Molybdenum monophosphide

Last updated
Molybdenum monophosphide
MoP unit cell.png
Names
IUPAC name
Phosphanylidynemolybdenum
Identifiers
3D model (JSmol)
ECHA InfoCard 100.032.090 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 235-312-8
  • InChI=1S/Mo.P
    Key: AMWVZPDSWLOFKA-UHFFFAOYSA-N
  • [Mo]#P
Properties
MoP
Molar mass 126.92 g·mol−1
Appearanceblack crystals
Density 7.34 g/cm3
insoluble
Hazards
GHS labelling:
GHS-pictogram-exclam.svg
Warning
H319, H335
P261, P280, P304, P305, P338, P340, P351, P405, P501
Related compounds
Related compounds
Trimolybdenum phosphide, molybdenum diphosphide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Molybdenum monophosphide is a binary inorganic compound of molybdenum metal and phosphorus with the chemical formula MoP. [1] [2] [3]

Contents

Preparation

Molybdenum monophosphide can be obtained from electrolysis of molten molybdenum hexametaphosphate: [4]

4 Mo(PO3)6 → 4 MoP + 10 P2O5 + 9 O2

It can also be prepared from heating of a mixture of molybdenum and metaphosphoric acid in a carbon crucible:

2 Mo + 2 HPO3 + 5 C → 2 MoP + 5 CO + H2O

Other reactions are known too. [5] [6]

Properties

Molybdenum monophosphide forms black crystals of hexagonal crystal system with space group P6m2. [7] It is insoluble in water. Molybdenum monophosphide decomposes when heated in air:

4 MoP + 11 O2 → 4 MoO3 + 2 P2O5

Uses

Molybdenum monophosphide can be used as a catalyst. [8] [9]

Related Research Articles

<span class="mw-page-title-main">Rhenium</span> Chemical element, symbol Re and atomic number 75

Rhenium is a chemical element; it has symbol Re and atomic number 75. It is a silvery-gray, heavy, third-row transition metal in group 7 of the periodic table. With an estimated average concentration of 1 part per billion (ppb), rhenium is one of the rarest elements in the Earth's crust. It has the third-highest melting point and second-highest boiling point of any element at 5869 K. It resembles manganese and technetium chemically and is mainly obtained as a by-product of the extraction and refinement of molybdenum and copper ores. It shows in its compounds a wide variety of oxidation states ranging from −1 to +7.

<span class="mw-page-title-main">Molybdenum disulfide</span> Chemical compound

Molybdenum disulfide is an inorganic compound composed of molybdenum and sulfur. Its chemical formula is MoS
2
.

Molybdenum trioxide describes a family of inorganic compounds with the formula MoO3(H2O)n where n = 0, 1, 2. The anhydrous compound is produced on the largest scale of any molybdenum compound since it is the main intermediate produced when molybdenum ores are purified. The anhydrous oxide is a precursor to molybdenum metal, an important alloying agent. It is also an important industrial catalyst. It is a yellow solid, although impure samples can appear blue or green.

<span class="mw-page-title-main">Sodium phosphide</span> Chemical compound

Sodium phosphide is the inorganic compound with the formula Na3P. It is a black solid. It is often described as Na+ salt of the P3− anion. Na3P is a source of the highly reactive phosphide anion. It should not be confused with sodium phosphate, Na3PO4.

Germanium dioxide, also called germanium(IV) oxide, germania, and salt of germanium, is an inorganic compound with the chemical formula GeO2. It is the main commercial source of germanium. It also forms as a passivation layer on pure germanium in contact with atmospheric oxygen.

Molybdenum dioxide is the chemical compound with the formula MoO2. It is a violet-colored solid and is a metallic conductor. The mineralogical form of this compound is called tugarinovite, and is only very rarely found. The discovery and early studies of molybdenum dioxide date back to the late 18th and early 19th centuries. One of the notable figures in the history of molybdenum dioxide is the Hungarian chemist Jakob Joseph Winterl (1732-1809). Winterl, who was a professor of chemistry and botany at the University of Budapest, made significant contributions to the understanding of molybdenum compounds. In 1787, he proposed that copper was a compound of nickel, molybdenum, silica, and a volatile substance, showcasing his interest in molybdenum chemistry.

Iron phosphide is a chemical compound of iron and phosphorus, with a formula of FeP. Its physical appearance is grey, hexagonal needles.

<span class="mw-page-title-main">Molybdate</span> Chemical compound of the form –O–MoO₂–O–

In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of 6: O−Mo(=O)2−O. Molybdenum can form a very large range of such oxyanions, which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state. The larger oxyanions are members of group of compounds termed polyoxometalates, and because they contain only one type of metal atom are often called isopolymetalates. The discrete molybdenum oxyanions range in size from the simplest MoO2−
4
, found in potassium molybdate up to extremely large structures found in isopoly-molybdenum blues that contain for example 154 Mo atoms. The behaviour of molybdenum is different from the other elements in group 6. Chromium only forms the chromates, CrO2−
4
, Cr
2
O2−
7
, Cr
3
O2−
10
and Cr
4
O2−
13
ions which are all based on tetrahedral chromium. Tungsten is similar to molybdenum and forms many tungstates containing 6 coordinate tungsten.

<span class="mw-page-title-main">Molybdenum diselenide</span> Chemical compound

Molybdenum diselenide is an inorganic compound of molybdenum and selenium. Its structure is similar to that of MoS
2
. Compounds of this category are known as transition metal dichalcogenides, abbreviated TMDCs. These compounds, as the name suggests, are made up of a transition metals and elements of group 16 on the periodic table of the elements. Compared to MoS
2
, MoSe
2
exhibits higher electrical conductivity.

Lithium phosphide is an inorganic compound of lithium and phosphorus with the chemical formula Li
3
P
. This dark colored compound is formally the Li+ salt of P3-. It is a hazardous to handle because of its high reactivity toward air.

<span class="mw-page-title-main">Scandium phosphide</span> Chemical compound

Scandium phosphide is an inorganic compound of scandium and phosphorus with the chemical formula ScP.

Lutetium phosphide is an inorganic compound of lutetium and phosphorus with the chemical formula LuP. The compound forms dark crystals, does not dissolve in water.

Praseodymium monophosphide is an inorganic compound of praseodymium and phosphorus with the chemical formula PrP. The compound forms crystals.

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Ytterbium compounds are chemical compounds that contain the element ytterbium (Yb). The chemical behavior of ytterbium is similar to that of the rest of the lanthanides. Most ytterbium compounds are found in the +3 oxidation state, and its salts in this oxidation state are nearly colorless. Like europium, samarium, and thulium, the trihalides of ytterbium can be reduced to the dihalides by hydrogen, zinc dust, or by the addition of metallic ytterbium. The +2 oxidation state occurs only in solid compounds and reacts in some ways similarly to the alkaline earth metal compounds; for example, ytterbium(II) oxide (YbO) shows the same structure as calcium oxide (CaO).

Holmium nitride is a binary inorganic compound of holmium and nitrogen with the chemical formula HoN.

Zirconium monophosphide is a binary inorganic compound of zirconium metal and phosphorus with the chemical formula ZrP.

Trimolybdenum phosphide is a binary inorganic compound of molybdenum metal and phosphorus with the chemical formula Mo3P.

Molybdenum diphosphide is a binary inorganic compound of molybdenum metal and phosphorus with the chemical formula MoP2.

References

  1. "Molybdenum Phosphide". American Elements . Retrieved 8 March 2024.
  2. Toxic Substances Control Act (TCSA) Chemical Substance Inventory: Cumulative Supplement to the Original Inventory. User Guide and Indices. U.S. Environment Protection Agency, Office of Toxic Substances. 1980. p. 14. Retrieved 8 March 2024.
  3. Lide, David R. (29 June 2004). CRC Handbook of Chemistry and Physics, 85th Edition. CRC Press. p. 4-70. ISBN   978-0-8493-0485-9 . Retrieved 8 March 2024.
  4. Conrad, Ulrich (1935). Die Elektrolyse von Molybdänsäure in Phosphatschmelzen (in German). Technische Hochschule zu Breslau. p. 13. Retrieved 8 March 2024.
  5. Yao, Z. W.; Wang, Li; Dong, Haitao (3 April 2009). "A new approach to the synthesis of molybdenum phosphide via internal oxidation and reduction route". Journal of Alloys and Compounds . 473 (1): L10–L12. doi:10.1016/j.jallcom.2008.05.048. ISSN   0925-8388 . Retrieved 8 March 2024.
  6. Hui, Ge; Xingchen, Liu; Shanmin, Wang; Tao, Yang; Xiaodong, Wen (8 February 2017). Innovative Applications of Mo(W)-Based Catalysts in the Petroleum and Chemical Industry: Emerging Research and Opportunities: Emerging Research and Opportunities. IGI Global. p. 66. ISBN   978-1-5225-2275-1 . Retrieved 8 March 2024.
  7. "mp-219: MoP (Hexagonal, P-6m2, 187)". Materials Project . Retrieved 8 March 2024.
  8. Xiao, Peng; Sk, Mahasin Alam; Thia, Larissa; Ge, Xiaoming; Lim, Rern Jern; Wang, Jing-Yuan; Lim, Kok Hwa; Wang, Xin (18 July 2014). "Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction". Energy & Environmental Science . 7 (8): 2624–2629. doi:10.1039/C4EE00957F. hdl: 10356/103094 . ISSN   1754-5706 . Retrieved 8 March 2024.
  9. Issues in Chemical Engineering and other Chemistry Specialties: 2011 Edition. ScholarlyEditions. 9 January 2012. p. 560. ISBN   978-1-4649-6354-4 . Retrieved 8 March 2024.