Strontium iodide

Last updated
Strontium iodide
Strontium-iodide-unit-cell-3D-balls.png
Names
IUPAC name
Strontium iodide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.871 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 233-972-1
PubChem CID
RTECS number
  • WK9275000
UNII
  • InChI=1S/2HI.Sr/h2*1H;/q;;+2/p-2
  • I[Sr]I
  • [Sr+2].[I-].[I-]
Properties
Sr I2 (anhydrous)
SrI2·6H2O (hexahydrate)
Molar mass 341.43 g/mol (anhydrous)
AppearanceColorless to white crystalline plates
Density 4.55 g/cm3 (anhydrous) [1]
4.40 g/cm3 (hexahydrate) [1]
Melting point 507 to 645 °C (945 to 1,193 °F; 780 to 918 K) [2]
Boiling point 1,773 °C (3,223 °F; 2,046 K) (decomposes)
177.0 g/100 mL (20 °C) [3]
Solubility in ethanol 3.1 g/100 ml (4 °C) [3]
112.0·10−6 cm3/mol
Structure
Orthorhombic, oP24
Pbca, No. 61
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
Corrosive
GHS labelling: [4]
GHS-pictogram-acid.svg
Danger
H314
P280, P305+P351+P338, P310
NFPA 704 (fire diamond)
NFPA 704.svgHealth 1: Exposure would cause irritation but only minor residual injury. E.g. turpentineFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
1
0
0
Related compounds
Other anions
strontium fluoride
strontium chloride
strontium bromide
Other cations
beryllium iodide
magnesium iodide
calcium iodide
barium iodide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Strontium iodide (SrI2) is a salt of strontium and iodine. It is an ionic, water-soluble, and deliquescent compound that can be used in medicine as a substitute for potassium iodide . [5] It is also used as a scintillation gamma radiation detector, typically doped with europium, due to its optical clarity, relatively high density, high effective atomic number (Z=48), and high scintillation light yield. [6] In recent years, europium-doped strontium iodide (SrI2:Eu2+) has emerged as a promising scintillation material for gamma-ray spectroscopy with extremely high light yield and proportional response, exceeding that of the widely used high performance commercial scintillator LaBr3:Ce3+. Large diameter SrI2 crystals can be grown reliably using vertical Bridgman technique [7] and are being commercialized by several companies. [8] [9]

Reactions

Strontium iodide can be prepared by reacting strontium carbonate with hydroiodic acid:

SrCO3 + 2 HI → SrI2 + H2O + CO2

Strontium iodide forms a white powder that slowly changes to a yellowish colour when exposed to air. At high temperatures (in the presence of air) strontium iodide completely decomposes to form strontium oxide and free iodine. [10]

Related Research Articles

<span class="mw-page-title-main">Iodine</span> Chemical element, symbol I and atomic number 53

Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at 114 °C (237 °F), and boils to a violet gas at 184 °C (363 °F). The element was discovered by the French chemist Bernard Courtois in 1811 and was named two years later by Joseph Louis Gay-Lussac, after the Ancient Greek Ιώδης, meaning 'violet'.

<span class="mw-page-title-main">Phosphor</span> Luminescent substance

A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or visible light, and cathodoluminescent substances which glow when struck by an electron beam in a cathode-ray tube.

<span class="mw-page-title-main">Scintillator</span> Material which glows when excited by ionizing radiation

A scintillator is a material that exhibits scintillation, the property of luminescence, when excited by ionizing radiation. Luminescent materials, when struck by an incoming particle, absorb its energy and scintillate. Sometimes, the excited state is metastable, so the relaxation back down from the excited state to lower states is delayed. The process then corresponds to one of two phenomena: delayed fluorescence or phosphorescence. The correspondence depends on the type of transition and hence the wavelength of the emitted optical photon.

<span class="mw-page-title-main">Lodewijk van den Berg</span> Dutch-born American chemical engineer and astronaut (1932–2022)

Lodewijk van den Berg was a Dutch-born American chemical engineer. He studied crystal growth and flew on a 1985 Space Shuttle Challenger mission as a payload specialist.

<span class="mw-page-title-main">Lead(II) iodide</span> Chemical compound

Lead(II) iodide is a chemical compound with the formula PbI
2
. At room temperature, it is a bright yellow odorless crystalline solid, that becomes orange and red when heated. It was formerly called plumbous iodide.

<span class="mw-page-title-main">Gamma-ray spectrometer</span> Instrument for measuring gamma radiation

A gamma-ray spectrometer (GRS) is an instrument for measuring the distribution of the intensity of gamma radiation versus the energy of each photon. The study and analysis of gamma-ray spectra for scientific and technical use is called gamma spectroscopy, and gamma-ray spectrometers are the instruments which observe and collect such data. Because the energy of each photon of EM radiation is proportional to its frequency, gamma rays have sufficient energy that they are typically observed by counting individual photons.

<span class="mw-page-title-main">Gamma spectroscopy</span> Quantitative study of the energy spectra of gamma-ray sources

Gamma-ray spectroscopy is the qualitative study of the energy spectra of gamma-ray sources, such as in the nuclear industry, geochemical investigation, and astrophysics. Gamma-ray spectrometry, on the other hand, is the method used to acquire a quantitative spectrum measurement.

<span class="mw-page-title-main">Caesium iodide</span> Chemical compound

Caesium iodide or cesium iodide is the ionic compound of caesium and iodine. It is often used as the input phosphor of an X-ray image intensifier tube found in fluoroscopy equipment. Caesium iodide photocathodes are highly efficient at extreme ultraviolet wavelengths.

<span class="mw-page-title-main">Sodium iodide</span> Chemical compound

Sodium iodide (chemical formula NaI) is an ionic compound formed from the chemical reaction of sodium metal and iodine. Under standard conditions, it is a white, water-soluble solid comprising a 1:1 mix of sodium cations (Na+) and iodide anions (I) in a crystal lattice. It is used mainly as a nutritional supplement and in organic chemistry. It is produced industrially as the salt formed when acidic iodides react with sodium hydroxide. It is a chaotropic salt.

<span class="mw-page-title-main">Neutron detection</span>

Neutron detection is the effective detection of neutrons entering a well-positioned detector. There are two key aspects to effective neutron detection: hardware and software. Detection hardware refers to the kind of neutron detector used and to the electronics used in the detection setup. Further, the hardware setup also defines key experimental parameters, such as source-detector distance, solid angle and detector shielding. Detection software consists of analysis tools that perform tasks such as graphical analysis to measure the number and energies of neutrons striking the detector.

<span class="mw-page-title-main">Strontium aluminate</span> Chemical compound

Strontium aluminate is an aluminate compound with the chemical formula SrAl2O4. It is a pale yellow, monoclinic crystalline powder that is odourless and non-flammable. When activated with a suitable dopant, it acts as a photoluminescent phosphor with long persistence of phosphorescence.

<span class="mw-page-title-main">Thallium(I) iodide</span> Chemical compound

Thallium(I) iodide is a chemical compound with the formula TlI. It is unusual in being one of the few water-insoluble metal iodides, along with AgI, CuI, SnI2, SnI4, PbI2 and HgI2.

<span class="mw-page-title-main">Magnesium iodide</span> Chemical compound

Magnesium iodide is an inorganic compound with the chemical formula MgI2. It forms various hydrates MgI2·xH2O. Magnesium iodide is a salt of magnesium and hydrogen iodide. These salts are typical ionic halides, being highly soluble in water.

<span class="mw-page-title-main">Cerium(III) bromide</span> Chemical compound

Cerium(III) bromide is an inorganic compound with the formula CeBr3. This white hygroscopic solid is of interest as a component of scintillation counters.

Lanthanum(III) bromide (LaBr3) is an inorganic halide salt of lanthanum. When pure, it is a colorless white powder. The single crystals of LaBr3 are hexagonal crystals with melting point of 783 °C. It is highly hygroscopic and water-soluble. There are several hydrates, La3Br·x H2O, of the salt also known. It is often used as a source of lanthanum in chemical synthesis and as a scintillation material in certain applications.

In phosphors and scintillators, the activator is the element added as dopant to the crystal of the material to create desired type of nonhomogeneities.

<span class="mw-page-title-main">Radionuclide identification device</span>

A radionuclide identification device is a small, lightweight, portable gamma-ray spectrometer used for the detection and identification of radioactive substances. As RIIDs are portable, they are suitable for medical and industrial applications, fieldwork, geological surveys, first-line responders in Homeland Security, and Environmental Monitoring and Radiological Mapping along with other industries that necessitate the identification of radioactive substances..

<span class="mw-page-title-main">Europium(II) iodide</span> Chemical compound

Europium(II) iodide is the iodide salt of divalent europium cation.

Europium(III) iodide is an inorganic compound containing europium and iodine with the chemical formula EuI3.

<span class="mw-page-title-main">Lutetium(III) iodide</span> Chemical compound

Lutetium(III) iodide or lutetium iodide is an inorganic compound consisting of iodine and lutetium, with the chemical formula of LuI3.

References

  1. 1 2 Yaws, C.L. (2008). Thermophysical properties of chemicals and hydrocarbons. William Andrew. ISBN   978-0-8155-1596-8.
  2. Turner, Jr., Francis M., ed. (1920), The Condensed Chemical Dictionary, New York: The Chemical Catalog Company, p. 449, retrieved 2007-12-10
  3. 1 2
    177 g/100 mL (20 °C) Seidell, Atherton (1907), Solubilities of Inorganic and Organic Substances, New York: D. Van Nostrand, p. 318, retrieved 2007-12-10
  4. "Strontium iodide". Sigma Aldrich.
  5. Shoemaker, John V. (1908), A Practical Treatise on Materia Medica and Therapeutics (7th ed.), Philadelphia: F. A. Davis, p. 854, retrieved 2007-12-10
  6. Prettyman, Thomas; Burger, Arnold; Yamashita, Naoyuki; Lambert, James; Stassun, Keivan; Raymond, Carol (2015). "Ultra-bright scintillators for planetary gamma-ray spectroscopy". SPIE Newsroom. doi:10.1117/2.1201510.006162. ISSN   1818-2259.
  7. Datta, A.; Lam, S.; Swider, S.; Motakef, S. (October 2016). "Crystal growth of large diameter strontium iodide scintillators using in Situ stoichiometry monitoring". 2016 IEEE Nuclear Science Symposium, Medical Imaging Conference and Room-Temperature Semiconductor Detector Workshop (NSS/MIC/RTSD). pp. 1–4. doi:10.1109/NSSMIC.2016.8116640. ISBN   978-1-5090-1642-6. S2CID   31775311.
  8. Inc., CapeSym. "CapeSym | SrI2(Eu)". www.capesym.com. Retrieved 2018-02-13.{{cite web}}: |last= has generic name (help)
  9. "Strontium Iodide | RMD". rmdinc.com. Archived from the original on 2018-02-14. Retrieved 2018-02-13.
  10. Bartley, Elias H. (1898), Text-book of Medical and Pharmaceutical Chemistry (5th ed.), Philadelphia: P. Blakiston, pp. 267–268, retrieved 2007-12-10