Germanite is a rare copper iron germanium sulfide mineral, Cu26Fe4Ge4S32. It was first discovered in 1922, and named for its germanium content. It is only a minor source of this important semiconductor element, which is mainly derived from the processing of the zinc sulfide mineral sphalerite. Germanite contains gallium, zinc, molybdenum, arsenic, and vanadium as impurities.
Bornite, also known as peacock ore, is a sulfide mineral with chemical composition Cu5FeS4 that crystallizes in the orthorhombic system (pseudo-cubic).
Zinkenite is a steel-gray metallic sulfosalt mineral composed of lead antimony sulfide Pb9Sb22S42. Zinkenite occurs as acicular needle-like crystals.
Ullmannite or Nickel glance is a nickel antimony sulfide mineral with formula: NiSbS. Considerable substitution occurs with cobalt and iron in the nickel site along with bismuth and arsenic in the antimony site. A solid solution series exists with the high cobalt willyamite.
Uvarovite is a chromium-bearing garnet group species with the formula: Ca3Cr2(SiO4)3. It was discovered in 1832 by Germain Henri Hess who named it after Count Sergei Uvarov (1765–1855), a Russian statesman and amateur mineral collector. It is classified in the ugrandite group alongside the other calcium-bearing garnets andradite and grossular.
Adamite is a zinc arsenate hydroxide mineral, Zn2AsO4OH. It is a mineral that typically occurs in the oxidized or weathered zone above zinc ore occurrences. Pure adamite is colorless, but usually it possess yellow color due to Fe compounds admixture. Tints of green also occur and are connected with copper substitutions in the mineral structure. Olivenite is a copper arsenate that is isostructural with adamite and there is considerable substitution between zinc and copper resulting in an intermediate called cuproadamite. Zincolivenite is a recently discovered mineral being an intermediate mineral with formula CuZn(AsO4)(OH). Manganese, cobalt, and nickel also substitute in the structure. An analogous zinc phosphate, tarbuttite, is known.
Bournonite, wheel ore or berthonite (German: antimonbleikupferblende) is a sulfosalt mineral species, trithioantimoniate of lead and copper with the formula PbCuSbS3.
Livingstonite is a mercury antimony sulfosalt mineral. It occurs in low-temperature hydrothermal veins associated with cinnabar, stibnite, sulfur and gypsum.
Alabandite or alabandine, formerly known as manganese blende or bluemenbachite is a rarely occurring manganese sulfide mineral. It crystallizes in the cubic crystal system with the chemical composition Mn2+S and develops commonly massive to granular aggregates, but rarely also cubic or octahedral crystals to 1 cm.
Allactite is a rare arsenate mineral of metamorphosed manganese zinc ore deposits. It is found in Sweden and New Jersey, US. Its name originated from Greek αλλάκτειν (allaktein) meaning "to change", referring to the strong pleochroism of the mineral.
Andorite is a sulfosalt mineral with the chemical formula PbAgSb3S6.
Beudandite is a secondary mineral occurring in the oxidized zones of polymetallic deposits. It is a lead, iron, arsenate, sulfate with endmember formula: PbFe3(OH)6SO4AsO4.
Fettelite, also known as sanguinite, is a mercury-sulfosalt mineral with the chemical formula Ag16HgAs4S15. The mineral was first described by Wang and Paniagua (1996) who named it after M. Fettel, a German field geologist who collected the first samples from Odenwald. It was first collected in the Nieder-Beerbach mine, 10 km south of Darmstadt, Odenwald, Germany. Its normal occurrence is in hydrothermal veins, which can cut gabbro-diorite intrusives. It is closely related to other rare minerals like dervillite, daomanite, vaughanite and criddleite which are also found in the same type locality as fettelite.
Semseyite is a rarely occurring sulfosalt mineral and is part of the class of lead antimony sulfides. It crystallizes in the monoclinic system with the chemical composition Pb9Sb8S21. The mineral forms dark gray to black aggregates.
Vesselina Vassileva Breskovska was a 20th-century Bulgarian geologist, mineralogist and crystallographer.
Kostovite is a rare orthorhombic-pyramidal gray white telluride mineral containing copper and gold with chemical formula AuCuTe4.
Hemusite is a very rare isometric gray mineral containing copper, molybdenum, sulfur, and tin with chemical formula Cu6SnMoS8. It was discovered by Bulgarian mineralogist Georgi Ivanov Terziev in 1963. He also described it and named it after Haemus, the ancient name of Stara planina (Balkan) mountains in Europe. The type locality is Chelopech copper ore deposit, Bulgaria. Later tiny deposits of hemusite were found in Ozernovskoe deposit, Kamchatka, Russia; Kawazu mine, Rendaiji, Shimoda city, Chūbu region, Honshu Island, Japan; Iriki mine, Iriki, Satsuma-gun, Kagoshima Prefecture, Kyushu Region, Japan; Kochbulak deposit, Tashkent, Uzbekistan. Hemusite occurs as rounded isometric grains and aggregates usually about 0.05 mm in diameter and in association with enargite, luzonite, colusite, stannoidite, renierite, tennantite, chalcopyrite, pyrite, and other minerals.
Strashimirite is a rare monoclinic mineral containing arsenic, copper, hydrogen, and oxygen. It has the chemical formula Cu8(AsO4)4(OH)4·5(H2O).
Playfairite is a rare sulfosalt mineral with chemical formula Pb16Sb18S43 in the monoclinic crystal system, named after the Scottish scientist and mathematician John Playfair. It was discovered in 1966 by the Canadian mineralogist John Leslie Jambor. Lead gray to black in color, its luster is metallic. Playfairite shows strong reflection pleochroism from white to brownish gray. Playfairite has a hardness of 3.5 to 4 on Mohs scale and a specific gravity of approximately 5.72.
Bieberite (CoSO4 · 7H2O) is a pinkish red colored sulfate mineral high in cobalt content. The name is derived from the type locality at the copper deposit in Bieber, Hesse, Germany. It has been described and reported as far back as the 1700s. Bieberite primarily occurs as a secondary mineral, forming in cobalt-bearing arsenide and sulfide deposits through oxidation.
