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An antibubble is a droplet of liquid surrounded by a thin film of gas, [1] as opposed to a gas bubble, which is a sphere of gas surrounded by a liquid. Antibubbles are formed when liquid drops or flows turbulently into the same or another liquid. They can either skim across the surface of a liquid such as water, in which case they are also called water globules, or they can be completely submerged into the liquid to which they are directed.
Antibubbles are a common but widely unrecognized phenomenon, in part because of their resemblance to air bubbles, and in part because of their typically transient, or short-lived, nature. [2] With certain (soapy) solutions, they can be made to last much longer. [3]
Antibubbles can be created by allowing a tap to drip into a container of water to which a drop or two of soap has been added. They have all been produced aided by an ultrasound contrast agent. [4] Being inherently unstable, they are difficult to form. [5] [6] The soap reduces the water's surface tension and allows the skin of air surrounding the droplet to remain in place for more than just a fraction of a second. As antibubbles can be easily created at home, they have attracted attention from popular science magazines. [7] [8]
Just as soap bubbles, with air inside and air outside, have negative buoyancy and tend to sink towards the ground, so antibubbles, with water inside and air outside have positive buoyancy and tend to rise towards the water surface. But again, just as soap bubbles can be filled with a lighter gas to give them positive buoyancy, so antibubbles can be filled with a heavier liquid to give them negative buoyancy. Using a drinking straw to drop droplets of sugar solution onto soapy water will produce antibubbles that sink.
Antibubbles usually pop when they touch the bottom or the side of the vessel containing the liquid. This can be prevented by tipping a few teaspoons of sugar into the soapy water and giving it some time to dissolve (but without stirring it). This will produce a denser layer of sugary water at the bottom of the container. Antibubbles made from sugar solution will then sink through the water and rest on top of the denser layer at the bottom. Antibubbles made this way can last for several minutes.
The layers of an antibubble are water, which it is submerged in, air, and the water trapped in the air.
The behavior of antibubbles differs from that of air bubbles in three primary ways, and provides a ready means of identification:
If antibubbles can be stabilized they can be used to form a long lasting froth — antifoam. Possible uses for antifoam are as a lubricant or using the thin passageways permeating antifoam as a filter for air or other gasses.
Antibubbles themselves could be used for chemical processes such as removing pollutants from a smokestack. Replacing the air in antibubble shells with another liquid could be used for a drug delivery system by creating a shell of liquid-polymer around a drug. Hardening the polymer with ultraviolet light would create a drug filled capsule.
Microscopic antibubbles have demonstrated their feasibility in harmonic imaging. [9] [10] It has been proposed to incorporate therapeutics into antibubble cores. Such drug-loaded antibubbles might be used in ultrasound-guided drug delivery, where acoustic waves create sufficient pulsations of the antibubble surface to release its drug-containing core. [11]
The lifetime of an antibubble on top of a water surface might be prolonged by making the water underneath it vibrate. [12] [13] Such antibubbles have been referred to as "walking bubbles" and have been proposed to be used as a model of quantum mechanical behavior. [14] Another way to increase the lifetime of antibubbles is by applying so-called Pickering stabilization. [15]
Cavitation in fluid mechanics and engineering normally refers to the phenomenon in which the static pressure of a liquid reduces to below the liquid's vapour pressure, leading to the formation of small vapor-filled cavities in the liquid. When subjected to higher pressure, these cavities, called "bubbles" or "voids", collapse and can generate shock waves that may damage machinery. These shock waves are strong when they are very close to the imploded bubble, but rapidly weaken as they propagate away from the implosion. Cavitation is a significant cause of wear in some engineering contexts. Collapsing voids that implode near to a metal surface cause cyclic stress through repeated implosion. This results in surface fatigue of the metal, causing a type of wear also called "cavitation". The most common examples of this kind of wear are to pump impellers, and bends where a sudden change in the direction of liquid occurs. Cavitation is usually divided into two classes of behavior: inertial cavitation and non-inertial cavitation.
An emulsion is a mixture of two or more liquids that are normally immiscible owing to liquid-liquid phase separation. Emulsions are part of a more general class of two-phase systems of matter called colloids. Although the terms colloid and emulsion are sometimes used interchangeably, emulsion should be used when both phases, dispersed and continuous, are liquids. In an emulsion, one liquid is dispersed in the other. Examples of emulsions include vinaigrettes, homogenized milk, liquid biomolecular condensates, and some cutting fluids for metal working.
A drop or droplet is a small column of liquid, bounded completely or almost completely by free surfaces. A drop may form when liquid accumulates at the end of a tube or other surface boundary, producing a hanging drop called a pendant drop. Drops may also be formed by the condensation of a vapor or by atomization of a larger mass of solid. Water vapor will condense into droplets depending on the temperature. The temperature at which droplets form is called the dew point.
The Leidenfrost effect is a physical phenomenon in which a liquid, close to a surface that is significantly hotter than the liquid's boiling point, produces an insulating vapor layer that keeps the liquid from boiling rapidly. Because of this repulsive force, a droplet hovers over the surface, rather than making physical contact with it. The effect is named after the German doctor Johann Gottlob Leidenfrost, who described it in A Tract About Some Qualities of Common Water.
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects to float on a water surface without becoming even partly submerged.
Surfactants are chemical compounds that decrease the surface tension or interfacial tension between two liquids, a liquid and a gas, or a liquid and a solid. The word "surfactant" is a blend of surface-active agent, coined c. 1950. As they consist of a water-repellent and a water-attracting part, they enable water and oil to mix; they can form foam and facilitate the detachment of dirt.
Soap films are thin layers of liquid surrounded by air. For example, if two soap bubbles come into contact, they merge and a thin film is created in between. Thus, foams are composed of a network of films connected by Plateau borders. Soap films can be used as model systems for minimal surfaces, which are widely used in mathematics.
A soap bubble is an extremely thin film of soap or detergent and water enclosing air that forms a hollow sphere with an iridescent surface. Soap bubbles usually last for only a few seconds before bursting, either on their own or on contact with another object. They are often used for children's enjoyment, but they are also used in artistic performances. Assembling many bubbles results in foam.
Diving physics, or the physics of underwater diving is the basic aspects of physics which describe the effects of the underwater environment on the underwater diver and their equipment, and the effects of blending, compressing, and storing breathing gas mixtures, and supplying them for use at ambient pressure. These effects are mostly consequences of immersion in water, the hydrostatic pressure of depth and the effects of pressure and temperature on breathing gases. An understanding of the physics is useful when considering the physiological effects of diving, breathing gas planning and management, diver buoyancy control and trim, and the hazards and risks of diving.
In thermodynamics, nucleation is the first step in the formation of either a new thermodynamic phase or structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled below 0 °C, it will tend to freeze into ice, but volumes of water cooled only a few degrees below 0 °C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay.
In chemistry, the study of sonochemistry is concerned with understanding the effect of ultrasound in forming acoustic cavitation in liquids, resulting in the initiation or enhancement of the chemical activity in the solution. Therefore, the chemical effects of ultrasound do not come from a direct interaction of the ultrasonic sound wave with the molecules in the solution.
Contrast-enhanced ultrasound (CEUS) is the application of ultrasound contrast medium to traditional medical sonography. Ultrasound contrast agents rely on the different ways in which sound waves are reflected from interfaces between substances. This may be the surface of a small air bubble or a more complex structure. Commercially available contrast media are gas-filled microbubbles that are administered intravenously to the systemic circulation. Microbubbles have a high degree of echogenicity. There is a great difference in echogenicity between the gas in the microbubbles and the soft tissue surroundings of the body. Thus, ultrasonic imaging using microbubble contrast agents enhances the ultrasound backscatter, (reflection) of the ultrasound waves, to produce a sonogram with increased contrast due to the high echogenicity difference. Contrast-enhanced ultrasound can be used to image blood perfusion in organs, measure blood flow rate in the heart and other organs, and for other applications.
Coalescence is the process by which two or more droplets, bubbles, or particles merge during contact to form a single daughter droplet, bubble, or particle. Coalescence manifests itself from a microscopic scale in meteorology to a macroscopic scale in astrophysics. For example, it is seen in the formation of raindrops as well as planetary and star formation.
In fluid mechanics, multiphase flow is the simultaneous flow of materials with two or more thermodynamic phases. Virtually all processing technologies from cavitating pumps and turbines to paper-making and the construction of plastics involve some form of multiphase flow. It is also prevalent in many natural phenomena.
A bubble is a globule of a gas substance in a liquid. In the opposite case, a globule of a liquid in a gas, is called a drop. Due to the Marangoni effect, bubbles may remain intact when they reach the surface of the immersive substance.
A jet is a stream of fluid that is projected into a surrounding medium, usually from some kind of a nozzle, aperture or orifice. Jets can travel long distances without dissipating.
A Ramsden emulsion, sometimes named Pickering emulsion, is an emulsion that is stabilized by solid particles which adsorb onto the interface between the water and oil phases. Typically, the emulsions are either water-in-oil or oil-in-water emulsions, but other more complex systems such as water-in-water, oil-in-oil, water-in-oil-in-water, and oil-in-water-in-oil also do exist. Pickering emulsions were named after S.U. Pickering, who described the phenomenon in 1907, although the effect was first recognized by Walter Ramsden in 1903.
A liquid is a nearly incompressible fluid that conforms to the shape of its container but retains a nearly constant volume independent of pressure. It is one of the four fundamental states of matter, and is the only state with a definite volume but no fixed shape.
A defoamer or an anti-foaming agent is a chemical additive that reduces and hinders the formation of foam in industrial process liquids. The terms anti-foam agent and defoamer are often used interchangeably. Strictly speaking, defoamers eliminate existing foam and anti-foamers prevent the formation of further foam. Commonly used agents are insoluble oils, polydimethylsiloxanes and other silicones, certain alcohols, stearates and glycols. The additive is used to prevent formation of foam or is added to break a foam already formed.
Liquid marbles are non-stick droplets wrapped by micro- or nano-metrically scaled hydrophobic, colloidal particles ; representing a platform for a diversity of chemical and biological applications. Liquid marbles are also found naturally; aphids convert honeydew droplets into marbles. A variety of non-organic and organic liquids may be converted into liquid marbles. Liquid marbles demonstrate elastic properties and do not coalesce when bounced or pressed lightly. Liquid marbles demonstrate a potential as micro-reactors, micro-containers for growing micro-organisms and cells, micro-fluidics devices, and have even been used in unconventional computing. Liquid marbles remain stable on solid and liquid surfaces. Statics and dynamics of rolling and bouncing of liquid marbles were reported. Liquid marbles coated with poly-disperse and mono-disperse particles have been reported. Liquid marbles are not hermetically coated by solid particles but connected to the gaseous phase. Kinetics of the evaporation of liquid marbles has been investigated.