Printed electronics

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Gravure printing of electronic structures on paper Elektronikdruck.jpg
Gravure printing of electronic structures on paper

Printed electronics is a set of printing methods used to create electrical devices on various substrates. Printing typically uses common printing equipment suitable for defining patterns on material, such as screen printing, flexography, gravure, offset lithography, and inkjet. By electronic-industry standards, these are low-cost processes. Electrically functional electronic or optical inks are deposited on the substrate, creating active or passive devices, such as thin film transistors; capacitors; coils; resistors. Some researchers expect printed electronics to facilitate widespread, very low-cost, low-performance electronics for applications such as flexible displays, smart labels, decorative and animated posters, and active clothing that do not require high performance. [1]

Contents

The term printed electronics is often related[ by whom? ] to organic electronics or plastic electronics, in which one or more inks are composed of carbon-based compounds. [2] [ need quotation to verify ] These other terms refer to the ink material, which can be deposited by solution-based, vacuum-based, or other processes. Printed electronics, in contrast, specifies the process, and, subject to the specific requirements of the printing process selected, can utilize any solution-based material. This includes organic semiconductors, inorganic semiconductors, metallic conductors, nanoparticles, and nanotubes. The solution usually consist of filler materials dispersed in a suitable solvent. The most commonly used solvents include ethanol, xylene, Dimethylformamide (DMF),Dimethyl sulfoxide (DMSO), toluene and water, whereas, the most common conductive fillers include silver nanoparticles, silver flakes, carbon black, graphene, carbon nanotubes, conductive polymers (such as polyaniline and polypyrrole), and metal powders (such as copper or nickel). Considering the environmental impacts of the organic solvents, researchers are now focused on developing printable iks using water. [3] [4] [5]

For the preparation of printed electronics nearly all industrial printing methods are employed. Similar to conventional printing, printed electronics applies ink layers one atop another. [6] So the coherent development of printing methods and ink materials are the field's essential tasks. [7]

The most important benefit of printing is low-cost volume fabrication.[ citation needed ] The lower cost enables use in more applications. [8] An example is RFID-systems, which enable contactless identification in trade and transport. In some domains, such as light-emitting diodes printing does not impact performance. [6] Printing on flexible substrates allows electronics to be placed on curved surfaces, for example: printing solar cells on vehicle roofs. More typically, conventional semiconductors justify their much higher costs by providing much higher performance.

Printed and conventional electronics as complementary technologies. ComplementaryTechnologies.png
Printed and conventional electronics as complementary technologies.

Resolution, registration, thickness, holes, materials

The maximum required resolution of structures in conventional printing is determined by the human eye. Feature sizes smaller than approximately 20 µm cannot be distinguished by the human eye and consequently exceed the capabilities of conventional printing processes. [9] In contrast, higher resolution and smaller structures are necessary in most electronics printing, because they directly affect circuit density and functionality (especially transistors). A similar requirement holds for the precision with which layers are printed on top of each other (layer to layer registration).

Control of thickness, holes, and material compatibility (wetting, adhesion, solubility) are essential, but matter in conventional printing only if the eye can detect them. Conversely, the visual impression is irrelevant for printed electronics. [10]

Printing technologies

The attraction of printing technology for the fabrication of electronics mainly results from the possibility of preparing stacks of micro-structured layers (and thereby thin-film devices) in a much simpler and cost-effective way compared to conventional electronics. [11] Also, the ability to implement new or improved functionalities (e.g. mechanical flexibility) plays a role. The selection of the printing method used is determined by requirements concerning printed layers, by the properties of printed materials as well as economic and technical considerations of the final printed products.

Printing technologies divide between sheet-based and roll-to-roll-based approaches. Sheet-based inkjet and screen printing are best for low-volume, high-precision work. Gravure, offset and flexographic printing are more common for high-volume production, such as solar cells, reaching 10,000 square meters per hour (m2/h). [9] [11] While offset and flexographic printing are mainly used for inorganic [12] [13] and organic [14] [15] conductors (the latter also for dielectrics), [16] gravure printing is especially suitable for quality-sensitive layers like organic semiconductors and semiconductor/dielectric-interfaces in transistors, due to high layer quality. [16] If high resolution is needed, gravure is also suitable for inorganic [17] and organic [18] conductors. Organic field-effect transistors and integrated circuits can be prepared completely by means of mass-printing methods. [16]

Inkjet printing

Inkjets are flexible and versatile, and can be set up with relatively low effort. [19] However, inkjets offer lower throughput of around 100 m2/h and lower resolution (ca. 50 µm). [9] It is well suited for low-viscosity, soluble materials like organic semiconductors. With high-viscosity materials, like organic dielectrics, and dispersed particles, like inorganic metal inks, difficulties due to nozzle clogging occur. Because ink is deposited via droplets, thickness and dispersion homogeneity is reduced. Using many nozzles simultaneously and pre-structuring the substrate allows improvements in productivity and resolution, respectively. However, in the latter case non-printing methods must be employed for the actual patterning step. [20] Inkjet printing is preferable for organic semiconductors in organic field-effect transistors (OFETs) and organic light-emitting diodes (OLEDs), but also OFETs completely prepared by this method have been demonstrated. [21] Frontplanes [22] and backplanes [23] of OLED-displays, integrated circuits, [24] organic photovoltaic cells (OPVCs) [25] and other devices can be prepared with inkjets.

Screen printing

Screen printing is appropriate for fabricating electrics and electronics due to its ability to produce patterned, thick layers from paste-like materials. This method can produce conducting lines from inorganic materials (e.g. for circuit boards and antennas), but also insulating and passivating layers, whereby layer thickness is more important than high resolution. Its 50 m2/h throughput and 100 µm resolution are similar to inkjets. [9] This versatile and comparatively simple method is used mainly for conductive and dielectric layers, [26] [27] but also organic semiconductors, e.g. for OPVCs, [28] and even complete OFETs [22] can be printed.

Aerosol jet printing

Aerosol Jet Printing (also known as Maskless Mesoscale Materials Deposition or M3D) [29] is another material deposition technology for printed electronics. The Aerosol Jet process begins with atomization of an ink, via ultrasonic or pneumatic means, producing droplets on the order of one to two micrometers in diameter. The droplets then flow through a virtual impactor which deflects the droplets having lower momentum away from the stream. This step helps maintaining a tight droplet size distribution. The droplets are entrained in a gas stream and delivered to the print head. Here, an annular flow of clean gas is introduced around the aerosol stream to focus the droplets into a tightly collimated beam of material. The combined gas streams exit the print head through a converging nozzle that compresses the aerosol stream to a diameter as small as 10 µm. The jet of droplets exits the print head at high velocity (~50 meters/second) and impinges upon the substrate.

Electrical interconnects, passive and active components [30] are formed by moving the print head, equipped with a mechanical stop/start shutter, relative to the substrate. The resulting patterns can have features ranging from 10 µm wide, with layer thicknesses from tens of nanometers to >10 µm. [31] A wide nozzle print head enables efficient patterning of millimeter size electronic features and surface coating applications. All printing occurs without the use of vacuum or pressure chambers. The high exit velocity of the jet enables a relatively large separation between the print head and the substrate, typically 2–5 mm. The droplets remain tightly focused over this distance, resulting in the ability to print conformal patterns over three dimensional substrates.

Despite the high velocity, the printing process is gentle; substrate damage does not occur and there is generally minimal splatter or overspray from the droplets. [32] Once patterning is complete, the printed ink typically requires post treatment to attain final electrical and mechanical properties. Post-treatment is driven more by the specific ink and substrate combination than by the printing process. A wide range of materials has been successfully deposited with the Aerosol Jet process, including diluted thick film pastes, conducting polymer inks, [33] thermosetting polymers such as UV-curable epoxies, and solvent-based polymers like polyurethane and polyimide, and biologic materials. [34]

Recently, printing paper was proposed to be used as the substrate of the printing. Highly conductive (close to bulk copper) and high-resolution traces can be printed on foldable and available office printing papers, with 80°Celsius curing temperature and 40 minutes of curing time. [35]

Evaporation printing

Evaporation printing uses a combination of high precision screen printing with material vaporization to print features to 5  µm. This method uses techniques such as thermal, e-beam, sputter and other traditional production technologies to deposit materials through a high precision shadow mask (or stencil) that is registered to the substrate to better than 1 µm. By layering different mask designs and/or adjusting materials, reliable, cost-effective circuits can be built additively, without the use of photo-lithography.

Other methods

Other methods with similarities to printing, among them microcontact printing and nano-imprint lithography are of interest. [36] Here, µm- and nm-sized layers, respectively, are prepared by methods similar to stamping with soft and hard forms, respectively. Often the actual structures are prepared subtractively, e.g. by deposition of etch masks or by lift-off processes. For example, electrodes for OFETs can be prepared. [37] [38] Sporadically pad printing is used in a similar manner. [39] Occasionally so-called transfer methods, where solid layers are transferred from a carrier to the substrate, are considered printed electronics. [40] Electrophotography is currently not used in printed electronics.

Materials

Both organic and inorganic materials are used for printed electronics. Ink materials must be available in liquid form, for solution, dispersion or suspension. [41] They must function as conductors, semiconductors, dielectrics, or insulators. Material costs must be fit for the application.

Electronic functionality and printability can interfere with each other, mandating careful optimization. [10] For example, a higher molecular weight in polymers enhances conductivity, but diminishes solubility. For printing, viscosity, surface tension and solid content must be tightly controlled. Cross-layer interactions such as wetting, adhesion, and solubility as well as post-deposition drying procedures affect the outcome. Additives often used in conventional printing inks are unavailable, because they often defeat electronic functionality.

Material properties largely determine the differences between printed and conventional electronics. Printable materials provide decisive advantages beside printability, such as mechanical flexibility and functional adjustment by chemical modification (e.g. light color in OLEDs). [42]

Printed conductors offer lower conductivity and charge carrier mobility. [43]

With a few exceptions, inorganic ink materials are dispersions of metallic or semiconducting micro- and nano-particles. Semiconducting nanoparticles used include silicon [44] and oxide semiconductors. [45] Silicon is also printed as an organic precursor [46] which is then converted by pyrolisis and annealing into crystalline silicon.

PMOS but not CMOS is possible in printed electronics. [47]

Organic materials

Organic printed electronics integrates knowledge and developments from printing, electronics, chemistry, and materials science, especially from organic and polymer chemistry. Organic materials in part differ from conventional electronics in terms of structure, operation and functionality, [48] which influences device and circuit design and optimization as well as fabrication method. [49]

The discovery of conjugated polymers [43] and their development into soluble materials provided the first organic ink materials. Materials from this class of polymers variously possess conducting, semiconducting, electroluminescent, photovoltaic and other properties. Other polymers are used mostly as insulators and dielectrics.

In most organic materials, hole transport is favored over electron transport. [50] Recent studies indicate that this is a specific feature of organic semiconductor/dielectric-interfaces, which play a major role in OFETs. [51] Therefore, p-type devices should dominate over n-type devices. Durability (resistance to dispersion) and lifetime is less than conventional materials. [47]

Organic semiconductors include the conductive polymers poly(3,4-ethylene dioxitiophene), doped with poly(styrene sulfonate), (PEDOT:PSS) and poly(aniline) (PANI). Both polymers are commercially available in different formulations and have been printed using inkjet, [52] screen [26] and offset printing [14] or screen, [26] flexo [15] and gravure [18] printing, respectively.

Polymer semiconductors are processed using inkjet printing, such as poly(thiopene)s like poly(3-hexylthiophene) (P3HT) [53] and poly(9,9-dioctylfluorene co-bithiophen) (F8T2). [54] The latter material has also been gravure printed. [16] Different electroluminescent polymers are used with inkjet printing, [20] as well as active materials for photovoltaics (e.g. blends of P3HT with fullerene derivatives), [55] which in part also can be deposited using screen printing (e.g. blends of poly(phenylene vinylene) with fullerene derivatives). [28]

Printable organic and inorganic insulators and dielectrics exist, which can be processed with different printing methods. [56]

Inorganic materials

Inorganic electronics provides highly ordered layers and interfaces that organic and polymer materials cannot provide.

Silver nanoparticles are used with flexo, [13] offset [57] and inkjet. [58] Gold particles are used with inkjet. [59]

A.C. electroluminescent (EL) multi-color displays can cover many tens of square meters, or be incorporated in watch faces and instrument displays. They involve six to eight printed inorganic layers, including a copper doped phosphor, on a plastic film substrate. [60]

CIGS cells can be printed directly onto molybdenum coated glass sheets.

A printed gallium arsenide germanium solar cell demonstrated 40.7% conversion efficiency, eight times that of the best organic cells, approaching the best performance of crystalline silicon. [60]

Substrates

Printed electronics allows the use of flexible substrates, which lowers production costs and allows fabrication of mechanically flexible circuits. While inkjet and screen printing typically imprint rigid substrates like glass and silicon, mass-printing methods nearly exclusively use flexible foil and paper. Poly(ethylene terephthalate)-foil (PET) is a common choice, due to its low cost and moderately high temperature stability. [61] Poly(ethylene naphthalate)- (PEN) and poly(imide)-foil (PI) are higher performance, higher cost alternatives. Paper's low costs and manifold applications make it an attractive substrate, however, its high roughness and high wettability have traditionally made it problematic for electronics. This is an active research area, [62] however, and print-compatible metal deposition techniques have been demonstrated that adapt to the rough 3D surface geometry of paper. [63] [64]

Other important substrate criteria are low roughness and suitable wet-ability, which can be tuned pre-treatment by use of coating or Corona discharge. In contrast to conventional printing, high absorbency is usually disadvantageous.

History

Albert Hanson, a German by birth, is credited to have introduced the concept of printed electronics. in 1903 he filled a patent for “Printed Wires,” and thus printed electronics were born. [65] Hanson proposed forming a Printed Circuit Board pattern on copper foil through cutting or stamping. The drawn elements were glued to the dielectric, in this case, paraffined paper. [66] The first printed circuit was produced in 1936 by Paul Eisler, and that process was used for large-scale production of radios by the USA during World War II. Printed circuit technology was released for commercial use in the US in 1948 (Printed Circuits Handbook, 1995). In the over a half-century since its inception, printed electronics has evolved from the production of printed circuit boards (PCBs), through the everyday use of membrane switches, to today's RFID, photovoltaic and electroluminescent technologies. [67] Today it is nearly impossible to look around a modern American household and not see devices that either uses printed electronic components or that are the direct result of printed electronic technologies. Widespread production of printed electronics for household use began in the 1960s when the Printed Circuit Board became the foundation for all consumer electronics. Since then printed electronics have become a cornerstone in many new commercial products. [68]

The biggest trend in recent history when it comes to printed electronics is the widespread use of them in solar cells. In 2011, researchers from MIT created a flexible solar cell by inkjet printing on normal paper. [69] In 2018, researchers at Rice University have developed organic solar cells which can be painted or printed onto surfaces. These solar cells have been shown to max out at fifteen percent efficiency. [70] Konarka Technologies, now a defunct company in the US, was the pioneering company in producing inkjet solar cells. Today there are more than fifty companies across a diverse number of countries that are producing printed solar cells.

While printed electronics have been around since the 1960s, they are predicted[ when? ] to have a major boom in total revenue. As of 2011, the total printed electronic revenue was reported to be at $12.385 (billion). [71] A report by IDTechEx predicts the PE market will reach $330 (billion) in 2027. [72] A big reason for this increase in revenue is because of the incorporation of printed electronic into cellphones. Nokia was one of the companies that pioneered the idea of creating a “Morph” phone using printed electronics. Since then, Apple has implemented this technology into their iPhone XS, XS Max, and XR devices. [73] Printed electronics can be used to make all of the following components of a cellphone: 3D main antenna, GPS antenna, energy storage, 3D interconnections, multi-layer PCB, edge circuits, ITO jumpers, hermetic seals, LED packaging, and tactile feedback.

With the revolutionary discoveries and advantages that printed electronic gives to companies many large companies have made recent investments into this technology. In 2007, Soligie Inc. and Thinfilm Electronics entered into an agreement to combine IPs for soluble memory materials and functional materials printing to develop printed memory in commercial volumes. [67] LG announce significant investment, potentially $8.71 billion in OLEDs on Plastic. Sharp (Foxconn) will invest $570m in pilot line for OLED displays. BOE announce potential $6.8 billion in flexible AMOLED fab. Heliatek has secured €80m in additional funding for OPV manufacturing in Dresden. PragmatIC has raised ~ €20m from investors including Avery Dennison. Thinfilm invests in new production site in Silicon Valley (formerly owned by Qualcomm). Cambrios back in business after acquisition by TPK. [72]

Applications

Printed electronics are in use or under consideration include wireless sensors in packaging, skin patches that communicate with the internet, and buildings that detect leaks to enable preventative maintenance. Most of these applications are still in the prototyping and development stages. [74] There is a particularly growing interest for flexible smart electronic systems, including photovoltaic, sensing and processing devices, driven by the desire to extend and integrate the latest advances in (opto-)electronic technologies into a broad range of low-cost (even disposable) consumer products of our everyday life, and as tools to bring together the digital and physical worlds. [75]

Norwegian company ThinFilm demonstrated roll-to-roll printed organic memory in 2009. [76] [77] [78] [79]

Standards development and activities

Technical standards and road-mapping initiatives are intended to facilitate value chain development (for sharing of product specifications, characterization standards, etc.) This strategy of standards development mirrors the approach used by silicon-based electronics over the past 50 years. Initiatives include:

IPC—Association Connecting Electronics Industries has published three standards for printed electronics. All three have been published in cooperation with the Japan Electronic Packaging and Circuits Association (JPCA):

These standards, and others in development, are part of IPC's Printed Electronics Initiative.

See also

Related Research Articles

<span class="mw-page-title-main">Organic electronics</span> Field of materials science

Organic electronics is a field of materials science concerning the design, synthesis, characterization, and application of organic molecules or polymers that show desirable electronic properties such as conductivity. Unlike conventional inorganic conductors and semiconductors, organic electronic materials are constructed from organic (carbon-based) molecules or polymers using synthetic strategies developed in the context of organic chemistry and polymer chemistry.

<span class="mw-page-title-main">Inkjet printing</span> Type of computer printing

Inkjet printing is a type of computer printing that recreates a digital image by propelling droplets of ink onto paper and plastic substrates. Inkjet printers were the most commonly used type of printer in 2008, and range from small inexpensive consumer models to expensive professional machines. By 2019, laser printers outsold inkjet printers by nearly a 2:1 ratio, 9.6% vs 5.1% of all computer peripherals.

<span class="mw-page-title-main">Roll-to-roll processing</span>

In the field of electronic devices, roll-to-roll processing, also known as web processing, reel-to-reel processing or R2R, is the process of creating electronic devices on a roll of flexible plastic, metal foil, or flexible glass. In other fields predating this use, it can refer to any process of applying coating, printing, or performing other processes starting with a roll of a flexible material and re-reeling after the process to create an output roll. These processes, and others such as sheeting, can be grouped together under the general term converting. When the rolls of material have been coated, laminated or printed they can be subsequently slit to their finished size on a slitter rewinder.

<span class="mw-page-title-main">OLED</span> Diode that emits light from an organic compound

An organic light-emitting diode (OLED), also known as organic electroluminescentdiode, is a type of light-emitting diode (LED) in which the emissive electroluminescent layer is an organic compound film that emits light in response to an electric current. This organic layer is situated between two electrodes; typically, at least one of these electrodes is transparent. OLEDs are used to create digital displays in devices such as television screens, computer monitors, and portable systems such as smartphones and handheld game consoles. A major area of research is the development of white OLED devices for use in solid-state lighting applications.

A thin-film transistor (TFT) is a special type of field-effect transistor (FET) where the transistor is made by thin film deposition. TFTs are grown on a supporting substrate, such as glass. This differs from the conventional bulk metal oxide field effect transistor (MOSFET), where the semiconductor material typically is the substrate, such as a silicon wafer. The traditional application of TFTs is in TFT liquid-crystal displays.

<span class="mw-page-title-main">Flexible electronics</span> Mounting of electronic devices on flexible plastic substrates

Flexible electronics, also known as flex circuits, is a technology for assembling electronic circuits by mounting electronic devices on flexible plastic substrates, such as polyimide, PEEK or transparent conductive polyester film. Additionally, flex circuits can be screen printed silver circuits on polyester. Flexible electronic assemblies may be manufactured using identical components used for rigid printed circuit boards, allowing the board to conform to a desired shape, or to flex during its use.

<span class="mw-page-title-main">Conductive polymer</span> Organic polymers that conduct electricity

Conductive polymers or, more precisely, intrinsically conducting polymers (ICPs) are organic polymers that conduct electricity. Such compounds may have metallic conductivity or can be semiconductors. The main advantage of conductive polymers is that they are easy to process, mainly by dispersion. Conductive polymers are generally not thermoplastics, i.e., they are not thermoformable. But, like insulating polymers, they are organic materials. They can offer high electrical conductivity but do not show similar mechanical properties to other commercially available polymers. The electrical properties can be fine-tuned using the methods of organic synthesis and by advanced dispersion techniques.

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<span class="mw-page-title-main">Flexible organic light-emitting diode</span> Type of computer monitor

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<span class="mw-page-title-main">Organic field-effect transistor</span> Type of field-effect transistor

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poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) is a polymer mixture of two ionomers. One component in this mixture is made up of polystyrene sulfonate which is a sulfonated polystyrene. Part of the sulfonyl groups are deprotonated and carry a negative charge. The other component poly(3,4-ethylenedioxythiophene) (PEDOT) is a conjugated polymer and carries positive charges and is based on polythiophene. Together the charged macromolecules form a macromolecular salt.

Conductive ink is an ink that results in a printed object which conducts electricity. It is typically created by infusing graphite or other conductive materials into ink. There has been a growing interest in replacing metallic materials with nanomaterials due to the emergence of nanotechnology. Among other nanomaterials, graphene, and carbon nanotube-based conductive ink are gaining immense popularity due to their high electrical conductivity and high surface area. Recently, more attention has been paid on using eco-friendly conductive ink using water as a solvent as compared to organic solvents since they are harmful to the environment. However, the high surface tension of water prevents its applicability. Various natural and synthetic surfactants are now used to reduce the surface tension of water and ensure uniform nanomaterials dispersibility for smooth printing and wide application. Although graphene oxide inks are eco-friendly and can be produced in bulk quantities, they are insulating in nature which needs an additional step of reduction using reducing ink is required to restore the electrical properties. The external reduction process is not suitable for large scale continuous manufacturing of electronic devices. Hence an in-situ reduction process also known as reactive inkjet printing has been developed by various scientists. In the in-situ reduction process the reducing inks are printed on top of the GO printed patterns in order to carry out the reduction process on the substrate.

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References

  1. ↑ Coatanéa, E., Kantola, V., Kulovesi, J., Lahti, L., Lin, R., & Zavodchikova, M. (2009). Printed Electronics, Now and Future. In Neuvo, Y., & Ylönen, S. (eds.), Bit Bang – Rays to the Future. Helsinki University of Technology (TKK), MIDE, Helsinki University Print, Helsinki, Finland, 63-102. ISBN   978-952-248-078-1. http://lib.tkk.fi/Reports/2009/isbn9789522480781.pdf - "Moreover, PE technology could provide a number of enabling factors like flexibility and robustness, allowing incorporation of electronics functions into objects that do not yet contain any active electronic components, e.g. toy applications, printed advertising material or electronic labels [...]."
  2. ↑ "Printed & Flexible Electronics - IDTechEx Research Reports and Subscriptions". www.idtechex.com. Retrieved 2020-09-21.
  3. ↑ Khan, Junaid; Mariatti, M; Zubir, Syazana A; Rusli, Arjulizan; Manaf, Asrulnizam Abd; Khirotdin, Rd Khairilhijra (29 January 2024). "Eco-friendly alkali lignin-assisted water-based graphene oxide ink and its application as a resistive temperature sensor". Nanotechnology. 35 (5): 055301. doi:10.1088/1361-6528/ad06d4.
  4. ↑ Khan, Junaid; Mariatti, M (1 September 2023). "In-situ graphene oxide reduction via inkjet printing using natural reducing inks". Flexible and Printed Electronics. 8 (3): 035009. doi:10.1088/2058-8585/acf143.
  5. ↑ Khan, Junaid; Mariatti, M. (November 2022). "Effect of natural surfactant on the performance of reduced graphene oxide conductive ink". Journal of Cleaner Production. 376: 134254. doi:10.1016/j.jclepro.2022.134254.
  6. 1 2 Roth, H.-K.; et al. (2001). "Organische Funktionsschichten in Polymerelektronik und Polymersolarzellen". Materialwissenschaft und Werkstofftechnik. 32 (10): 789. doi:10.1002/1521-4052(200110)32:10<789::AID-MAWE789>3.0.CO;2-E.
  7. ↑ Thomas, D.J. (2016). "Integration of Silicon and Printed Electronics for Rapid Diagnostic Disease Biosensing". Point of Care: The Journal of Near-Patient Testing & Technology. 15 (2): 61–71. doi:10.1097/POC.0000000000000091. S2CID   77379659.
  8. ↑ Xu, J.M.(Jimmy) (2000). "Plastic electronics and future trends in microelectronics". Synthetic Metals. 115 (1–3): 1–3. doi:10.1016/s0379-6779(00)00291-5.
  9. 1 2 3 4 A. Blayo and B. Pineaux, Joint sOC-EUSAI Conference, Grenoble, 2005.
  10. 1 2 U. Fügmann et al., mstNews 2 (2006) 13.
  11. 1 2 J. R. Sheats, Journal of Materials Research 2004; 19 1974.
  12. ↑ Harrey, P.M.; et al. (2002). "Capacitive-type humidity sensors fabricated using the offset lithographic printing process". Sensors and Actuators B. 87 (2): 226–232. doi:10.1016/s0925-4005(02)00240-x.
  13. 1 2 J. Siden et al., Polytronic Conference, Wroclaw, 2005.
  14. 1 2 Zielke, D.; et al. (2005). "Polymer-based organic field-effect transistor using offset printed source/drain structures". Applied Physics Letters. 87 (12): 123508. doi:10.1063/1.2056579.
  15. 1 2 Mäkelä, T.; et al. (2005). "Utilizing roll-to-roll techniques for manufacturing source-drain electrodes for all-polymer transistors". Synthetic Metals. 153 (1–3): 285–288. doi:10.1016/j.synthmet.2005.07.140.
  16. 1 2 3 4 Hübler, A.; et al. (2007). "Ring oscillator fabricated completely by means of mass-printing technologies". Organic Electronics. 8 (5): 480. doi:10.1016/j.orgel.2007.02.009.
  17. ↑ S. Leppavuori et al., Sensors and Actuators 41-42 (1994) 593.
  18. 1 2 Mäkelä, T.; et al. (2003). "Roll-to-roll method for producing polyaniline patterns on paper". Synthetic Metals. 135: 41. doi:10.1016/s0379-6779(02)00753-1.
  19. ↑ Parashkov, R.; et al. (2005). "Large Area Electronics Using Printing Methods". Proceedings of the IEEE. 93 (7): 1321–1329. doi:10.1109/jproc.2005.850304. S2CID   27061013.
  20. 1 2 de Gans, B.‐J.; et al. (2004). "Inkjet Printing of Polymers: State of the Art and Future Developments". Advanced Materials. 16 (3): 203. doi:10.1002/adma.200300385.
  21. ↑ Subramanian, V.; et al. (2005). "Progress Toward Development of All-Printed RFID Tags: Materials, Processes, and Devices". Proceedings of the IEEE. 93 (7): 1330. doi:10.1109/jproc.2005.850305. S2CID   8915461.
  22. 1 2 S. Holdcroft, Advanced Materials 2001; 13 1753.
  23. ↑ Arias, A.C.; et al. (2004). "All jet-printed polymer thin-film transistor active-matrix backplanes". Applied Physics Letters. 85 (15): 3304. doi:10.1063/1.1801673.
  24. ↑ Sirringhaus, H.; et al. (2000). "High-Resolution Inkjet Printing of All-Polymer Transistor Circuits". Science. 290 (5499): 2123–2126. doi:10.1126/science.290.5499.2123. PMID   11118142.
  25. ↑ V.G. Shah and D.B. Wallace, IMAPS Conference, Long Beach, 2004.
  26. 1 2 3 Bock, K.; et al. (2005). "Polymer Electronics Systems - Polytronics". Proceedings of the IEEE. 93 (8): 1400–1406. doi:10.1109/jproc.2005.851513. S2CID   23177369.
  27. ↑ Bao, Z.; et al. (1997). "High-Performance Plastic Transistors Fabricated by Printing Techniques". Chemistry of Materials. 9 (6): 1299–1301. doi:10.1021/cm9701163.
  28. 1 2 Shaheen, S.E.; et al. (2001). "Fabrication of bulk heterojunction plastic solar cells by screen printing". Applied Physics Letters. 79 (18): 2996. doi:10.1063/1.1413501.
  29. ↑ M. Renn, US Patent number 7,485,345 B2. Page 3.
  30. ↑ J.H. Cho et al, Nature Materials, 19 October 2008.
  31. ↑ B. Kahn, Organic and Printed Electronics, Volume 1, Issue 2 (2007).
  32. ↑ B. H. King et al, Photovoltaic Specialists Conference (PVSC), 2009 34th IEEE.
  33. ↑ Fisher, Christine; Warmack, Bruce J.; Yu, Yongchao; Skolrood, Lydia N.; Li, Kai; Joshi, Pooran C.; Saito, Tomonori; Aytug, Tolga (2021-04-19). "All-aerosol-jet-printed highly sensitive and selective polyaniline-based ammonia sensors: a route toward low-cost, low-power gas detection". Journal of Materials Science. 56 (22): 12596–12606. doi:10.1007/s10853-021-06080-0. ISSN   1573-4803. S2CID   233303736.
  34. ↑ Ingo Grunwald et al, 2010 Biofabrication 2 014106.
  35. ↑ Chen, Yi-Dan; Nagarajan, Vijayasarathi; Rosen, David W.; Yu, Wenwei; Huang, Shao Ying (Oct 2020). "Wireless Power Transfer via Strongly Coupled Magnetic Resonances". Journal of Manufacturing Processes. 58: 55–66. doi:10.1016/j.jmapro.2020.07.064.
  36. ↑ Gate, B.D.; et al. (2005). "New Approaches to Nanofabrication: Molding, Printing, and Other Techniques". Chemical Reviews. 105 (4): 1171–96. doi:10.1021/cr030076o. PMID   15826012.
  37. ↑ Li, D.; Guo, L.J. (2006). "Micron-scale organic thin film transistors with conducting polymer electrodes patterned by polymer inking and stamping" (PDF). Applied Physics Letters. 88 (6): 063513. doi:10.1063/1.2168669. hdl: 2027.42/87779 .
  38. ↑ Leising, G.; et al. (2006). "Nanoimprinted devices for integrated organic electronics". Microelectronics Engineering. 83 (4–9): 831. doi:10.1016/j.mee.2006.01.241.
  39. ↑ Knobloch, A.; et al. (2004). "Fully printed integrated circuits from solution processable polymers". Journal of Applied Physics. 96 (4): 2286. doi:10.1063/1.1767291.
  40. ↑ Hines, D.R.; et al. (2007). "Transfer printing methods for the fabrication of flexible organic electronics". Journal of Applied Physics. 101 (2): 024503. doi:10.1063/1.2403836.
  41. ↑ Z. Bao, Advanced Materials 2000; 12: 227.
  42. ↑ Moliton; Hiorns, R.C. (2004). "Review of electronic and optical properties of semiconductingπ-conjugated polymers: applications in optoelectronics". Polymer International. 53 (10): 1397–1412. doi:10.1002/pi.1587.
  43. 1 2 http://nobelprize.org/nobel_prizes/chemistry/laureates/2000/chemadv.pdf Nobel prize in chemistry, 2000
  44. ↑ Maennl, U.; et al. (2013). "Interfacial and Network Characteristics of Silicon Nanoparticle Layers Used in Printed Electronics". Japanese Journal of Applied Physics. 52 (5S1): 05DA11. doi:10.7567/JJAP.52.05DA11.
  45. ↑ Faber, H.; et al. (2009). "Low-Temperature Solution-Processed Memory Transistors Based on Zinc Oxide Nanoparticles". Advanced Materials. 21 (30): 3099. doi:10.1002/adma.200900440.
  46. ↑ Shimoda, T.; et al. (2006). "Solution-processed silicon films and transistors". Nature. 440 (7085): 783–786. doi:10.1038/nature04613. PMID   16598254. S2CID   4344708.
  47. 1 2 de Leeuw, D. M.; et al. (1997). "Stability of n-type doped conducting polymers and consequences for polymeric microelectronic devices". Synthetic Metals. 87: 53. doi:10.1016/s0379-6779(97)80097-5.
  48. ↑ Vardeny, Z.V.; et al. (2005). "Fundamental research needs in organic electronic materials". Synthetic Metals. 148: 1. doi:10.1016/j.synthmet.2004.09.001.
  49. ↑ H. Kempa et al., it 3 (2008) 167.
  50. ↑ Fachetti (2007). "Semiconductors for organic transistors". Materials Today. 10 (3): 38. doi: 10.1016/S1369-7021(07)70017-2 .
  51. ↑ Zaumseil, J.; Sirringhaus, H. (2007). "Electron and Ambipolar Transport in Organic Field-Effect Transistors". Chemical Reviews. 107 (4): 1296–1323. doi:10.1021/cr0501543. PMID   17378616.
  52. ↑ Bharathan, J.; Yang, Y. (2006). "Polymer electroluminescent devices processed by inkjet printing: I. Polymer light-emitting logo". Applied Physics Letters. 72 (21): 2660. doi:10.1063/1.121090.
  53. ↑ Speakman, S.P.; et al. (2001). "High performance organic semiconducting thin films: Ink jet printed polythiophene [rr-P3HT]". Organic Electronics. 2 (2): 65. doi:10.1016/S1566-1199(01)00011-8.
  54. ↑ Paul, K.E.; et al. (2003). "Additive jet printing of polymer thin-film transistors". Applied Physics Letters. 83 (10): 2070. doi:10.1063/1.1609233.
  55. ↑ Aernouts, T.; et al. (2008). "Polymer based organic solar cells using ink-jet printed active layers". Applied Physics Letters. 92 (3): 033306. doi:10.1063/1.2833185.
  56. ↑ "Ion Gel Insulator". Archived from the original on November 14, 2011.
  57. ↑ Harrey, P. M.; et al. (2000). "Interdigitated Capacitors by Offset Lithography". Journal of Electronics Manufacturing. 10: 69–77. doi:10.1142/s096031310000006x.
  58. ↑ Perelaer, J.; et al. (2006). "Ink-jet Printing and Microwave Sintering of Conductive Silver Tracks". Advanced Materials. 18 (16): 2101–2104. doi:10.1002/adma.200502422.
  59. ↑ Noh, Y.-Y.; et al. (2007). "Downscaling of self-aligned, all-printed polymer thin-film transistors". Nature Nanotechnology. 2 (12): 784–789. doi:10.1038/nnano.2007.365. PMID   18654432.
  60. 1 2 Mflex UK (formerly Pelikon) and elumin8, both in the UK, Emirates Technical Innovation Centre in Dubai, Schreiner in Germany and others are involved in EL displays. Spectrolab already offers commercially flexible solar cells based on various inorganic compounds.
  61. ↑ Carey, T., Cacovich, S., Divitini, G., Ren, J., Mansouri, A., Kim, J. M., ... & Torrisi, F. (2017). Fully inkjet-printed two-dimensional material field-effect heterojunctions for wearable and textile electronics. Nature communications, 8(1), 1-11.https://doi.org/10.1038/s41467-017-01210-2
  62. ↑ Tobjörk, Daniel; Österbacka, Ronald (2011-03-23). "Paper Electronics". Advanced Materials. 23 (17): 1935–1961. doi:10.1002/adma.201004692. ISSN   0935-9648. PMID   21433116.
  63. ↑ Grell, Max; Dincer, Can; Le, Thao; Lauri, Alberto; Nunez Bajo, Estefania; Kasimatis, Michael; Barandun, Giandrin; Maier, Stefan A.; Cass, Anthony E. G. (2018-11-09). "Autocatalytic Metallization of Fabrics Using Si Ink, for Biosensors, Batteries and Energy Harvesting". Advanced Functional Materials. 29 (1): 1804798. doi: 10.1002/adfm.201804798 . ISSN   1616-301X. PMC   7384005 . PMID   32733177.
  64. ↑ Vicente, António T.; Araújo, Andreia; Gaspar, Diana; Santos, Lídia; Marques, Ana C.; Mendes, Manuel J.; Pereira, Luís; Martins, Elvira Fortunato and Rodrigo (2017-02-22). Optoelectronics and Bio Devices on Paper Powered by Solar Cells. IntechOpen. ISBN   978-953-51-2936-3.
  65. ↑ GB 4681,Hanson, Albert,"Printed Wires",issued 1903
  66. ↑ "The printed circuit board is the base of modern electronics". rostec.ru. Rostec. November 24, 2014. Archived from the original on August 28, 2019. Retrieved November 28, 2018.
  67. 1 2 Jacobs, John (2010). An Investigation of Fundamental Competencies for Printed Electronics (Thesis). Clemson University.
  68. ↑ "Printing Electronics Just", National Geographic News, National Geographic Partners, LLC, 10 May 2013, archived from the original on May 13, 2013, retrieved November 30, 2018
  69. ↑ "While You're Pp, Print Me a Solar Cell", MIT News, MIT News Office, retrieved November 30, 2018
  70. ↑ "Stretchy solar cells a step closer", Printed Electronics World, IDTechEx, 15 November 2018, retrieved November 30, 2018
  71. ↑ Zhang, Chuck, Printed Electronics:Manufacturing Technologies and Applications (PDF), Georgia Tech, retrieved November 30, 2018
  72. 1 2 Das, Raghu, Printed Electronics: Markets, Technologies, Trends (PDF), IDTechEx, retrieved November 30, 2018
  73. ↑ "New iPhones models support native 'background' NFC tag read function" (Press release). Thinfilm. Retrieved November 30, 2018– via IDTechEx.
  74. ↑ "Custom Printed Electronics". Almax - RP. 30 December 2016. Retrieved 13 August 2021.
  75. ↑ Vicente, António T.; Araújo, Andreia; Mendes, Manuel J.; Nunes, Daniela; Oliveira, Maria J.; Sanchez-Sobrado, Olalla; Ferreira, Marta P.; Águas, Hugo; Fortunato, Elvira; Martins, Rodrigo (2018-03-29). "Multifunctional cellulose-paper for light harvesting and smart sensing applications". Journal of Materials Chemistry C. 6 (13): 3143–3181. doi:10.1039/C7TC05271E. ISSN   2050-7534.
  76. ↑ Thinfilm and InkTec awarded IDTechEx' Technical Development Manufacturing Award IDTechEx, April 15th 2009
  77. ↑ PolyIC, ThinFilm announce pilot of volume printed plastic memories EETimes, September 22nd 2009
  78. ↑ All set for high-volume production of printed memories Printed Electronics World, April 12th 2010
  79. ↑ Thin Film Electronics Plans to Provide ‘Memory Everywhere’ Printed Electronics Now, May 2010
  80. ↑ "IEEE P1620 Index page". Archived from the original on 2011-06-10. Retrieved 2006-11-30.
  81. ↑ "IEEE P1620.1 Index page". Archived from the original on 2011-06-10. Retrieved 2006-11-30.
  82. ↑ "iNEMI | International Electronics Manufacturing Initiative". www.inemi.org.

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