Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, quantum field theory, quantum technology, and quantum information science.
Wave–particle duality is the concept in quantum mechanics that every particle or quantum entity may be described as either a particle or a wave. It expresses the inability of the classical concepts "particle" or "wave" to fully describe the behaviour of quantum-scale objects. As Albert Einstein wrote:
It seems as though we must use sometimes the one theory and sometimes the other, while at times we may use either. We are faced with a new kind of difficulty. We have two contradictory pictures of reality; separately neither of them fully explains the phenomena of light, but together they do.
Spintronics, also known as spin electronics, is the study of the intrinsic spin of the electron and its associated magnetic moment, in addition to its fundamental electronic charge, in solid-state devices. The field of spintronics concerns spin-charge coupling in metallic systems; the analogous effects in insulators fall into the field of multiferroics.
The Aharonov–Bohm effect, sometimes called the Ehrenberg–Siday–Aharonov–Bohm effect, is a quantum mechanical phenomenon in which an electrically charged particle is affected by an electromagnetic potential, despite being confined to a region in which both the magnetic field B and electric field E are zero. The underlying mechanism is the coupling of the electromagnetic potential with the complex phase of a charged particle's wave function, and the Aharonov–Bohm effect is accordingly illustrated by interference experiments.
The Penrose–Hawking singularity theorems are a set of results in general relativity that attempt to answer the question of when gravitation produces singularities. The Penrose singularity theorem is a theorem in semi-Riemannian geometry and its general relativistic interpretation predicts a gravitational singularity in black hole formation. The Hawking singularity theorem is based on the Penrose theorem and it is interpreted as a gravitational singularity in the Big Bang situation. Penrose was awarded the Nobel Prize in Physics in 2020 "for the discovery that black hole formation is a robust prediction of the general theory of relativity", which he shared with Reinhard Genzel and Andrea Ghez.
In relativistic physics, Lorentz symmetry or Lorentz invariance, named after the Dutch physicist Hendrik Lorentz, is an equivalence of observation or observational symmetry due to special relativity implying that the laws of physics stay the same for all observers that are moving with respect to one another within an inertial frame. It has also been described as "the feature of nature that says experimental results are independent of the orientation or the boost velocity of the laboratory through space".
In theoretical physics, the pilot wave theory, also known as Bohmian mechanics, was the first known example of a hidden-variable theory, presented by Louis de Broglie in 1927. Its more modern version, the de Broglie–Bohm theory, interprets quantum mechanics as a deterministic theory, avoiding troublesome notions such as wave–particle duality, instantaneous wave function collapse, and the paradox of Schrödinger's cat. To solve these problems, the theory is inherently nonlocal.
A Rydberg atom is an excited atom with one or more electrons that have a very high principal quantum number, n. The higher the value of n, the farther the electron is from the nucleus, on average. Rydberg atoms have a number of peculiar properties including an exaggerated response to electric and magnetic fields, long decay periods and electron wavefunctions that approximate, under some conditions, classical orbits of electrons about the nuclei. The core electrons shield the outer electron from the electric field of the nucleus such that, from a distance, the electric potential looks identical to that experienced by the electron in a hydrogen atom.
Negative refraction is the electromagnetic phenomenon where light rays become refracted at an interface that is opposite to their more commonly observed positive refractive properties. Negative refraction can be obtained by using a metamaterial which has been designed to achieve a negative value for (electric) permittivity (ε) and (magnetic) permeability (μ); in such cases the material can be assigned a negative refractive index. Such materials are sometimes called "double negative" materials.
Mott insulators are a class of materials that are expected to conduct electricity according to conventional band theories, but turn out to be insulators. These insulators fail to be correctly described by band theories of solids due to their strong electron–electron interactions, which are not considered in conventional band theory. A Mott transition is a transition from a metal to an insulator, driven by the strong interactions between electrons. One of the simplest models that can capture Mott transition is the Hubbard model.
Angle-resolved photoemission spectroscopy (ARPES) is an experimental technique used in condensed matter physics to probe the allowed energies and momenta of the electrons in a material, usually a crystalline solid. It is based on the photoelectric effect, in which an incoming photon of sufficient energy ejects an electron from the surface of a material. By directly measuring the kinetic energy and emission angle distributions of the emitted photoelectrons, the technique can map the electronic band structure and Fermi surfaces. ARPES is best suited for the study of one- or two-dimensional materials. It has been used by physicists to investigate high-temperature superconductors, graphene, topological materials, quantum well states, and materials exhibiting charge density waves.
Coherent diffractive imaging (CDI) is a "lensless" technique for 2D or 3D reconstruction of the image of nanoscale structures such as nanotubes, nanocrystals, porous nanocrystalline layers, defects, potentially proteins, and more. In CDI, a highly coherent beam of X-rays, electrons or other wavelike particle or photon is incident on an object.
The light-front quantization of quantum field theories provides a useful alternative to ordinary equal-time quantization. In particular, it can lead to a relativistic description of bound systems in terms of quantum-mechanical wave functions. The quantization is based on the choice of light-front coordinates, where plays the role of time and the corresponding spatial coordinate is . Here, is the ordinary time, is one Cartesian coordinate, and is the speed of light. The other two Cartesian coordinates, and , are untouched and often called transverse or perpendicular, denoted by symbols of the type . The choice of the frame of reference where the time and -axis are defined can be left unspecified in an exactly soluble relativistic theory, but in practical calculations some choices may be more suitable than others.
Speckle, speckle pattern, or speckle noise is a granular noise texture degrading the quality as a consequence of interference among wavefronts in coherent imaging systems, such as radar, synthetic aperture radar (SAR), medical ultrasound and optical coherence tomography. Speckle is not external noise; rather, it is an inherent fluctuation in diffuse reflections, because the scatterers are not identical for each cell, and the coherent illumination wave is highly sensitive to small variations in phase changes.
Resonant inelastic X-ray scattering (RIXS) is an X-ray spectroscopy technique used to investigate the electronic structure of molecules and materials.
The phase-space formulation of quantum mechanics places the position and momentum variables on equal footing in phase space. In contrast, the Schrödinger picture uses the position or momentum representations. The two key features of the phase-space formulation are that the quantum state is described by a quasiprobability distribution and operator multiplication is replaced by a star product.
The light-front quantization of quantum field theories provides a useful alternative to ordinary equal-time quantization. In particular, it can lead to a relativistic description of bound systems in terms of quantum-mechanical wave functions. The quantization is based on the choice of light-front coordinates, where plays the role of time and the corresponding spatial coordinate is . Here, is the ordinary time, is a Cartesian coordinate, and is the speed of light. The other two Cartesian coordinates, and , are untouched and often called transverse or perpendicular, denoted by symbols of the type . The choice of the frame of reference where the time and -axis are defined can be left unspecified in an exactly soluble relativistic theory, but in practical calculations some choices may be more suitable than others. The basic formalism is discussed elsewhere.
In nonlinear systems, a resonant interaction is the interaction of three or more waves, usually but not always of small amplitude. Resonant interactions occur when a simple set of criteria coupling wave-vectors and the dispersion equation are met. The simplicity of the criteria make technique popular in multiple fields. Its most prominent and well-developed forms appear in the study of gravity waves, but also finds numerous applications from astrophysics and biology to engineering and medicine. Theoretical work on partial differential equations provides insights into chaos theory; there are curious links to number theory. Resonant interactions allow waves to (elastically) scatter, diffuse or to become unstable. Diffusion processes are responsible for the eventual thermalization of most nonlinear systems; instabilities offer insight into high-dimensional chaos and turbulence.
Solar radio emission refers to radio waves that are naturally produced by the Sun, primarily from the lower and upper layers of the atmosphere called the chromosphere and corona, respectively. The Sun produces radio emissions through four known mechanisms, each of which operates primarily by converting the energy of moving electrons into radiation. The four emission mechanisms are thermal bremsstrahlung (braking) emission, gyromagnetic emission, plasma emission, and electron-cyclotron maser emission. The first two are incoherent mechanisms, which means that they are the summation of radiation generated independently by many individual particles. These mechanisms are primarily responsible for the persistent "background" emissions that slowly vary as structures in the atmosphere evolve. The latter two processes are coherent mechanisms, which refers to special cases where radiation is efficiently produced at a particular set of frequencies. Coherent mechanisms can produce much larger brightness temperatures (intensities) and are primarily responsible for the intense spikes of radiation called solar radio bursts, which are byproducts of the same processes that lead to other forms of solar activity like solar flares and coronal mass ejections.
In physics and chemistry, photoemission orbital tomography is a combined experimental / theoretical approach which reveals information about the spatial distribution of individual molecular orbitals. Experimentally, it uses angle-resolved photoemission spectroscopy (ARPES) to obtain constant binding energy photoemission angular distribution maps, so-called tomograms, to reveal information about the electron probability distribution in molecular orbitals. Theoretically, one rationalizes these tomograms as hemispherical cuts through the molecular orbital in momentum space. This interpretation relies on the assumption of a plane wave final state, i.e., the idea that the outgoing electron can be treated as a free electron, which can be further exploited to reconstruct real-space images of molecular orbitals on a sub-Ångström length scale in two or three dimensions. Presently, POT has been applied to various organic molecules forming well-oriented monolayers on single crystal surfaces or to two-dimensional materials.
