Phonolite

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Phonolite
Clinkstone
Extrusive igneous rock
Aegirine-phonolite2-2005.jpg
Dark, prismatic phenocrysts of aegirine in phonolite sample
Composition
Primary nepheline, sodalite, hauyne, leucite, analcite, sanidine, anorthoclase
Secondary biotite, amphibole, pyroxene, olivine
Demonstration of sound produced when phonolite is struck, Cerro de la Campana (Hermosillo, Sonora, Mexico)
Lithophone made of Phonolite in Schellerhau botanic garden (Germany) Schellerhau Botanischer Garten Lithophon (01).JPG
Lithophone made of Phonolite in Schellerhau botanic garden (Germany)

Phonolite is an uncommon shallow intrusive or extrusive rock, of intermediate chemical composition between felsic and mafic, with texture ranging from aphanitic (fine-grained) to porphyritic (mixed fine- and coarse-grained). Phonolite is a variation of the igneous rock trachyte that contains nepheline or leucite rather than quartz. [1] It has an unusually high (12% or more) Na2O + K2O content, defining its position in the TAS classification of igneous rocks. Its coarse grained (phaneritic) intrusive equivalent is nepheline syenite. Phonolite is typically fine grained and compact. The name phonolite comes from the Ancient Greek meaning "sounding stone" due to the metallic sound it produces if an unfractured plate is hit; hence, the English name clinkstone is given as a synonym.

Contents

Formation

Unusually, phonolite forms from magma with a relatively low silica content, generated by low degrees of partial melting (less than 10%) of highly aluminous rocks of the lower crust such as tonalite, monzonite and metamorphic rocks. Melting of such rocks to a very low degree promotes the liberation of aluminium, potassium, sodium and calcium by melting of feldspar, with some involvement of mafic minerals. Because the rock is silica-undersaturated, it has no quartz or other silica crystals, and is dominated by low-silica feldspathoid minerals more than feldspar minerals.

A few geological processes and tectonic events can melt the necessary precursor rocks to form phonolite. These include intracontinental hotspot volcanism, [2] such as may form above mantle plumes covered by thick continental crust. A-type granites and alkaline igneous provinces usually occur alongside phonolites. Low-degree partial melting of underplates of granitic material in collisional orogenic belts may also produce phonolites.

Mineralogy and petrology

Total alkali vs. silica classification scheme (TAS), as proposed in Le Maitre's 2002 Igneous Rocks - A classification and glossary of terms Petrology Igneous.svg
Total alkali vs. silica classification scheme (TAS), as proposed in Le Maitre's 2002 Igneous Rocks – A classification and glossary of terms

Phonolite is a fine-grained equivalent of nepheline syenite. They are products of partial melting, are silica-undersaturated, and have feldspathoids in their normative mineralogy.

Mineral assemblages in phonolite occurrences are usually abundant feldspathoids (nepheline, sodalite, hauyne, leucite and analcite) and alkali feldspar (sanidine, anorthoclase or orthoclase), and rare sodic plagioclase. Biotite, sodium-rich amphiboles and pyroxenes along with iron-rich olivine are common minor minerals. Accessory phases include titanite, apatite, corundum, zircon, magnetite and ilmenite. [4] Phonolite's characteristic dark color comes from its concentration of dark pyroxenes such as aegirine and augite.

Blairmorite is an analcite-rich variety of phonolite. [5] [6]

Phonolite dike in Haddinnet in Ethiopia Dyke in Tsili.jpg
Phonolite dike in Haddinnet in Ethiopia

Occurrence

Outcrop of phonolite at Beemerville Complex, New Jersey Phonolite Beemerville Complex NJ.jpg
Outcrop of phonolite at Beemerville Complex, New Jersey

Nepheline syenites and phonolites occur widely distributed throughout the world [7] in Canada, Norway, Greenland, Sweden, the United Kingdom, the Ural Mountains, the Pyrenees, Italy, Eifel and Kaiserstuhl in Germany, Brazil, the Transvaal region, the Magnet Cove igneous complex of Arkansas, the Beemerville Complex of New Jersey, [8] as well as on oceanic islands such as the Canary Islands. [9]

Phonolite is common across Europe, particularly within the Eifel Plateau and the Laacher See. It is also found in the Czech Republic and the Mediterranean area near Italy. For localities in the United States, phonolite can be found in the Black Hills Forest in South Dakokta. The most well known phonolite-composed natural structure is the Devil's Tower, found in Wyoming. [1]

Nepheline-normative rocks occur in close association with the Bushveld Igneous Complex, possibly formed from partial melting of the wall rocks adjacent to that large ultramafic layered intrusion. Phonolite occurs in the related Pilanesberg Complex and Pienaars River Complex. [10]

Examples

North America

Porphyritic phonolite at Devils Tower Phonolite Porphyry of Devils Tower in Wyoming in USA - with scale.jpg
Porphyritic phonolite at Devils Tower

Europe

Other

Economic importance

Phonolites can be of interest as dimension stone or as aggregate for gravels.

Rarely, economically mineralised phonolite-nepheline syenite alkaline complexes can be associated with rare-earth mineralisation, uranium mineralisation and phosphates, such as at Phalaborwa, South Africa.

Phonolite tuff was used as a source of flint for adze heads and such by prehistoric people from Hohentwiel and Hegau, Germany. [18]

Phonolites can be separated into slabs of appropriate dimensions to be used as roofing tiles in place of roofing slate. One such occurrence is in the French Massif Central region such as the Haute Loire département.[ citation needed ]

Related Research Articles

<span class="mw-page-title-main">Gabbro</span> Coarse-grained mafic intrusive rock

Gabbro is a phaneritic (coarse-grained), mafic intrusive igneous rock formed from the slow cooling of magnesium-rich and iron-rich magma into a holocrystalline mass deep beneath the Earth's surface. Slow-cooling, coarse-grained gabbro is chemically equivalent to rapid-cooling, fine-grained basalt. Much of the Earth's oceanic crust is made of gabbro, formed at mid-ocean ridges. Gabbro is also found as plutons associated with continental volcanism. Due to its variant nature, the term gabbro may be applied loosely to a wide range of intrusive rocks, many of which are merely "gabbroic". By rough analogy, gabbro is to basalt as granite is to rhyolite.

<span class="mw-page-title-main">Syenite</span> Intrusive igneous rock

Syenite is a coarse-grained intrusive igneous rock with a general composition similar to that of granite, but deficient in quartz, which, if present at all, occurs in relatively small concentrations. It is considered a granitoid. Some syenites contain larger proportions of mafic components and smaller amounts of felsic material than most granites; those are classed as being of intermediate composition.

<span class="mw-page-title-main">Trachyte</span> Extrusive igneous rock

Trachyte is an extrusive igneous rock composed mostly of alkali feldspar. It is usually light-colored and aphanitic (fine-grained), with minor amounts of mafic minerals, and is formed by the rapid cooling of lava enriched with silica and alkali metals. It is the volcanic equivalent of syenite.

<span class="mw-page-title-main">Basanite</span> Type of volcanic rock

Basanite is an igneous, volcanic (extrusive) rock with aphanitic to porphyritic texture. It is composed mostly of feldspathoids, pyroxenes, olivine, and plagioclase and forms from magma low in silica and enriched in alkali metal oxides that solidifies rapidly close to the Earth's surface.

<span class="mw-page-title-main">Nepheline</span> Silica-undersaturated aluminosilicate mineral

Nepheline, also called nephelite (from Ancient Greek νεφέλη (nephélē) 'cloud'), is a rock-forming mineral in the feldspathoid group – a silica-undersaturated aluminosilicate, Na3KAl4Si4O16, that occurs in intrusive and volcanic rocks with low silica, and in their associated pegmatites. It is used in glass and ceramic manufacturing and other industries, and has been investigated as an ore of aluminium.

<span class="mw-page-title-main">Nepheline syenite</span> Holocrystalline plutonic rock

Nepheline syenite is a holocrystalline plutonic rock that consists largely of nepheline and alkali feldspar. The rocks are mostly pale colored, grey or pink, and in general appearance they are not unlike granites, but dark green varieties are also known. Phonolite is the fine-grained extrusive equivalent.

<span class="mw-page-title-main">Lamprophyre</span> Ultrapotassic igneous rocks

Lamprophyres are uncommon, small-volume ultrapotassic igneous rocks primarily occurring as dikes, lopoliths, laccoliths, stocks, and small intrusions. They are alkaline silica-undersaturated mafic or ultramafic rocks with high magnesium oxide, >3% potassium oxide, high sodium oxide, and high nickel and chromium.

<span class="mw-page-title-main">Carbonatite</span> Igneous rock with more than 50% carbonate minerals

Carbonatite is a type of intrusive or extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geochemical verification.

<span class="mw-page-title-main">Essexite</span> Igneous rock type

Essexite, also called nepheline monzogabbro, is a dark gray or black holocrystalline plutonic igneous rock. Its name is derived from the type locality in Essex County, Massachusetts, in the United States.

Theralite is, in petrology, the name given to calcic foidal gabbro, a plutonic hylocrystalline rock consisting of augite, olivine, calcic plagioclase (labradorite), and nepheline, along with accessories including biotite, magnetite, ilmenite and analcime.

<span class="mw-page-title-main">Hauyne</span> Tectosilicate mineral with sometimes a blue colour due to a cyclic trisulfide anion

Hauyne or haüyne, also called hauynite or haüynite, is a tectosilicate sulfate mineral with endmember formula Na3Ca(Si3Al3)O12(SO4). As much as 5 wt % K2O may be present, and also H2O and Cl. It is a feldspathoid and a member of the sodalite group. Hauyne was first described in 1807 from samples discovered in Vesuvian lavas in Monte Somma, Italy, and was named in 1807 by Brunn-Neergard for the French crystallographer René Just Haüy (1743–1822). It is sometimes used as a gemstone.

Borolanite is an historical petrological name for a pyroxene-melanite bearing nepheline syenite variety which contains nepheline-alkali feldspar pseudomorphs interpreted to be after leucite which occur as conspicuous white spots in the dark rock matrix. The rock occurs in the Borralan Igneous Complex or Loch Borralan Complex which is an alkalic igneous complex near Loch Borralan in northwest Scotland.

<span class="mw-page-title-main">Leucitite</span>

Leucitite or leucite rock is an igneous rock containing leucite. It is scarce, many countries such as England being entirely without them. However, they are of wide distribution, occurring in every quarter of the globe. Taken collectively, they exhibit a considerable variety of types and are of great interest petrographically. For the presence of this mineral it is necessary that the silica percentage of the rock should be low, since leucite is incompatible with free quartz and reacts with it to form potassium feldspar. Because it weathers rapidly, leucite is most common in lavas of recent and Tertiary age, which have a fair amount of potassium, or at any rate have potassium equal to or greater than sodium; if sodium is abundant nepheline occurs rather than leucite.

<span class="mw-page-title-main">Case hardening of rocks</span>

Case hardening is a weathering phenomenon of rock surface induration. It is observed commonly in: felsic alkaline rocks, such as nepheline syenite, phonolite and trachyte; pyroclastic rocks, as pyroclastic flow deposit, fine air-fall deposits and vent-filling pyroclastic deposits; sedimentary rocks, as sandstone and mudstone.

<span class="mw-page-title-main">Shonkinite</span> Intrusive igneous rock

Shonkinite is an intrusive igneous rock found in few places in the world. It is unique in having low silica, feldspathoid minerals, and large blocky crystals of black augite. It makes up much of the hard dark grey rock comprising certain mountains and buttes in Montana that are remnants of laccoliths and stocks, such as the Highwood mountains.

<span class="mw-page-title-main">Igneous rock</span> Rock formed through the cooling and solidification of magma or lava

Igneous rock, or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.

<span class="mw-page-title-main">Rutan Hill</span> Hill in New Jersey, United States

Rutan Hill is the local name for a hill on the United States Geological Survey Branchville 7.5-minute map. It is located about 2.46 miles (3.96 km) south-southwest of Colesville, New Jersey in Wantage Township, of Sussex County, New Jersey in the United States. Rutan Hill rises about 270 feet (82 m) above the adjacent creek valley to an elevation of just over 1,020 feet (310 m). This hill lies entirely within private, posted property. This nondescript hill is the surface expression of a diatreme that is the northern part of the Late Ordovician Beemerville Alkaline Complex.

The alkaline magma series is a chemically distinct range of magma compositions that describes the evolution of an alkaline mafic magma into a more evolved, silica-rich end member.

<span class="mw-page-title-main">Red Hill Syenite</span>

The Red Hill Syenite is a layered igneous rock complex in central New Hampshire, about 20 mi (32 km) east of Plymouth. The Red Hill Syenite is part of the White Mountain magma series, which underlays the White Mountains of New Hampshire. Red Hill is roughly oval-shaped, covers just under 7.7 square miles (20 km2), and has a summit elevation of 2,028 feet (618 m).

References

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