Alkaline precipitation

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Alkaline precipitation occurs due to natural and anthropogenic causes. It happens when minerals, such as calcium, aluminum, or magnesium combine with other minerals to form alkaline residues that are emitted into the atmosphere, absorbed by water droplets in clouds, and eventually fall as rain. Aquatic environments are especially impacted by alkaline precipitation. Because alkaline precipitation can be harmful to the environment, it is important to utilize various methods such as air pollution control, solidification and stabilization, and remediation to manage it. [1]

Contents

The impact of alkaline residue in the environment. Industrial processes produce alkaline residue that leaks into the environment such as groundwater changing the pH or can become fugitive dust in the air. Alkaline precipitation.png
The impact of alkaline residue in the environment. Industrial processes produce alkaline residue that leaks into the environment such as groundwater changing the pH or can become fugitive dust in the air.

Natural causes

While most natural rains are weakly acidic, alkaline rain can also occur in natural conditions without the significant impact of pollutants. [2] Natural alkaline rains from semiarid areas carry a substantial amount of mineral dust lifted from desert soil convection and transported by winds. After mixing with water vapor, they are carried by clouds and deposited on the ground in the form of rain dust.

Anthropogenic causes

The principal cause of alkaline rain are emissions from factories and waste deposits. Mineral dust containing large amounts of alkaline compounds such as calcium carbonate can also increase the pH of precipitation and contribute to basic rain. [3] Alkaline rain can be viewed as opposite to acid rain. Industrial processes such as coal combustion, limestone, chromium ore, alumina extraction, iron, and steel manufacture can cause pollution by producing alkaline residue. [1] These residues are significant and increasing in the global flux and are composed of sodium, calcium, or magnesium oxides that are hydrated to produce soluble hydroxides. [1] Other sources include the surfaces of unpaved roads and soils that are covered in major alkaline elements (e.g. sodium, calcium, magnesium, and potassium). [4]

Impacts of alkaline precipitation

Alkaline precipitation increases the pH of rainwater to 8.5-10, causing disturbances in aquatic ecosystems. These disturbances can cause physiological changes to aquatic life, changing the rates at which ammonia is dispelled, which leads to accumulation in organisms. [1] The pH change in the water can cause precipitation of calcite from alkaline leachates that suffocate benthic and littoral aquatic habitats, along with reducing light penetration. [1]

Management

Air pollution control yields two management practices of recycling ceramic material or landfill after treatment. [1] These practices are made possible by several treatment methods of solidification/stabilization, thermal, and combined. [1] The most commonly used method for dealing with these types of waste such as bauxite is solidification / stabilization. [1] Remediation for alkaline leachate requires active aeration in order to promote carbonation, recirculation of drainage waters over stockpiled or lagooned residues, and acid dosing. Strong acids (e.g. hydrochloric acid and sulfuric acid ) are also used in neutralizing the pH; this is used at active processing plants but the liquid runoff can remain toxic to aquatic environments. [1] Wetlands are also a low-cost remedy for alkaline leachates. [1]

See also

Related Research Articles

<span class="mw-page-title-main">Acid rain</span> Rain that is unusually acidic

Acid rain is rain or any other form of precipitation that is unusually acidic, meaning that it has elevated levels of hydrogen ions. Most water, including drinking water, has a neutral pH that exists between 6.5 and 8.5, but acid rain has a pH level lower than this and ranges from 4–5 on average. The more acidic the acid rain is, the lower its pH is. Acid rain can have harmful effects on plants, aquatic animals, and infrastructure. Acid rain is caused by emissions of sulfur dioxide and nitrogen oxide, which react with the water molecules in the atmosphere to produce acids.

<span class="mw-page-title-main">Limestone</span> Sedimentary rocks made of calcium carbonate

Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.

<span class="mw-page-title-main">Calcium carbonate</span> Chemical compound

Calcium carbonate is a chemical compound with the chemical formula CaCO3. It is a common substance found in rocks as the minerals calcite and aragonite and is the main component of eggshells, gastropod shells, shellfish skeletons and pearls. Things containing much calcium carbonate or resembling it are described as calcareous. Calcium carbonate is the active ingredient in agricultural lime and is created when calcium ions in hard water react with carbonate ions to create limescale. It has medical use as a calcium supplement or as an antacid, but excessive consumption can be hazardous and cause hypercalcemia and digestive issues.

<span class="mw-page-title-main">Weathering</span> Deterioration of rocks and minerals through exposure to the elements

Weathering is the deterioration of rocks, soils and minerals as well as wood and artificial materials through contact with water, atmospheric gases, and biological organisms. Weathering occurs in situ, and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity.

<span class="mw-page-title-main">Soil pH</span> Measure of the acidity or alkalinity in soils

Soil pH is a measure of the acidity or basicity (alkalinity) of a soil. Soil pH is a key characteristic that can be used to make informative analysis both qualitative and quantitatively regarding soil characteristics. pH is defined as the negative logarithm (base 10) of the activity of hydronium ions in a solution. In soils, it is measured in a slurry of soil mixed with water, and normally falls between 3 and 10, with 7 being neutral. Acid soils have a pH below 7 and alkaline soils have a pH above 7. Ultra-acidic soils and very strongly alkaline soils are rare.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils. Because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

<span class="mw-page-title-main">Magnesium sulfate</span> Chemical compound with formula MgSO4

Magnesium sulfate or magnesium sulphate (in English-speaking countries other than the US) is a chemical compound, a salt with the formula MgSO4, consisting of magnesium cations Mg2+ (20.19% by mass) and sulfate anions SO2−4. It is a white crystalline solid, soluble in water but not in ethanol.

<span class="mw-page-title-main">Environmental remediation</span> Removal of pollution from soil, groundwater etc.

Environmental remediation deals with the removal of pollution or contaminants from environmental media such as soil, groundwater, sediment, or surface water. Remedial action is generally subject to an array of regulatory requirements, and may also be based on assessments of human health and ecological risks where no legislative standards exist, or where standards are advisory.

<span class="mw-page-title-main">Magnesium chloride</span> Inorganic salt: MgCl2 and its hydrates

Magnesium chloride is an inorganic compound with the formula MgCl2. It forms hydrates MgCl2·nH2O, where n can range from 1 to 12. These salts are colorless or white solids that are highly soluble in water. These compounds and their solutions, both of which occur in nature, have a variety of practical uses. Anhydrous magnesium chloride is the principal precursor to magnesium metal, which is produced on a large scale. Hydrated magnesium chloride is the form most readily available.

<span class="mw-page-title-main">Water softening</span> Removing positive ions from hard water

Water softening is the removal of calcium, magnesium, and certain other metal cations in hard water. The resulting soft water requires less soap for the same cleaning effort, as soap is not wasted bonding with calcium ions. Soft water also extends the lifetime of plumbing by reducing or eliminating scale build-up in pipes and fittings. Water softening is usually achieved using lime softening or ion-exchange resins but is increasingly being accomplished using nanofiltration or reverse osmosis membranes.

<span class="mw-page-title-main">Fly ash</span> Residue of coal combustion

Fly ash, flue ash, coal ash, or pulverised fuel ash – plurale tantum: coal combustion residuals (CCRs) – is a coal combustion product that is composed of the particulates that are driven out of coal-fired boilers together with the flue gases. Ash that falls to the bottom of the boiler's combustion chamber is called bottom ash. In modern coal-fired power plants, fly ash is generally captured by electrostatic precipitators or other particle filtration equipment before the flue gases reach the chimneys. Together with bottom ash removed from the bottom of the boiler, it is known as coal ash.

<span class="mw-page-title-main">Alkalinity</span> Capacity of water to resist changes in pH that would make the water more acidic

Alkalinity (from Arabic: القلوي, romanized: al-qaly, lit. 'ashes of the saltwort') is the capacity of water to resist acidification. It should not be confused with basicity, which is an absolute measurement on the pH scale. Alkalinity is the strength of a buffer solution composed of weak acids and their conjugate bases. It is measured by titrating the solution with an acid such as HCl until its pH changes abruptly, or it reaches a known endpoint where that happens. Alkalinity is expressed in units of concentration, such as meq/L (milliequivalents per liter), μeq/kg (microequivalents per kilogram), or mg/L CaCO3 (milligrams per liter of calcium carbonate). Each of these measurements corresponds to an amount of acid added as a titrant.

Soil acidification is the buildup of hydrogen cations, which reduces the soil pH. Chemically, this happens when a proton donor gets added to the soil. The donor can be an acid, such as nitric acid, sulfuric acid, or carbonic acid. It can also be a compound such as aluminium sulfate, which reacts in the soil to release protons. Acidification also occurs when base cations such as calcium, magnesium, potassium and sodium are leached from the soil.

<span class="mw-page-title-main">Alkali soil</span> Soil type with pH > 8.5

Alkali, or Alkaline, soils are clay soils with high pH, a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico-chemical properties mainly to the dominating presence of sodium carbonate, which causes the soil to swell and difficult to clarify/settle. They derive their name from the alkali metal group of elements, to which sodium belongs, and which can induce basicity. Sometimes these soils are also referred to as alkaline sodic soils.
Alkaline soils are basic, but not all basic soils are alkaline.

<span class="mw-page-title-main">In situ leach</span>

In-situ leaching (ISL), also called in-situ recovery (ISR) or solution mining, is a mining process used to recover minerals such as copper and uranium through boreholes drilled into a deposit, in situ. In situ leach works by artificially dissolving minerals occurring naturally in a solid state. For recovery of material occurring naturally in solution, see: Brine mining.

Bittern, or nigari, is the salt solution formed when halite precipitates from seawater or brines. Bitterns contain magnesium, calcium, and potassium ions as well as chloride, sulfate, iodide, and other ions.

<span class="mw-page-title-main">Rain dust</span>

Rain dust or snow dust, traditionally known as muddy rain, red rain, or coloured rain, is a variety of rain which contains enough desert dust for the dust to be visible without using a microscope.

<span class="mw-page-title-main">Residual sodium carbonate index</span>

The residual sodium carbonate (RSC) index of irrigation water or soil water is used to indicate the alkalinity hazard for soil. The RSC index is used to find the suitability of the water for irrigation in clay soils which have a high cation exchange capacity. When dissolved sodium in comparison with dissolved calcium and magnesium is high in water, clay soil swells or undergoes dispersion which drastically reduces its infiltration capacity.

Soil stabilization is a general term for any physical, chemical, mechanical, biological, or combined method of changing a natural soil to meet an engineering purpose. Improvements include increasing the weight-bearing capabilities, tensile strength, and overall performance of in-situ subsoils, sands, and waste materials in order to strengthen road pavements.

<span class="mw-page-title-main">Calthemite</span> Secondary calcium carbonate deposit growing under man-made structures

Calthemite is a secondary deposit, derived from concrete, lime, mortar or other calcareous material outside the cave environment. Calthemites grow on or under, man-made structures and mimic the shapes and forms of cave speleothems, such as stalactites, stalagmites, flowstone etc. Calthemite is derived from the Latin calx "lime" + Latin < Greek théma, "deposit" meaning ‘something laid down’, and the Latin –ita < Greek -itēs – used as a suffix indicating a mineral or rock. The term "speleothem", due to its definition can only be used to describe secondary deposits in caves and does not include secondary deposits outside the cave environment.

References

  1. 1 2 3 4 5 6 7 8 9 10 11 Gomes, Helena I.; Mayes, William M.; Rogerson, Mike; Stewart, Douglas I.; Burke, Ian T. (2016). "Alkaline residues and the environment: a review of impacts, management practices and opportunities". Journal of Cleaner Production. 112: 3571–3582. doi: 10.1016/j.jclepro.2015.09.111 . ISSN   0959-6526. S2CID   52591037.
  2. Zhang, D. D.; Peart, M. R.; Jim, C. Y.; Jia, La (2002). "Alkaline rains on the Tibetan Plateau and their implication for the original pH of natural rainfall". Journal of Geophysical Research: Atmospheres. 107 (D104): ACH 9.1–ACH 9.6. Bibcode:2002JGRD..107.4198Z. doi:10.1029/2001JD001332. hdl: 10722/54351 .
  3. Özsoy, Türkan; Cemal Saydam, A (2000). "Acidic and alkaline precipitation in the Cilician Basin, north-eastern Mediterranean Sea". Science of the Total Environment. 253 (1–3): 93–109. Bibcode:2000ScTEn.253...93O. doi:10.1016/S0048-9697(00)00380-6. PMID   10843334.
  4. Gatz, Donald F.; Barnard, William R.; Stensland, Gary J. (1986). "The role of alkaline materials in precipitation chemistry: A brief review of the issues". Water, Air, and Soil Pollution. 30 (1): 245–251. doi:10.1007/BF00305195. ISSN   1573-2932.