Zoisite, first known as saualpite, after its type locality, is a calcium aluminum hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2Al3(SiO4)(Si2O7)O(OH).
Nickeline or niccolite is the mineral form of nickel arsenide. The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.
Vivianite (Fe(II)
3(PO
4)
2·8H
2O) is a hydrated iron(II) phosphate mineral found in a number of geological environments. Small amounts of manganese Mn2+, magnesium Mg2+, and calcium Ca2+ may substitute for iron Fe2+ in its structure. Pure vivianite is colorless, but the mineral oxidizes very easily, changing the color, and it is usually found as deep blue to deep bluish green prismatic to flattened crystals. Vivianite crystals are often found inside fossil shells, such as those of bivalves and gastropods, or attached to fossil bone. Vivianite can also appear on the iron coffins or on the corpses of humans as a result of a chemical reaction of the decomposing body with the iron enclosure.
Skutterudite is a cobalt arsenide mineral containing variable amounts of nickel and iron substituting for cobalt with the ideal formula CoAs3. Some references give the arsenic a variable formula subscript of 2–3. High nickel varieties are referred to as nickel-skutterudite, previously chloanthite. It is a hydrothermal ore mineral found in moderate to high temperature veins with other Ni-Co minerals. Associated minerals are arsenopyrite, native silver, erythrite, annabergite, nickeline, cobaltite, silver sulfosalts, native bismuth, calcite, siderite, barite and quartz. It is mined as an ore of cobalt and nickel with a by-product of arsenic.
Erythrite, also known as red cobalt, is a secondary hydrated cobalt arsenate mineral with the formula Co
3(AsO
4)
2•8H
2O. Erythrite and annabergite, chemical formula Ni
3(AsO
4)
2•8H
2O, or nickel arsenate form a complete series with the general formula (Co,Ni)
3(AsO
4)
2•8H
2O.
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.
Cobaltite is an arsenide and sulfide mineral with the mineral formula CoAsS. It is the naming mineral of the cobaltite group of minerals, whose members structurally resemble pyrite (FeS2).
The rare mineral adelite, is a calcium, magnesium, arsenate with chemical formula CaMgAsO4OH. It forms a solid solution series with the vanadium-bearing mineral gottlobite. Various transition metals substitute for magnesium and lead replaces calcium leading to a variety of similar minerals in the adelite–duftite group.
Cabrerite is an arsenate mineral bearing magnesium and nickel. It is a member of the hörnesite-annabergite series in the vivianite group.
Spherocobaltite or sphaerocobaltite is a cobalt carbonate mineral with chemical composition CoCO3. In its (rare) pure form, it is typically a rose-red color, but impure specimens can be shades of pink to pale brown. It crystallizes in the trigonal crystal system.
Népouite is a rare nickel silicate mineral which has the apple green color typical of such compounds. It was named by the French mining engineer Edouard Glasser in 1907 after the place where it was first described, the Népoui Mine, Népoui, Poya Commune, North Province, New Caledonia. The ideal formula is Ni3(Si2O5)(OH)4, but most specimens contain some magnesium, and (Ni,Mg)3(Si2O5)(OH)4 is more realistic. There is a similar mineral called lizardite in which all of the nickel is replaced by magnesium, formula Mg3(Si2O5)(OH)4. These two minerals form a series; intermediate compositions are possible, with varying proportions of nickel to magnesium.
Lavendulan is an uncommon arsenate mineral in the lavendulan group. It is known for its characteristic intense electric blue colour. Lavendulan is very similar to Lemanskiite, the analogue trihydrate mineral, to the point of them being considered dimorphs. Lemanskiite is tetragonal, but lavendulan is monoclinic. Lavendulan has the same structure as sampleite, and the two minerals form a series. It is the calcium analogue of zdenĕkite and the arsenate analogue of sampleite.
Roselite is a rare arsenate mineral with chemical formula: Ca2(Co,Mg)[AsO4]2·H2O. It was first described in 1825 for an occurrence in the Rappold mines of Schneeberg, Saxony, Germany and named by Armand Lévy after German mineralogist Gustav Rose. It occurs in cobalt-bearing hydrothermal environments and was associated with veins of quartz and chalcedony in the type locality. It has also been reported from Italy, Morocco, Chile, British Columbia and several locations in Germany.
Vladimirite is a rare calcium arsenate mineral with a formula of Ca5(HAsO4)2(AsO4)2·5H2O. It is named after the Vladimirovskoye deposit in Russia, where it was discovered in the 1950s.
Magnesiopascoite is a bright orange mineral with formula Ca2Mg(V10O28)·16H2O. It was discovered in the U.S. state of Utah and formally described in 2008. The mineral's name derives from its status as the magnesium analogue of pascoite.
Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (1824–1892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the mineral. It has the formula Zn3(AsO4)2·8H2O and it is a dimorph of metaköttigite, which means that the two minerals have the same formula, but a different structure: köttigite is monoclinic and metaköttigite is triclinic. There are several minerals with similar formulae but with other cations in place of the zinc. Iron forms parasymplesite Fe2+3(AsO4)2·8H2O; cobalt forms the distinctively coloured pinkish purple mineral erythrite Co3(AsO4)2·8H2O and nickel forms annabergite Ni3(AsO4)2·8H2O. Köttigite forms series with all three of these minerals and they are all members of the vivianite group.
Talmessite is a hydrated calcium magnesium arsenate, often with significant amounts of cobalt or nickel. It was named in 1960 for the type locality, the Talmessi mine, Anarak district, Iran. It forms a series with β-Roselite, where cobalt replaces some of the magnesium, and with gaitite, where zinc replaces the magnesium. All these minerals are members of the fairfieldite group. Talmessite is dimorphic with wendwilsonite.
Widgiemoolthalite is a rare hydrated nickel(II) carbonate mineral with the chemical formula (Ni,Mg)5(CO3)4(OH)2·5H2O. Usually bluish-green in color, it is a brittle mineral formed during the weathering of nickel sulfide. Present on gaspéite surfaces, widgiemoolthalite has a Mohs scale hardness of 3.5 and an unknown though likely disordered crystal structure. Widgiemoolthalite was first discovered in 1992 in Widgiemooltha, Western Australia, which is to date its only known source. It was named the following year by the three researchers who first reported its existence, Ernest H. Nickel, Bruce W. Robinson, and William G. Mumme.
Miguelromeroite is a mineral named for Miguel Romero Sanchez by Anthony Robert Kampf. The mineral, first described in 2008 was named in 2009, the same year it got approved by the International Mineralogical Association.
Hörnesite is an arsenate mineral bearing magnesium. It is a member of the vivianite group of minerals, and constitutes the magnesium endpoint of a mineral series with nickel or cobalt replacing the magnesium, ending in annabergite or Erythrite.
