Collodion is a flammable, syrupy solution of nitrocellulose in ether and alcohol. There are two basic types: flexible and non-flexible. The flexible type is often used as a surgical dressing or to hold dressings in place. When painted on the skin, collodion dries to form a flexible nitrocellulose film. While it is initially colorless, it discolors over time. Non-flexible collodion is often used in theatrical make-up. Collodion was also the basis of most wet-plate photography until it was superseded by modern gelatin emulsions.
In 1846, Louis-Nicolas Ménard and Florès Domonte discovered that cellulose nitrate could be dissolved in ether. [1] They devised a mixture of ether (ethoxyethane) as the solvent and ethanol as a diluent that rendered cellulose nitrate into a clear gelatinous liquid. Collodion was first used medically as a dressing in 1847 by the Boston physician John Parker Maynard. [2] [3] The solution was dubbed "collodion" (from the Greek κολλώδης (kollodis), gluey) by Dr. A.A. Gould of Boston, Massachusetts. [4]
In 1851, Frederick Scott Archer, an Englishman, discovered that collodion could be used as an alternative to egg white (albumen) on glass photographic plates. [5] Collodion reduced the exposure time necessary for making an image. This method became known as the 'wet-plate collodion' or 'wet collodion' method. Collodion was relatively grainless and colorless, and allowed for one of the first high-quality duplication processes, also known as negatives. This process also produced two types of positives: the ambrotype and the tintype (also known as ferrotype).
The process required great skill and included the following steps:
All of this was done in a matter of minutes, and some of the steps in (red) safelight conditions, which meant that the photographer had to carry the chemicals and a portable darkroom with him wherever he went. After these steps the plate needed rinsing in fresh water. Finally, the plate was dried and varnished using a varnish made from sandarac, alcohol and lavender oil.
Dark tents to be used outdoors consisted of a small tent that was tied around the photographer's waist. Otherwise a wheelbarrow or a horse and covered wagon were used.
Richard Hill Norris, a doctor of medicine and professor of physiology at Queen's College, Birmingham (a predecessor college of Birmingham University), [6] is generally credited with the first development of dry collodion plate when in 1856 he took out a new patent for a dry plate used in photography in which the emulsion was coated with gelatine or gum arabic to preserve its sensitivity. Another method, using tannin, invented by Major C. Russell in 1861, followed and in 1864 W.E. Bolton and E.J. Sayce mixed silver bromide with collodion, so that by the mid-1860s the wet-plate process was being replaced. [7]
Nitrocellulose is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and sulfuric acid. One of its first major uses was as guncotton, a replacement for gunpowder as propellant in firearms. It was also used to replace gunpowder as a low-order explosive in mining and other applications. In the form of collodion it was also a critical component in an early photographic emulsion, the use of which revolutionized photography in the 1860s.
Celluloids are a class of materials produced by mixing nitrocellulose and camphor, often with added dyes and other agents. Once much more common for its use as photographic film before the advent of safer methods, celluloid's common present-day uses are for manufacturing table tennis balls, musical instruments, combs, office equipment, fountain pen bodies, and guitar picks.
The collodion process is an early photographic process. The collodion process, mostly synonymous with the "collodion wet plate process", requires the photographic material to be coated, sensitized, exposed, and developed within the span of about fifteen minutes, necessitating a portable darkroom for use in the field. Collodion is normally used in its wet form, but it can also be used in its dry form, at the cost of greatly increased exposure time. The increased exposure time made the dry form unsuitable for the usual portraiture work of most professional photographers of the 19th century. The use of the dry form was mostly confined to landscape photography and other special applications where minutes-long exposure times were tolerable.
The albumen print, also called albumen silver print, is a method of producing a photographic print using egg whites. Published in January 1847 by Louis Désiré Blanquart-Evrard, it was the first commercial process of producing a photo on a paper base from a negative, previous methods - such as the daguerreotype and the tintype - having been printed on metal. It became the dominant form of photographic positives from 1855 to the start of the 20th century, with a peak in the 1860–90 period. During the mid-19th century, the carte de visite became one of the more popular uses of the albumen method. In the 19th century, E. & H. T. Anthony & Company were the largest makers and distributors of albumen photographic prints and paper in the United States.
The gelatin silver process is the most commonly used chemical process in black-and-white photography, and is the fundamental chemical process for modern analog color photography. As such, films and printing papers available for analog photography rarely rely on any other chemical process to record an image. A suspension of silver salts in gelatin is coated onto a support such as glass, flexible plastic or film, baryta paper, or resin-coated paper. These light-sensitive materials are stable under normal keeping conditions and are able to be exposed and processed even many years after their manufacture. The "dry plate" gelatin process was an improvement on the collodion wet-plate process dominant from the 1850s–1880s, which had to be exposed and developed immediately after coating.
A silver halide is one of the chemical compounds that can form between the element silver (Ag) and one of the halogens. In particular, bromine (Br), chlorine (Cl), iodine (I) and fluorine (F) may each combine with silver to produce silver bromide (AgBr), silver chloride (AgCl), silver iodide (AgI), and four forms of silver fluoride, respectively.
The ambrotype also known as a collodion positive in the UK, is a positive photograph on glass made by a variant of the wet plate collodion process. Like a print on paper, it is viewed by reflected light. Like the daguerreotype, which it replaced, and like the prints produced by a Polaroid camera, each is a unique original that could only be duplicated by using a camera to copy it.
A tintype, also known as a melanotype or ferrotype, is a photograph made by creating a direct positive on a thin sheet of metal, colloquially called 'tin', coated with a dark lacquer or enamel and used as the support for the photographic emulsion. It was introduced in 1853 by Adolphe Alexandre Martin in Paris, like the daguerreotype was fourteen years before by Daguerre. The daguerreotype was established and most popular by now, though the primary competition for the tintype would have been the ambrotype, that shared the same collodion process, but on a glass support instead of metal. Both found unequivocal, if not exclusive, acceptance in North America. Tintypes enjoyed their widest use during the 1860s and 1870s, but lesser use of the medium persisted into 1930s and it has been revived as a novelty and fine art form in the 21st century. It has been described as the first "truly democratic" medium for mass portraiture.
The conservation and restoration of photographs is the study of the physical care and treatment of photographic materials. It covers both efforts undertaken by photograph conservators, librarians, archivists, and museum curators who manage photograph collections at a variety of cultural heritage institutions, as well as steps taken to preserve collections of personal and family photographs. It is an umbrella term that includes both preventative preservation activities such as environmental control and conservation techniques that involve treating individual items. Both preservation and conservation require an in-depth understanding of how photographs are made, and the causes and prevention of deterioration. Conservator-restorers use this knowledge to treat photographic materials, stabilizing them from further deterioration, and sometimes restoring them for aesthetic purposes.
A film base is a transparent substrate which acts as a support medium for the photosensitive emulsion that lies atop it. Despite the numerous layers and coatings associated with the emulsion layer, the base generally accounts for the vast majority of the thickness of any given film stock. Since the late 19th century, there have been three major types of film base in use: nitrate, acetate, and polyester.
Richard Leach Maddox was an English photographer and physician who invented lightweight gelatin negative dry plates for photography in 1871.
Leon Warnerke was a Polish civil engineer and inventor in the field of photography, independence activist, revolutionary and successful forger. Leon Warnerke was a pseudonym; his real name was Władysław Małachowski.
The Collodion-Albumen process is one of the early dry plate processes, invented by Joseph Sidebotham in 1861.
Photographic emulsion is a light-sensitive colloid used in film-based photography. Most commonly, in silver-gelatin photography, it consists of silver halide crystals dispersed in gelatin. The emulsion is usually coated onto a substrate of glass, films, paper, or fabric. The substrate is often flexible and known as a film base.
William H. Bell was an English-born American photographer in the latter half of the 19th century. Many of his photographs documenting war-time diseases and combat injuries were published in the medical book, Medical and Surgical History of the War of the Rebellion, and he took photographs of western landscapes taken as part of the Wheeler expedition in 1872. In his later years, he wrote articles on the dry plate process and other techniques for various photography journals.
The practice and appreciation of photographyin the United States began in the 19th century, when various advances in the development of photography took place and after daguerreotype photography was introduced in France in 1839. The earliest commercialization of photography was made in the country when Alexander Walcott and John Johnson opened the first commercial portrait gallery in 1840. In 1866, the first color photograph was taken. Only in the 1880s, would photography expand to a mass audience with the first easy-to-use, lightweight Kodak camera, issued by George Eastman and his company.
The conservation and restoration of film is the physical care and treatment of film-based materials. These include photographic film and motion picture film stock.
The conservation and restoration of photographic plates is caring for and maintaining photographic plates to preserve their materials and content. It covers the necessary measures that can be taken by conservators, curators, collection managers, and other professionals to conserve the material unique to photographic plate processes. This practice includes understanding the composition and agents of deterioration of photographic plates, as well as the preventive conservation and interventive conservation measures that can be taken to increase their longevity.
The Wothlytype was an alternative photographic printing process, the eponymous 1864 invention of the German Jacob Wothly, in which a mixture of uranium ammonio-nitrate and silver nitrate in collodion formed a light-sensitive layer.