Nail polish (also known as nail varnish in British English or nail enamel) is a lacquer that can be applied to the human fingernails or toenails to decorate and protect the nail plates. The formula has been revised repeatedly to enhance its decorative properties, to be safer for the consumer to use, and to suppress cracking or peeling. Nail polish consists of a mix of an organic polymer and several other components that give it colors and textures. [1] Nail polishes come in all color shades and play a significant part in manicures and pedicures.
Nail polish originated in China and dates back to 3000 BCE. [1] [2] Around 600 BCE, during the Zhou dynasty, the royal house preferred the colors gold and silver. [1] However, red and black eventually replaced these metallic colors as royal favorites. [1] During the Ming dynasty, nail polish was often made from a mixture that included beeswax, egg whites, gelatin, vegetable dyes, and gum arabic. [1] [2]
In Egypt, the lower classes wore pale colors of nail polish, whereas high society painted their nails a reddish brown with henna. [3] [4] Mummified pharaohs also had their nails painted with henna. [5]
In Europe, Frederick S. N. Douglas, while traveling in Greece in 1810–1812, noticed that the Greek women used to paint their nails "dingy pink", which he understood as an ancient custom. [6] Early nail polish formulas were created using basic ingredients such as lavender oil, carmine, oxide tin, and bergamot oil. [7] [ self-published source ] It was more common to polish nails with tinted powders and creams, finishing off by buffing the nail until left shiny. One type of polishing product sold around this time was Graf's Hyglo nail polish paste. [7] [ self-published source ]
In Victorian era culture it was generally considered improper for women to adorn themselves with either makeup or nail coloring, since natural appearances were considered more chaste and pure. In the 1920s, however, women began to wear color in new makeups and nail products, partly in rebellion to such prim customs of their recent past.[ citation needed ] In 1920s France, a big pioneer of nail polish was the hairstylist Antoine de Paris, whose cosmetic company produced some of the first modern polishes, and he himself shocked the newspapers by wearing each nail painted a different color. [8]
Since the 1920s, nail colors progressed from French manicures and standard reds to various palettes of color choices, usually coordinated with the fashion industry's clothing colors for the season. By the 1940s the whole nail was painted; before that, it was fashionable to leave the tips and a half-moon on the nail bed bare.[ citation needed ]
Modern nail polish consists predominately of a film-forming polymer dissolved in a volatile organic solvent. The most common polymer is nitrocellulose, although the more expensive cellulose acetates such as CAB are claimed to give better performance. In gel nail varnish, the polymer is usually some sort of acrylate copolymer. The solvents are commonly butyl acetate or ethyl acetate. Low levels of various additives are included to give the desired finish: [9]
This type of nail polish is a clear, milky-colored, or opaque pink polish formula that is used specifically before applying nail polish to the nail. [13] Its function is to strengthen nails, restore moisture to the nail, and help polish adhere to the nail. It prevents staining and extends the lifespan of the manicure. [14] Some base coats are marketed as "ridge fillers", and can create a smooth surface, de-emphasizing the ridges that can appear on unbuffed nails. Some base coats, called "peel off base coats", allow the user to peel off their nail polish without using a remover.
This type of nail polish is a clear colored polish formula that is used specifically after applying nail polish to the nail. It forms a hardened barrier for the nail that can prevent chipping, scratching and peeling. Many topcoats are marketed as "quick-drying." Topcoats can help the underlying colored polish dry quickly as well. It gives the polish a more finished and desired look and may help to keep the polish on longer. [14]
Gel polish is a long-lasting variety of nail polish made up of a type of methacrylate polymer. It is painted on the nail similar to traditional nail polish, but does not dry. Instead it is cured under an ultraviolet lamp or ultraviolet LED. While regular nail polish formulas typically last two to seven days without chipping, gel polish can last as long as two weeks with proper application and home care. Gel polish can be more difficult to remove than regular nail polish. It is usually removed by soaking the nails in pure acetone (the solvent used in most nail polish removers) for five to fifteen minutes, depending on the formula.
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Traditionally, nail polish started in clear, white, red, pink, purple, and black. Nail polish can be found in a diverse variety of colors and shades. Beyond solid colors, nail polish has also developed an array of other designs, such as crackled, glitter, flake, speckled, iridescent, and holographic. Rhinestones or other decorative art are also often applied to nail polish. Some polish is advertised to induce nail growth, make nails stronger, prevent nails from breaking, cracking, or splitting, and even to stop nail biting.
French manicures are designed to resemble natural nails, and are characterized by natural pink or nude base nails with white tips. French manicures were one of the first popular and well-known color schemes. French manicures may have originated in the eighteenth-century in Paris but were most popular in the 1920s and 1930s. However, the traditional French manicures were much different from what we know today. They were generally red, while leaving a round crescent shape at the area near the cuticle blank to enhance the lunula of the nail, known now as a half-moon manicure.[ citation needed ]
With the modern French manicure, trends involving painting different colors for the tips of the nails instead of the white. French tip nails can be made with stickers and stencils. It is still typically done by hand through painting with polish or gel, or sculptured with acrylic.[ citation needed ]
Nail art is a creative way to paint, decorate, enhance, and embellish nails. Social media has expanded to a nail art culture by allowing users to share pictures of their nail art. Women's Wear Daily reports nail polish sales hit a record US$768 million in the United States in 2012, a 32% gain over 2011. [15] Several new polishes and related products came on to the market in the 2020s as part of the explosion of nail art, such as nail stickers (either made of nail polish or plastic), stencils, magnetic nail polish, [16] nail pens, glitter and sequin topcoats, nail caviar (micro beads), nail polish marketed for men, scented nail polish, and color changing nail polish (some which change hue when exposed to sunshine, and ranges which change hue in response to heat).
Nail polish in the Western world was more frequently worn by women, going in and out of acceptability depending upon moral customs of the day. It is less common for men to wear nail polish, and can be seen as a divergence from traditional gender norms. [17] Colored and clear polishes can be used to protect nails from breakage, impart a well-groomed sheen, or express oneself artistically. [18] Professional baseball players, especially catchers, may wear nail polish on the field. [19]
There are 18 principal nail polish finishes: [20] [ self-published source ]
Nail polish remover is an organic solvent that may also include oils, scents, and coloring. Nail polish remover packages may include individual felt pads soaked in remover, a bottle of liquid remover used with a cotton ball or cotton pad, or a foam-filled container into which one inserts a finger and twists it until the polish comes off. The choice of remover type depends on the user's preference, and often the price or quality of the remover.
The most common remover is acetone. Acetone can also remove artificial nails made of acrylic or cured gel.
An alternative nail polish remover is ethyl acetate, which often also contains isopropyl alcohol. Ethyl acetate is usually the original solvent for nail polish itself.
Acetonitrile has been used as a nail polish remover, but it is more toxic than the aforementioned options. It has been banned in the European Economic Area for use in cosmetics since 17 March 2000. [22]
The health risks associated with nail polish are disputed. According to the U.S. Department of Health and Human Services, "The amount of chemicals used in animal studies is probably a couple of hundred times higher than what you would be exposed to from using nail polish every week or so. So the chances of any individual phthalate producing such harm [in humans] is very slim." [23] A more serious health risk is faced by professional nail technicians, who perform manicures over a workstation, known as a nail table, on which the client's hands rest – directly below the technician's breathing zone. In 2009, Susan Reutman, an epidemiologist with the U.S. National Institute for Occupational Safety and Health's Division of Applied Research and Technology, announced a federal effort to evaluate the effectiveness of downdraft vented nail tables (VNTs) in removing potential nail polish chemical and dust exposures from the technician's work area. [24] These ventilation systems have potential to reduce worker exposure to chemicals by at least 50%. [25] Many nail technicians will often wear masks to cover their mouth and nose from inhaling any of the harsh dust or chemicals from the nail products.
According to Reutman, a growing body of scientific literature suggests that some inhaled and absorbed organic solvents found in nail salons such as glycol ethers and carbon disulfide may have adverse effects on reproductive health. These effects may including birth defects, low birth weight, miscarriage, and preterm birth. [24]
Nail polish formulations may include ingredients that are toxic or affect other health problems. One controversial family of ingredient are phthalates, [12] which are implicated as endocrine disruptors and linked to problems in the endocrine system and increased risk of diabetes. Manufacturers have been pressured by consumer groups to reduce or to eliminate potentially-toxic ingredients, [26] and in September 2006, several companies agreed to phase out dibutyl phthalates. [27] [28] There are no universal consumer safety standards for nail polish, however, and while formaldehyde has been eliminated from some nail polish brands, others still use it. [29]
The U.S. city of San Francisco enacted a city ordinance, publicly identifying establishments that use nail polishes free of the "toxic trio" of dibutyl phthalate, toluene, and formaldehyde. [30]
Nail polish is considered a hazardous waste by some regulatory bodies such as the Los Angeles Department of Public Works. [31] Many countries have strict restrictions on sending nail polish by mail. [32] [33] The "toxic trio" are currently being phased out, but there are still components of nail polish that could cause environmental concern. Leaking out of the bottle into the soil could cause contamination in ground water. [34] [35] Chromium(III) oxide green and Prussian blue are common in nail polish and have shown evidence of going through chemical degradation, which could have a detrimental effect on health.[ citation needed ]
Acetonitrile, often abbreviated MeCN, is the chemical compound with the formula CH3CN and structure H3C−C≡N. This colourless liquid is the simplest organic nitrile. It is produced mainly as a byproduct of acrylonitrile manufacture. It is used as a polar aprotic solvent in organic synthesis and in the purification of butadiene. The N≡C−C skeleton is linear with a short C≡N distance of 1.16 Å.
Cosmetics are composed of mixtures of chemical compounds derived from either natural sources or synthetically created ones. Cosmetics have various purposes, including personal and skin care. They can also be used to conceal blemishes and enhance natural features. Makeup can also add colour to a person's face, enhance a person's features or change the appearance of the face entirely to resemble a different person, creature, or object.
A manicure is a mostly cosmetic beauty treatment for the fingernails and hands performed at home or in a nail salon. A manicure usually consists of filing and shaping the free edge of nails, pushing and clipping any nonliving tissue at the cuticle and removing hangnails, treatments with various liquids, massage of the hand, and the application of fingernail polish. When the same is applied to the toenails and feet, the treatment is referred to as a pedicure. Together, the treatments may be known as a mani-pedi.
Phthalates, or phthalate esters, are esters of phthalic acid. They are mainly used as plasticizers, i.e., substances added to plastics to increase their flexibility, transparency, durability, and longevity. They are used primarily to soften polyvinyl chloride (PVC). Note that while phthalates are usually plasticizers, not all plasticizers are phthalates. The two terms are specific and unique and cannot be used interchangeably.
Cosmetology is the study and application of beauty treatment. Branches of specialty include hairstyling, skin care, cosmetics, manicures/pedicures, non-permanent hair removal such as waxing and sugaring, and permanent hair removal processes such as electrology and intense pulsed light (IPL).
A plasticizer is a substance that is added to a material to make it softer and more flexible, to increase its plasticity, to decrease its viscosity, and/or to decrease friction during its handling in manufacture.
Polymer clay is a type of hardenable modeling clay based on the polymer polyvinyl chloride (PVC). It typically contains no clay minerals, but like mineral clay a liquid is added to dry particles until it achieves gel-like working properties. Similarly, the part is put into an oven to harden, hence its colloquial designation as clay. Polymer clay is generally used for making arts and craft items, and is also used in commercial applications to make decorative parts. Art made from polymer clay can now be found in major museums.
Air fresheners are products designed to reduce unwanted odors in indoor spaces, or to introduce pleasant fragrances, or both. They typically emit fragrance to mask odors but may use other methods of action such as absorbing, bonding to, or chemically altering compounds in the air that produce smells, killing organisms that produce smells, or disrupting the sense of smell to reduce perception of unpleasant smells.
Methyl acetate, also known as MeOAc, acetic acid methyl ester or methyl ethanoate, is a carboxylate ester with the formula CH3COOCH3. It is a flammable liquid with a characteristically pleasant smell reminiscent of some glues and nail polish removers. Methyl acetate is occasionally used as a solvent, being weakly polar and lipophilic, but its close relative ethyl acetate is a more common solvent being less toxic and less soluble in water. Methyl acetate has a solubility of 25% in water at room temperature. At elevated temperature its solubility in water is much higher. Methyl acetate is not stable in the presence of strong aqueous bases or aqueous acids. Methyl acetate is not considered a VOC in the USA.
Acetone is an organic compound with the formula (CH3)2CO. It is the simplest and smallest ketone. It is a colorless, highly volatile, and flammable liquid with a characteristic pungent odour, very reminiscent of the smell of pear drops.
Spray paint is paint that comes in a sealed, pressurized container and is released in an aerosol spray when a valve button is depressed. The propellant is what the container of pressurized gas is called. When the pressure holding the gas is released through the valve, the aerosol paint releases as a fine spray. Aerosol painting is one form of spray painting; it leaves a smooth, even coat, unlike many traditional rolled and brushed paints. Aerosol primer can be applied directly to bare metal and many plastics.
A primer or undercoat is a preparatory coating put on materials before painting. Priming ensures better adhesion of paint to the surface, increases paint durability, and provides additional protection for the material being painted.
Diisobutyl phthalate (DIBP) is a phthalate ester having the structural formula C6H4(COOCH2CH 2)2. It is formed by the esterification of isobutanol and phthalic anhydride. This and other phthalates are used as plasticizers due to their flexibility and durability. They are found in many industrial and personal products, such as lacquers, nail polish and cosmetics. DIBP can be absorbed via oral ingestion and dermal exposure. When it comes to excretion, DIBP is first converted into the hydrolytic monoester monoisobutyl phthalate (MIBP). The primary excretory route is urine, with biliary excretion being noted in minor amounts. DIBP has lower density and freezing point than the related compound dibutyl phthalate (DBP).
Nitroethane is an organic compound having the chemical formula C2H5NO2. Similar in many regards to nitromethane, nitroethane is an oily liquid at standard temperature and pressure. Pure nitroethane is colorless and has a fruity odor.
Cellulose acetate phthalate (CAP), also known as cellacefate (INN) and cellulosi acetas phthalas, is a commonly used polymer phthalate in the formulation of pharmaceuticals, such as the enteric coating of tablets or capsules and for controlled release formulations. It is a cellulose polymer where about half of the hydroxyls are esterified with acetyls, a quarter are esterified with one or two carboxyls of a phthalic acid, and the remainder are unchanged. It is a hygroscopic white to off-white free-flowing powder, granules, or flakes. It is tasteless and odorless, though may have a weak odor of acetic acid. Its main use in pharmaceutics is with enteric formulations. It can be used together with other coating agents, e.g. ethyl cellulose. Cellulose acetate phthalate is commonly plasticized with diethyl phthalate, a hydrophobic compound, or triethyl citrate, a hydrophilic compound; other compatible plasticizers are various phthalates, triacetin, dibutyl tartrate, glycerol, propylene glycol, tripropionin, triacetin citrate, acetylated monoglycerides, etc.
A nail salon or nail bar is a specialty beauty salon establishment that primarily offers nail care services such as manicures, pedicures, and nail enhancements. Often, nail salons also offer skin care services. Manicures are also offered by general beauty salons, spas, and hotels. People who work at nail salons are usually called nail technicians, manicurists, or nailists.
Artificial nails, also known as fake nails, false nails, acrylic nails, press ons, nail extensions or nail enhancements, are extensions placed over fingernails as fashion accessories. Many artificial nail designs attempt to mimic the appearance of real fingernails as closely as possible, while others may deliberately stray in favor of an artistic look.
Nail art is a creative way to paint, decorate, enhance, and embellish nails. It is a type of artwork that can be done on fingernails and toenails, usually after manicures or pedicures.
Women's Voices for the Earth (WVE) is a feminist, women-led, North American environmental organization that specializes in research and advocacy regarding toxic chemicals used in products that disproportionately impact women's health, including cosmetics, menstrual care products, professional salon and cleaning products. WVE is a non-profit organization whose mission is to amplify women's voices to eliminate toxics that harm communities and health. With its inclusive vision of environmental work WVE has become a hub for visionary feminist environmentalism that recognizes the systemic connections between health, class, race, and the environment. Addressing the inter-connectivity of these various channels of exposure to toxic chemicals has been key to WVE's approach which is multi-scalar: targeting consumer behaviors, corporate practices, and government policies.
A migrant nail salon worker is a nail technician, manicurist, esthetician, or masseuse working in a Migrant, often Asian–owned nail salon in America. These workers are mostly women, including immigrants from Vietnam, South Korea, China, and Latin America. The majority of women who work in these nail salons are paid low wages, exposed to dangerous chemicals because of weak regulations, and develop complicated relationships with their clients, largely due to language differences and contradicting views on what constitutes quality customer service. Most Korean-owned nail salons are located in New York, and in reaction to a 2015 New York Times exposé documenting corruption within the state's nail salon industry, Gov. Andrew Cuomo created the New York State Nail Industry Enforcement Task Force, and signed into law stricter salon regulations and required the posting of wage bonds.
With inviting names such as peaches and cream or Caramel Smoothie, you are led away from the potential dangers of these polishes, with some ingredients that are known cancer-causing chemicals and those toxic to the nervous system. The top three chemicals of concern are toluene, dibutyl phthalate (dbp) and formaldehyde – the so-called 'toxic trio'.