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A bubble bath is a filled bathtub with a layer of soap bubbles on the surface of the water. Less commonly, aerated or carbonated baths are called bubble baths.
Bubbles on top of the water, less ambiguously known as a foam bath (see photo), can be obtained by adding a product containing foaming surfactants to water and temporarily aerating it by agitation (often merely by the fall of water filling the tub). The practice is popular for personal bathing because of the belief that it cleanses the skin, that the foam insulates the bath water,[ citation needed ] keeping it warm for longer, and (as a lime soap dispersant) prevents or reduces deposits on the bath tub at and below the water level [ citation needed ] (called "bathtub ring" and soap scum, respectively) produced by soap and hard water. It can hide the body of the bather, preserving modesty or, in theatre and film, giving the appearance that a performer who is actually clothed is bathing normally. [1] Children often find bubble baths enjoyable, so they are an enticement to get them into the bathtub.
Surfactant preparations for this purpose are themselves called "bath foam", "foaming bath", or "bubble bath", and frequently contain ingredients for additional purposes common to bath enhancers. Used at much higher concentration (for instance on a washcloth), such preparations (especially in liquid format) may also be used to wash skin or hair, so they are sometimes marketed for combined purposes; in a few cases, mild household detergents for hand washing of articles have also been labeled for such purposes, or for preventing soap scum on the bathtub (with or without foaming).
The earliest foam baths were foamed with soap, a practice which came about shortly after soap flakes were marketed. Saponins were also used to foam machine-aerated baths. Foam baths became more popular with later surfactants; an early publicized use of an alkyl sulfate surfactant as bath foam was in the original 1936 production of the play The Women , but it is possible that a similar composition was used to produce foams seen in bath photos since the marketing of Dreft in 1933. Foam baths became standard practice for bathing children after the mass marketing of products so positioned in supermarkets during the 1960s and thereabouts, Bub and Matey in the United States having been marketed shortly before 1960. The dubious claim had been made that their normal use (diluted in a tubful of water) would substitute for soap and/or rubbing to clean skin.[ citation needed ]
Preparations to produce a foam bath must be able at high dilution in water of common "hardness" to produce a foam and hold it for a useful duration. This is practically always done primarily by the action of an anionic, nonionic, or zwitterionic surfactant. Among cation surfactants betaines can be used in foam baths, but at their isoelectric point they are incompatible with anionic surfactants. In general cationic surfactants are not used as most of them are not compatible with anionic surfactants and are not good foaming agents. Main function of cationic surfactants is conditioning and are hence used more in personal care products such as shampoos and conditioners. Amphoteric surfactants or zwitterionic surfactants like alkyl amido alkyl amine (CAPB) are used. Typically a mixture of different surfactants is used. Of the anionics, soap is not a common deliberate constituent of bath foam preparations because they react rapidly with "hardness" cations in water to produce lime soaps, which are anti-foams. Usually one or more ingredients is primarily a foam stabilizer—a substance which retards the breakage of foams; these may themselves be surfactants or film-stabilizing polymers. Some surfactants used in foaming preparations may have a combination of foam-producing and foam-stabilizing properties. Surfactants used in bath foam preparations may also be included for primarily non-foaming purposes: solubilization of other components in the manufacturing of a liquid product, or lime soap dispersion to prevent bathtub ring when used with soap.
Bath foam preparations may be in the form of liquid (or gel) with water, or as solids in the form of powders, grains, or tablets. Liquids must be formulated to retain uniformity as solution or otherwise on storage at expected temperatures, and preserved against microbial growth and oxidative breakdown. Powders may contain various solid diluent ingredients which in some cases will have liquid components adsorbed to them, and have their own challenges in terms of retaining uniformity against sifting of different densities of components. For various reasons, although powdered products were more common at first, liquids have come to dominate the market.
Liquid and solid bath foam preparations may also include ingredients for purposes other than foaming, similarly to bath salts and oils. Formulation is also directed at minimizing adverse effects on the skin and exposed mucous membranes of bathers. Sometimes foaming ability is compromised to achieve mildness or non-foaming effects such as emolliency.
Bubbles in the water can be produced either by aerating it mechanically (in some cases using jets that also move the water) using equipment installed permanently or temporarily in a bathtub, hot tub, or pool, or by producing gas in the water in a bathtub through the use of effervescent solids. The latter can come as small pellets known as bath fizzies or as a bolus known as a bath bomb, and they produce carbon dioxide by reaction of a bicarbonate or carbonate with an organic acid. Fizzing bath products came into use as effervescent bath salts early in the 20th century; the bath bomb became a popular form late in that century.
Bath fizzies are infeasible as liquids because of the inability to keep the mixture from reacting prematurely. This is a distinction from foam bath (see above) preparations, which may be supplied as liquids or solids.
Machine-aerated baths originated in the early 20th century for therapeutic use, becoming more widely used with the introduction of the jacuzzi. Trends merged when the hot tub, which originally had still water, with its increasing popularity became more commonly a communal whirlpool bath. By the late 20th century jetted bathtubs had become popular for home installation.
It is possible to produce baths with bubbles simultaneously in and on top of the water (as in a poured beer), but the combination has not been popular. Mechanical aeration of a foam bath may produce much more foam than is sought—the Internet is replete with first hand accounts and sometimes photographs of such experiences—and many mechanically aerated baths are hot tubs which are shared and not drained between uses and so are desired to be kept free of non-maintenance materials. Mechanically aerated baths for tissue debridement of burn victims typically have added anti-foaming agents to counteract the film-forming properties that some medicinal additives have as a side effect, but the anti-foam is sometimes omitted or reduced for children to give them more of a pleasant distraction during debridement. Bath fizzies that also foam tend to produce disappointingly little foam when allowed to do so from their own fizz, and aeration of the water loses the gas from the fizz.
When the term "bubble bath" is encountered on the Internet referring to a gas-infused bath or pool, it is more often by a non-native user of English who may not be aware of its use to refer to foam baths (see above). In other languages the distinction is more likely to be kept by use of different words; for example in Dutch schuimbad refers to a bubble bath and bubbelbad refers to a jacuzzi which can produce bubbles on its own.
Sodium dodecyl sulfate (SDS) or sodium lauryl sulfate (SLS), sometimes written sodium laurilsulfate, is an organic compound with the formula CH3(CH2)11OSO3Na and structure H3C−(CH2)11−O−S(=O)2−O−Na+. It is an anionic surfactant used in many cleaning and hygiene products. This compound is the sodium salt of the 12-carbon organosulfate. Its hydrocarbon tail combined with a polar "headgroup" give the compound amphiphilic properties that make it useful as a detergent. SDS is also component of mixtures produced from inexpensive coconut and palm oils. SDS is a common component of many domestic cleaning, personal hygiene and cosmetic, pharmaceutical, and food products, as well as of industrial and commercial cleaning and product formulations.
A detergent is a surfactant or a mixture of surfactants with cleansing properties when in dilute solutions. There are a large variety of detergents, a common family being the alkylbenzene sulfonates, which are soap-like compounds that are more soluble in hard water, because the polar sulfonate is less likely than the polar carboxylate to bind to calcium and other ions found in hard water.
Surfactants are chemical compounds that decrease the surface tension or interfacial tension between two liquids, a liquid and a gas, or a liquid and a solid. The word "surfactant" is a blend of surface-active agent, coined in 1950. As they consist of a water-repellent and a water-attracting part, they enable water and oil to mix; they can form foam and facilitate the detachment of dirt.
A bathroom is a room in which people wash their bodies or parts thereof. It can contain one or more of the following plumbing fixtures: a shower, a bathtub, a bidet, and a sink. The inclusion of a toilet is common. There are also specific toilet rooms, only containing a toilet, which in North American English tend to be called "bathrooms", "powder rooms" or "washrooms", as euphemisms to conceal their actual purpose, while they in British and Irish English are known as just "toilets" or possibly "cloakrooms" - but also as "lavatories" when they are public.
Foams are two-phase material systems where a gas is dispersed in a second, non-gaseous material, specifically, in which gas cells are enclosed by a distinct liquid or solid material. The foam "may contain more or less liquid [or solid] according to circumstances", although in the case of gas-liquid foams, the gas occupies most of the volume. The word derives from the medieval German and otherwise obsolete veim, in reference to the "frothy head forming in the glass once the beer has been freshly poured".
A bathtub, also known simply as a bath or tub, is a container for holding water in which a person or another animal may bathe. Most modern bathtubs are made of thermoformed acrylic, porcelain-enameled steel or cast iron, or fiberglass-reinforced polyester. A bathtub is placed in a bathroom, either as a stand-alone fixture or in conjunction with a shower.
A fabric softener or fabric conditioner is a conditioner applied to laundry after it has been washed in a washing machine. A similar, more dilute preparation meant to be applied to dry fabric is known as a wrinkle releaser.
A foaming agent is a material such as a surfactant or a blowing agent that facilitates the formation of foam. A surfactant, when present in small amounts, reduces surface tension of a liquid or increases its colloidal stability by inhibiting coalescence of bubbles. A blowing agent is a gas that forms the gaseous part of the foam.
Laundry detergent is a type of detergent used for cleaning dirty laundry (clothes). Laundry detergent is manufactured in powder and liquid form.
Dishwashing liquid, also known as dishwashing soap, dish detergent, or dish soap, is a detergent used in dishwashing. Dishwashing detergent for dishwashers comes in various forms such as cartridges, gels, liquids, packs, powder, and tablets. It is usually a highly-foamy mixture of surfactants with low skin irritation that consumers primarily use for washing glasses, plates, cutleries, and cooking utensils. In addition to its primary use, dishwashing liquid is also used for various informal applications, like creating bubbles, clothes washing, and cleaning birds affected by oil spills.
Shower gel is a specialized liquid product used for cleaning the body during showers. Not to be confused with liquid soaps, shower gels, in fact, do not contain saponified oil. Instead, it uses synthetic detergents derived from either petroleum or plant sources.
Bath salts are water-soluble, pulverized minerals that are added to water to be used for bathing. It is said that these salts improve cleaning, enhance the enjoyment of bathing, and serve as a vehicle for cosmetic agents. Bath salts have been developed which mimic the properties of natural mineral baths or hot springs. Some bath salts contain glycerine so the product will act as an emollient, humectant, or lubricant. Fragrances and colors are often added to bath salts; the fragrances are used to increase the users' enjoyment of the bathing experience.
In organosulfur chemistry, organosulfates are a class of organic compounds sharing a common functional group with the structure R−O−SO−3. The SO4 core is a sulfate group and the R group is any organic residue. All organosulfates are formally esters derived from alcohols and sulfuric acid although many are not prepared in this way. Many sulfate esters are used in detergents, and some are useful reagents. Alkyl sulfates consist of a hydrophobic hydrocarbon chain, a polar sulfate group and either a cation or amine to neutralize the sulfate group. Examples include: sodium lauryl sulfate and related potassium and ammonium salts.
Cleaning agents or hard-surface cleaners are substances used to remove dirt, including dust, stains, foul odors, and clutter on surfaces. Purposes of cleaning agents include health, beauty, removing offensive odors, and avoiding the spread of dirt and contaminants to oneself and others. Some cleaning agents can kill bacteria and clean at the same time. Others, called degreasers, contain organic solvents to help dissolve oils and fats.
Shampoo is a hair care product, typically in the form of a viscous liquid, that is used for cleaning hair. Less commonly, shampoo is available in solid bar format. Shampoo is used by applying it to wet hair, massaging the product into the scalp, and then rinsing it out. Some users may follow a shampooing with the use of hair conditioner.
A defoamer or an anti-foaming agent is a chemical additive that reduces and hinders the formation of foam in industrial process liquids. The terms anti-foam agent and defoamer are often used interchangeably. Strictly speaking, defoamers eliminate existing foam and anti-foamers prevent the formation of further foam. Commonly used agents are insoluble oils, polydimethylsiloxanes and other silicones, certain alcohols, stearates and glycols. The additive is used to prevent formation of foam or is added to break a foam already formed.
Paint has four major components: pigments, binders, solvents, and additives. Pigments serve to give paint its color, texture, toughness, as well as determining if a paint is opaque or not. Common white pigments include titanium dioxide and zinc oxide. Binders are the film forming component of a paint as it dries and affects the durability, gloss, and flexibility of the coating. Polyurethanes, polyesters, and acrylics are all examples of common binders. The solvent is the medium in which all other components of the paint are dissolved and evaporates away as the paint dries and cures. The solvent also modifies the curing rate and viscosity of the paint in its liquid state. There are two types of paint: solvent-borne and water-borne paints. Solvent-borne paints use organic solvents as the primary vehicle carrying the solid components in a paint formulation, whereas water-borne paints use water as the continuous medium. The additives that are incorporated into paints are a wide range of things which impart important effects on the properties of the paint and the final coating. Common paint additives are catalysts, thickeners, stabilizers, emulsifiers, texturizers, biocides to fight bacterial growth, etc.
Alkylbenzene sulfonates are a class of anionic surfactants, consisting of a hydrophilic sulfonate head-group and a hydrophobic alkylbenzene tail-group. Along with sodium laureth sulfate, they are one of the oldest and most widely used synthetic detergents and may be found in numerous personal-care products and household-care products . They were introduced in the 1930s in the form of branched alkylbenzene sulfonates (BAS). However following environmental concerns these were replaced with linear alkylbenzene sulfonates (LAS) during the 1960s. Since then production has increased significantly from about one million tons in 1980, to around 3.5 million tons in 2016, making them most produced anionic surfactant after soaps.
Dishwasher detergent is a detergent made for washing dishes in a dishwasher. Dishwasher detergent is different from dishwashing liquid made to wash dishes by hand.
Taurates (or taurides) are a group of mild anionic surfactants. They are composed of a hydrophilic head group, consisting of N-methyltaurine (2-methylaminoethanesulfonic acid) and a lipophilic residue, consisting of a long-chain carboxylic acid (fatty acid), both linked via an amide bond. The fatty acids used could be lauric (C12), myristic (C14), palmitic (C16) or stearic acid (C18), but mainly mixtures of oleic acid (C18:1) and coconut fatty acid (C8 – C18) are used. Besides sodium, no other counterions play a relevant role (these could be e. g. ammonium or other alkali or alkaline earth metals).