fluoride or bismuth trifluoride is a chemical compound of bismuth and fluorine. The chemical formula is BiF3. It is a grey-white powder melting at 649 °C.

<span class="mw-page-title-main">Lanthanum trifluoride</span> Chemical compound

Lanthanum trifluoride is a refractory ionic compound of lanthanum and fluorine. The chemical formula is LaF
3
.

Terbium gallium garnet (TGG) is a kind of synthetic garnet, with the chemical composition Tb3Ga5O12. This is a Faraday rotator material with excellent transparency properties and is very resistant to laser damage. TGG can be used in optical isolators for laser systems, in optical circulators for fiber optic systems, in optical modulators, and in current and magnetic field sensors.

<span class="mw-page-title-main">Fluorocarbonate</span> Class of chemical compounds

A carbonate fluoride, fluoride carbonate, fluorocarbonate or fluocarbonate is a double salt containing both carbonate and fluoride. The salts are usually insoluble in water, and can have more than one kind of metal cation to make more complex compounds. Rare-earth fluorocarbonates are particularly important as ore minerals for the light rare-earth elements lanthanum, cerium and neodymium. Bastnäsite is the most important source of these elements. Other artificial compounds are under investigation as non-linear optical materials and for transparency in the ultraviolet, with effects over a dozen times greater than Potassium dideuterium phosphate.

Praseodymium(III) fluoride is an inorganic compound with the formula PrF3, being the most stable fluoride of praseodymium.

<span class="mw-page-title-main">Cerium(III) sulfide</span> Chemical compound

Cerium(III) sulfide, also known as cerium sesquisulfide, is an inorganic compound with the formula Ce2S3. It is the sulfide salt of cerium(III) and exists as three polymorphs with different crystal structures.

Einsteinium compounds are compounds that contain the element einsteinium (Es). These compounds largely have einsteinium in the +3 oxidation state, or in some cases in the +2 and +4 oxidation states. Although einsteinium is relatively stable, with half-lives ranging from 20 days upwards, these compounds have not been studied in great detail.

Einsteinium fluoride is a binary inorganic chemical compound of einsteinium and fluorine with the chemical formula EsF3.

References

  1. Holleman-Wiberg, 102. edition, p. 1942[ full citation needed ]
  2. "Fluocerite-(Ce)".
  3. "List of Minerals". 21 March 2011.
  4. Vojna, David; Yasuhara, Ryo; Slezák, Ondřej; Mužík, Jiří; Lucianetti, Antonio; Mocek, Tomáš (2017). "Verdet constant dispersion of CeF3 in the visible and near-infrared spectral range". Optical Engineering. 56 (6): 067105. Bibcode:2017OptEn..56f7105V. doi:10.1117/1.oe.56.6.067105. S2CID   125990210.
  5. Vojna, David; Slezák, Ondřej; Yasuhara, Ryo; Furuse, Hiroaki; Lucianetti, Antonio; Mocek, Tomáš (2020). "Faraday Rotation of Dy2O3, CeF3 and Y3Fe5O12 at the Mid-Infrared Wavelengths". Materials. 13 (23): 5324. Bibcode:2020Mate...13.5324V. doi: 10.3390/ma13235324 . PMC   7727863 . PMID   33255447.
  6. 1 2 3 Wells, A. F. (1984). Structural Inorganic Chemistry (5th ed.). Oxford University Press. pp. 420–421. ISBN   978-0-19-965763-6.
  7. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. pp. 1240–1241. ISBN   978-0-08-037941-8.
  8. Cheetham, A. K.; Fender, B. E. F.; Fuess, H.; Wright, A. F. (1976). "A powder neutron diffraction study of lanthanum and cerium trifluorides". Acta Crystallogr. B . 32: 94–97. doi:10.1107/S0567740876002380.