Hair spray (also hair lacquer or spritz) is a common cosmetic hairstyling product that is sprayed onto hair to protect against humidity and wind and have it stay in a desired shape. Hair sprays typically consist of several components for the hair as well as a propellant. [1]
Hair sprays consist of the following components: concentrate, plasticizers, luster agents, and fragrances, as well as propellants.
Hair spray are a blend of polymers that provide structural support to hair. These frequently include copolymers of polyvinylpyrrolidone (PVP) and polyvinyl acetate (PVAc). Vinyl acetate-crotonic acid copolymers give harder films. In this way hairsprays can be formulated as flexible, medium, and maximum hold. [2] The copolymer mixture is usually adjusted to achieve the desired physical properties (adhesive strength, foaming, etc.), using plasticizers such as aminomethyl propanol, surfactants such as benzalkonium chloride, and other agents like dimethicone.
Since the phase-out of CFCs in the 1980s, hydrocarbons are popular propellants. These include propane, butane, isobutane, and related volatile hydrocarbons, as well as other mixtures. Such hydrocarbons are poor solvents for the active ingredients such as the polymers. For this reason dimethyl ether is often added as well. It functions both as a propellant and a solvent. [1] In addition to hydrocarbon propellants, fluorinated gases have been widely used as propellants to replace CFCs, with the most common gas being 1,1-difluoroethane. It is often listed as hydrofluorocarbon-152a. [3]
Plasticizers used in hair spray include esters of citric acid and adipic acid. Silicones and polyglycols are also used.
The concentrate comprises only a small volume of a can of hairspray. Most of a canister is filled solvents such as isopropanol (rubbing alcohol) and ethanol. [1]
Early hair sprays were developed in Europe in the 1920s. In the US, hair sprays were developed around the time of the aerosol can in the 1940s, and the first patents describing copolymers for hair styling were published in the 1940s. [4] [5]
In the US, the first to package it was Chase products (an aerosol manufacturer) in 1948, as the beauty industry saw that the aerosol cans used in World War II for insecticides could be used as a dispenser for hairspray. [6] It thrived and became increasingly popular and mass-produced, as updos and other such hairstyles were created. By 1964, it became the highest selling beauty product on the market.
In 1968 at the feminist Miss America protest, protestors symbolically threw a number of feminine products into a "Freedom Trash Can." These included hairspray, [7] which was among items the protestors called "instruments of female torture" [8] and accoutrements of what they perceived to be enforced femininity.
Sales of hairspray declined in the 1970s as hairstyles became predominantly worn straight and loose. By the 1980s, hairspray’s popularity came back as big hairstyles resurged with the glam metal scene.
Prior to 1979, the most popular propellants in hairsprays were CFCs. Owing to environmental concerns, they were replaced.
Hair spray can be used for things other than hair. For example in the beauty world one might spray some hairspray on the leg and on the inside of the dress so that the dress won't ride up and stay in place.
Petrochemicals are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewable sources such as maize, palm fruit or sugar cane.
Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging (plastic bags, plastic films, geomembranes and containers including bottles, etc.). As of 2017, over 100 million tonnes of polyethylene resins are being produced annually, accounting for 34% of the total plastics market.
Polyvinyl acetate (PVA, PVAc, poly(ethenyl ethanoate)), commonly known as wood glue, PVA glue, white glue, carpenter's glue, school glue, or Elmer's Glue in the US, is a widely available adhesive used for porous materials like wood, paper, and cloth. An aliphatic rubbery synthetic polymer with the formula (C4H6O2)n, it belongs to the polyvinyl ester family, with the general formula −[RCOOCHCH2]−. It is a type of thermoplastic.
Acrylonitrile butadiene styrene (ABS) (chemical formula (C8H8)x·(C4H6)y·(C3H3N)z ) is a common thermoplastic polymer. Its glass transition temperature is approximately 105 °C (221 °F). ABS is amorphous and therefore has no true melting point.
A propellant is a mass that is expelled or expanded in such a way as to create a thrust or another motive force in accordance with Newton's third law of motion, and "propel" a vehicle, projectile, or fluid payload. In vehicles, the engine that expels the propellant is called a reaction engine. Although technically a propellant is the reaction mass used to create thrust, the term "propellant" is often used to describe a substance which contains both the reaction mass and the fuel that holds the energy used to accelerate the reaction mass. For example, the term "propellant" is often used in chemical rocket design to describe a combined fuel/propellant, although the propellants should not be confused with the fuel that is used by an engine to produce the energy that expels the propellant. Even though the byproducts of substances used as fuel are also often used as a reaction mass to create the thrust, such as with a chemical rocket engine, propellant and fuel are two distinct concepts.
Polyacrylonitrile (PAN) is a synthetic, semicrystalline organic polymer resin, with the linear formula (CH2CHCN)n. Almost all PAN resins are copolymers with acrylonitrile as the main monomer. PAN is used to produce large variety of products including ultra filtration membranes, hollow fibers for reverse osmosis, fibers for textiles, and oxidized PAN fibers. PAN fibers are the chemical precursor of very high-quality carbon fiber. PAN is first thermally oxidized in air at 230 °C to form an oxidized PAN fiber and then carbonized above 1000 °C in inert atmosphere to make carbon fibers found in a variety of both high-tech and common daily applications such as civil and military aircraft primary and secondary structures, missiles, solid propellant rocket motors, pressure vessels, fishing rods, tennis rackets and bicycle frames. It is a component repeat unit in several important copolymers, such as styrene-acrylonitrile (SAN) and acrylonitrile butadiene styrene (ABS) plastic.
Aerosol spray is a type of dispensing system which creates an aerosol mist of liquid particles. It comprises a can or bottle that contains a payload, and a propellant under pressure. When the container's valve is opened, the payload is forced out of a small opening and emerges as an aerosol or mist.
Hair gel is a hairstyling product that is used to harden hair into a particular hairstyle.
Air fresheners are products designed to reduce unwanted odors in indoor spaces, or to introduce pleasant fragrances, or both. They typically emit fragrance to mask odors, but may use other methods of action such as absorbing, bonding to, or chemically altering compounds in the air that produce smells, killing organisms that produce smells, or disrupting the sense of smell to reduce perception of unpleasant smells.
Polyoxymethylene (POM), also known as acetal, polyacetal, and polyformaldehyde, is an engineering thermoplastic used in precision parts requiring high stiffness, low friction, and excellent dimensional stability. As with many other synthetic polymers, it is produced by different chemical firms with slightly different formulas and sold variously by such names as Delrin, Kocetal, Ultraform, Celcon, Ramtal, Duracon, Kepital, Polypenco, Tenac and Hostaform.
Shaving cream or shave cream is a category of cream cosmetics used for shaving preparation. The purpose of shaving cream is to soften the hair by providing lubrication.
Ethylene-vinyl acetate (EVA), also known as poly(ethylene-vinyl acetate) (PEVA), is a copolymer of ethylene and vinyl acetate. The weight percent of vinyl acetate usually varies from 10 to 50%, with the remainder being ethylene. There are three different types of EVA copolymer, which differ in the vinyl acetate (VA) content and the way the materials are used.
Aerosol paint is paint that comes in a sealed, pressurized container and is released in an aerosol spray when a valve button is depressed. The propellant is what the container of pressurized gas is called. When the pressure holding the gas is released through the valve, the aerosol paint releases as a fine spray. Aerosol painting is one form of spray painting; it leaves a smooth, even coat, unlike many traditional rolled and brushed paints. Aerosol primer can be applied directly to bare metal and many plastics.
Hot-melt adhesive (HMA), also known as hot glue, is a form of thermoplastic adhesive that is commonly sold as solid cylindrical sticks of various diameters designed to be applied using a hot glue gun. The gun uses a continuous-duty heating element to melt the plastic glue, which the user pushes through the gun either with a mechanical trigger mechanism on the gun, or with direct finger pressure. The glue squeezed out of the heated nozzle is initially hot enough to burn and even blister skin. The glue is sticky when hot, and solidifies in a few seconds to one minute. Hot-melt adhesives can also be applied by dipping or spraying, and are popular with hobbyists and crafters both for affixing and as an inexpensive alternative to resin casting.
Silly String is a toy of flexible, sometimes brightly colored, plastic string propelled as a stream of liquid from an aerosol can. The solvent in the string quickly evaporates in mid-air, creating a continuous strand. Silly String is often used during weddings, birthday parties, carnivals and other festive occasions, and has also been used by the US military to detect tripwires.
Solution polymerization is a method of industrial polymerization. In this procedure, a monomer is dissolved in a non-reactive solvent that contains a catalyst or initiator.
Aqua Net is an American brand of aerosol hair spray created by Rayette of St. Paul, Minnesota. The company brought the product to retail stores in 1961. By 1964, hairspray had become the top-selling beauty product in America. The brand is known for its distinctive large purple spray cans, and the spray itself is known for its strong hold and distinctive smell.
Hairstyle products are used to change the texture and/or shape of hair.
Dry shampoo otherwise known as hybrid shampoo is a type of shampoo which reduces hair greasiness without the need for water. It is in powder form and is typically administered from an aerosol can. Dry shampoo is often based on corn starch or rice starch. In addition to cleansing hair, it can also be used as a tool for hair-styling as it can create volume, help tease hair, keep bobby pins in place, and be used in place of mousse in wet hair. Dry shampoo proponents attest that daily wash-and-rinse with detergent shampoo can strip away natural oils from hair. However, others attest that spraying dry shampoo every day will lead to a build-up of product that can dull hair color and irritate the scalp, arguing that the scalp needs regular cleansing and exfoliating to get rid of bacteria, remove dead skin cells, and stay healthy.
In the Western world, the 1950s were a decade known for experimentation with new styles and culture. Following World War II and the austerity years of the post-war period, the 1950s were a time of comparative prosperity, which influenced fashion and the concept of glamour. Hairstylists invented new hairstyles for wealthy patrons. Influential hairstylists of the period include Sydney Guilaroff, Alexandre of Paris and Raymond Bessone, who took French hair fashion to Hollywood, New York and London, popularising the pickle cut, the pixie cut and bouffant hairstyles.
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