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Preferred IUPAC name 2-Aminobenzene-1-thiol | |
Other names
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ChemSpider | |
ECHA InfoCard | 100.004.798 |
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CompTox Dashboard (EPA) | |
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Properties | |
C6H7NS | |
Molar mass | 125.19 g·mol−1 |
Appearance | Colorless (impure samples are colored) |
Density | 1.200 g/cm3 |
Melting point | 26 °C (79 °F; 299 K) |
Boiling point | 234 °C (453 °F; 507 K) |
low | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
2-Aminothiophenol is an organosulfur compound with the formula C6H4(SH)(NH2). It is a colorless oily solid, although impure samples can be deeply colored. It is soluble in organic solvents and in basic water. 2-Aminothiophenol is a precursor to benzothiazoles, some of which are bioactive or are commercial dyes. Isomers of aminothiophenols include 3-aminothiophenol and 4-aminothiophenol.
2-Aminothiophenol can prepared in two steps, starting with the reaction of aniline with carbon disulfide followed by hydrolysis of the resulting mercaptobenzothiazole. [1] It can also obtained by zinc reduction of 2-nitrobenzenesulfonyl chloride.
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The Herz reaction, named after the chemist Richard Herz, is the chemical conversion of an aniline to the benzodithiazolium salt by its reaction with disulfur dichloride. The salt is called a Herz salt. Hydrolysis of this Herz salt give the corresponding sodium thiolate, which can be further converted to the 2-aminothiophenol.
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Aminothiophenol may refer to:
1,2,3-Benzothiadiazole is a bicyclic aromatic chemical composed of a benzene ring that is fused to a 1,2,3-thiadiazole. A colorless solid, the compound is soluble in organic solvents.
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