Copper(II) cyanurate

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Copper(II) Cyanurate
Copper(II) Cyanurate.png
Names
IUPAC name
Copper 6-hydroxy-1,3,5-triazine-2,4-bis(olate)
Other names
Copper 1,3,5-triazine-2,4,6-triol
Identifiers
3D model (JSmol)
PubChem CID
  • InChI=1S/C3H3N3O3.Cu/c7-1-4-2(8)6-3(9)5-1;/h(H3,4,5,6,7,8,9);/q;+2/p-2
    Key: IXMUUTDLXYTMPF-UHFFFAOYSA-L
  • [Cu+2].[O-]c1nc(O)nc([O-])n1
Properties
C3HCuN3O3
Molar mass 190.60434
Appearancepurple powder
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Copper(II) cyanurate (C3 H Cu N3 O3) is an organic compound. It has very few uses, and is more often encountered accidentally, rather than actually synthesised.

Contents

It is often found when the copper concentration in an outdoor swimming pool is too high. It also occurs with heat pumps due to acid in the insulation, and it reacts with cyanuric acid (which is added as a chlorine stabilizer) to produce copper cyanurate. This phenomenon is called 'Purple Cyanurate', as it discolours the surfaces and the water of the pool to a purple shade. [1]

Synthesis

Copper cyanurate can be created by reacting cyanuric acid with copper oxide.[ citation needed ]

CuO + 2C3H3N3O3 → C3HCuN3O3 + H2O.

Joanneumite is a rare natural mineral found in bat guano with formula Cu(C3N3O3H2)2(NH3)2 which is an ammine.[ citation needed ]

By heating copper compounds, such as the nitrate or carbonate with molten urea up to 190°C, they are largely converted to the lavender coloured joanneumite compound. [2] This is dissolved and then recrystallised from a hot strong ammonia solution. If instead a weak (2%) cold ammonia solution is used, the dark purple compound CuC3N3O3H•2NH3 is formed instead. [2]

A green coloured copper cyanurate containing no extra water or ammonia ligands also exists: Cu3(C3N3O3)2. [2]

Applications

Copper cyanurate has no known practical uses. The only place it commonly occurs is as an adverse effect of high levels of copper in swimming pools, and is more commonly seen as a nuisance.[ citation needed ]

Related Research Articles

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<span class="mw-page-title-main">Ammonium</span> Polyatomic ion (NH₄, charge +1)

The ammonium cation is a positively charged polyatomic ion with the chemical formula NH+4 or [NH4]+. It is formed by the protonation of ammonia. Ammonium is also a general name for positively charged (protonated) substituted amines and quaternary ammonium cations, where one or more hydrogen atoms are replaced by organic or other groups.

<span class="mw-page-title-main">Copper(I) oxide</span> Chemical compound – an oxide of copper with formula Cu2O

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<span class="mw-page-title-main">Nitrogen trichloride</span> Chemical compound

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<span class="mw-page-title-main">Cyanuric acid</span> Chemical compound belonging to the class of triazine

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x
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<span class="mw-page-title-main">Copper(II) hydroxide</span> Hydroxide of copper

Copper(II) hydroxide is the hydroxide of copper with the chemical formula of Cu(OH)2. It is a pale greenish blue or bluish green solid. Some forms of copper(II) hydroxide are sold as "stabilized" copper(II) hydroxide, although they likely consist of a mixture of copper(II) carbonate and hydroxide. Cupric hydroxide is a strong base, although its low solubility in water makes this hard to observe directly.

<span class="mw-page-title-main">Biuret</span> Chemical compound

Biuret is a chemical compound with the chemical formula HN(CONH2)2. It is a white solid that is soluble in hot water. A variety of organic derivatives are known. The term "biuret" also describes a family of organic compounds with the chemical formula R1R2N−C(=O)−N(R3)−C(=O)−NR4R5, where R1, R2, R3, R4 and R5 are hydrogen, organyl or other groups. Also known as carbamylurea, it results from the condensation of two equivalents of urea. It is a common undesirable impurity in urea-based fertilizers, as biuret is toxic to plants.

<span class="mw-page-title-main">Isocyanic acid</span> Chemical compound (H–N=C=O)

Isocyanic acid is a chemical compound with the structural formula HNCO, which is often written as H−N=C=O. It is a colourless, volatile and poisonous substance, with a boiling point of 23.5 °C. It is the predominant tautomer and an isomer of cyanic acid (aka. cyanol).

<span class="mw-page-title-main">Murexide</span> Chemical compound

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<span class="mw-page-title-main">Sodium dichloroisocyanurate</span> Chemical compound

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<span class="mw-page-title-main">Ammineite</span>

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References

  1. "Purple Staining, Purple Cyanurate, Copper Cyanurate, PoolMoldSolutions.com". PoolMoldSolutions.com.
  2. 1 2 3 Taylor, R. M. (May 1972). "Metal cyanurate compounds formed directly from metal salts and urea". Zeitschrift für anorganische und allgemeine Chemie. 390 (1): 85–96. doi:10.1002/zaac.19723900112.