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Cosmic ray spallation, also known as the x-process, is a set of naturally occurring nuclear reactions causing nucleosynthesis; it refers to the formation of chemical elements from the impact of cosmic rays on an object. Cosmic rays are highly energetic charged particles from beyond Earth, ranging from protons, alpha particles, and nuclei of many heavier elements. About 1% of cosmic rays also consist of free electrons.[ citation needed ]
Cosmic rays cause spallation when a ray particle (e.g. a proton) impacts with matter, including other cosmic rays. The result of the collision is the expulsion of particles (protons, neutrons, and alpha particles) from the object hit. This process goes on not only in deep space, but in Earth's upper atmosphere and crustal surface (typically the upper ten meters) due to the ongoing impact of cosmic rays.
Cosmic ray spallation is thought to be responsible for the abundance in the universe of some light elements [1] —lithium, beryllium, and boron—as well as the isotope helium-3. This process (cosmogenic nucleosynthesis) was discovered somewhat by accident during the 1970s: models of Big Bang nucleosynthesis suggested that the amount of deuterium was too large to be consistent with the expansion rate of the universe and there was therefore great interest in processes that could generate deuterium after the Big Bang nucleosynthesis. Cosmic ray spallation was investigated as a possible process to generate deuterium. As it turned out, spallation could not generate much deuterium, but the new studies of spallation showed that this process could generate lithium, beryllium and boron; indeed, isotopes of these elements are over-represented in cosmic ray nuclei, as compared with solar atmospheres (whereas hydrogen and helium are present in about primordial ratios in cosmic rays).
An example of cosmic ray spallation is a neutron hitting a nitrogen-14 nucleus in the Earth's atmosphere, yielding a proton, an alpha particle, and a beryllium-10 nucleus, which eventually decays to boron-10. Alternatively, a proton can hit oxygen-16, yielding two protons, a neutron, and again an alpha particle and a beryllium-10 nucleus. Boron can also be created directly. The beryllium and boron are brought down to the ground by rain. [2] See Cosmogenic nuclide for a list of nuclides produced by cosmic ray spallation.
The x-process in cosmic rays is the primary means of nucleosynthesis for the five stable isotopes of lithium, beryllium, and boron. [3] As the proton–proton chain reaction cannot proceed beyond 4He due to the unbound nature of 5He and 5Li, [4] and the triple-alpha process skips over all species between 4He and 12C, these elements are not produced in the main reactions of stellar nucleosynthesis. In addition, nuclei of these elements (such as 7Li) are relatively weakly bound, resulting in their rapid destruction in stars and no significant accumulation, although new theory suggests that 7Li is generated primarily in novae eruptions. [5] It was thus postulated that another nucleosynthesis process occurring outside stars was necessary to explain their existence in the universe. This process is now known to occur in cosmic rays, where lower temperature and particle density favor reactions leading to the synthesis of lithium, beryllium, and boron. [3]
In addition to the above light elements, tritium and isotopes of aluminium, carbon (carbon-14), phosphorus (phosphorus-32), chlorine, iodine and neon are formed within Solar System materials through cosmic ray spallation, and are termed cosmogenic nuclides. Since they remain trapped in the atmosphere or rock in which they formed, some can be very useful in the dating of materials by cosmogenic radionuclide dating, particularly in the geological field. In formation of a cosmogenic nuclide, a cosmic ray interacts with the nucleus of an in situ Solar System atom, causing cosmic ray spallation. These isotopes are produced within Earth materials such as rocks or soil, in Earth's atmosphere, and in extraterrestrial items such as meteorites. By measuring cosmogenic isotopes, scientists are able to gain insight into a range of geological and astronomical processes. There are both radioactive and stable cosmogenic isotopes. Some of the well-known naturally-occurring radioisotopes are tritium, carbon-14, and phosphorus-32.
The timing of their formation determines whether nuclides formed by cosmic ray spallation are termed primordial or are termed cosmogenic (a nuclide cannot belong to both classes). The stable nuclides of lithium, beryllium, and boron found on Earth are thought to have been formed by the same process as the cosmogenic nuclides but at an earlier time in cosmic ray spallation predominantly before the Solar System's formation, and thus they are by definition primordial nuclides and not cosmogenic. In contrast, the radioactive nuclide beryllium-7 falls into the same light element range but has a half-life too short for it to have been formed before the formation of the Solar System, so that it cannot be a primordial nuclide. Since the cosmic ray spallation route is the most likely source of beryllium-7 in the environment, that isotope is thus cosmogenic.
Atoms are the basic particles of the chemical elements. An atom consists of a nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper. Atoms with the same number of protons but a different number of neutrons are called isotopes of the same element.
The neutron is a subatomic particle, symbol
n
or
n0
, that has no electric charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave similarly within the nucleus, they are both referred to as nucleons. Nucleons have a mass of approximately one atomic mass unit, or dalton. Their properties and interactions are described by nuclear physics. Protons and neutrons are not elementary particles; each is composed of three quarks.
Stable nuclides are isotopes of a chemical element whose nucleons are in a configuration that does not permit them the surplus energy required to produce a radioactive emission. The nuclei of such isotopes are not radioactive and unlike radionuclides do not spontaneously undergo radioactive decay. When these nuclides are referred to in relation to specific elements they are usually called that element's stable isotopes.
In physical cosmology, Big Bang nucleosynthesis is the production of nuclei other than those of the lightest isotope of hydrogen during the early phases of the universe. This type of nucleosynthesis is thought by most cosmologists to have occurred from 10 seconds to 20 minutes after the Big Bang. It is thought to be responsible for the formation of most of the universe's helium, along with small fractions of the hydrogen isotope deuterium, the helium isotope helium-3 (3He), and a very small fraction of the lithium isotope lithium-7 (7Li). In addition to these stable nuclei, two unstable or radioactive isotopes were produced: the heavy hydrogen isotope tritium and the beryllium isotope beryllium-7 (7Be). These unstable isotopes later decayed into 3He and 7Li, respectively, as above.
Nucleosynthesis is the process that creates new atomic nuclei from pre-existing nucleons and nuclei. According to current theories, the first nuclei were formed a few minutes after the Big Bang, through nuclear reactions in a process called Big Bang nucleosynthesis. After about 20 minutes, the universe had expanded and cooled to a point at which these high-energy collisions among nucleons ended, so only the fastest and simplest reactions occurred, leaving our universe containing hydrogen and helium. The rest is traces of other elements such as lithium and the hydrogen isotope deuterium. Nucleosynthesis in stars and their explosions later produced the variety of elements and isotopes that we have today, in a process called cosmic chemical evolution. The amounts of total mass in elements heavier than hydrogen and helium remains small, so that the universe still has approximately the same composition.
Nuclides are a class of atoms characterized by their number of protons, Z, their number of neutrons, N, and their nuclear energy state.
A neutron source is any device that emits neutrons, irrespective of the mechanism used to produce the neutrons. Neutron sources are used in physics, engineering, medicine, nuclear weapons, petroleum exploration, biology, chemistry, and nuclear power. Neutron source variables include the energy of the neutrons emitted by the source, the rate of neutrons emitted by the source, the size of the source, the cost of owning and maintaining the source, and government regulations related to the source.
Spallation is a process in which fragments of material (spall) are ejected from a body due to impact or stress. In the context of impact mechanics it describes ejection of material from a target during impact by a projectile. In planetary physics, spallation describes meteoritic impacts on a planetary surface and the effects of stellar winds and cosmic rays on planetary atmospheres and surfaces. In the context of mining or geology, spallation can refer to pieces of rock breaking off a rock face due to the internal stresses in the rock; it commonly occurs on mine shaft walls. In the context of metal oxidation, spallation refers to the breaking off of the oxide layer from a metal. For example, the flaking off of rust from iron. In the context of anthropology, spallation is a process used to make stone tools such as arrowheads by knapping. In nuclear physics, spallation is the process in which a heavy nucleus emits numerous nucleons as a result of being hit by a high-energy particle, thus greatly reducing its atomic weight. In industrial processes and bioprocessing the loss of tubing material due to the repeated flexing of the tubing within a peristaltic pump is termed spallation.
Beryllium-10 (10Be) is a radioactive isotope of beryllium. It is formed in the Earth's atmosphere mainly by cosmic ray spallation of nitrogen and oxygen. Beryllium-10 has a half-life of 1.39 × 106 years, and decays by beta decay to stable boron-10 with a maximum energy of 556.2 keV. It decays through the reaction 10Be→10B + e−. Light elements in the atmosphere react with high energy galactic cosmic ray particles. The spallation of the reaction products is the source of 10Be (t, u particles like n or p):
The Oddo–Harkins rule holds that an element with an even atomic number is more abundant than the elements with immediately adjacent atomic numbers. For example, carbon, with atomic number 6, is more abundant than boron (5) and nitrogen (7). Generally, the relative abundance of an even atomic numbered element is roughly two orders of magnitude greater than the relative abundances of the immediately adjacent odd atomic numbered elements to either side. This pattern was first reported by Giuseppe Oddo in 1914 and William Draper Harkins in 1917. The Oddo–Harkins rule is true for all elements beginning with carbon produced by stellar nucleosynthesis but not true for the lightest elements below carbon produced by big bang nucleosynthesis and cosmic ray spallation.
Naturally occurring lithium (3Li) is composed of two stable isotopes, lithium-6 (6Li) and lithium-7 (7Li), with the latter being far more abundant on Earth. Both of the natural isotopes have an unexpectedly low nuclear binding energy per nucleon when compared with the adjacent lighter and heavier elements, helium and beryllium. The longest-lived radioisotope of lithium is 8Li, which has a half-life of just 838.7(3) milliseconds. 9Li has a half-life of 178.2(4) ms, and 11Li has a half-life of 8.75(6) ms. All of the remaining isotopes of lithium have half-lives that are shorter than 10 nanoseconds. The shortest-lived known isotope of lithium is 4Li, which decays by proton emission with a half-life of about 91(9) yoctoseconds, although the half-life of 3Li is yet to be determined, and is likely to be much shorter, like 2He which undergoes proton emission within 10−9 s.
Beryllium (4Be) has 11 known isotopes and 3 known isomers, but only one of these isotopes is stable and a primordial nuclide. As such, beryllium is considered a monoisotopic element. It is also a mononuclidic element, because its other isotopes have such short half-lives that none are primordial and their abundance is very low. Beryllium is unique as being the only monoisotopic element with both an even number of protons and an odd number of neutrons. There are 25 other monoisotopic elements but all have odd atomic numbers, and even numbers of neutrons.
Cosmogenic nuclides are rare nuclides (isotopes) created when a high-energy cosmic ray interacts with the nucleus of an in situ Solar System atom, causing nucleons to be expelled from the atom. These nuclides are produced within Earth materials such as rocks or soil, in Earth's atmosphere, and in extraterrestrial items such as meteoroids. By measuring cosmogenic nuclides, scientists are able to gain insight into a range of geological and astronomical processes. There are both radioactive and stable cosmogenic nuclides. Some of these radionuclides are tritium, carbon-14 and phosphorus-32.
Nuclear astrophysics studies the origin of the chemical elements and isotopes, and the role of nuclear energy generation, in cosmic sources such as stars, supernovae, novae, and violent binary-star interactions. It is an interdisciplinary part of both nuclear physics and astrophysics, involving close collaboration among researchers in various subfields of each of these fields. This includes, notably, nuclear reactions and their rates as they occur in cosmic environments, and modeling of astrophysical objects where these nuclear reactions may occur, but also considerations of cosmic evolution of isotopic and elemental composition (often called chemical evolution). Constraints from observations involve multiple messengers, all across the electromagnetic spectrum (nuclear gamma-rays, X-rays, optical, and radio/sub-mm astronomy), as well as isotopic measurements of solar-system materials such as meteorites and their stardust inclusions, cosmic rays, material deposits on Earth and Moon). Nuclear physics experiments address stability (i.e., lifetimes and masses) for atomic nuclei well beyond the regime of stable nuclides into the realm of radioactive/unstable nuclei, almost to the limits of bound nuclei (the drip lines), and under high density (up to neutron star matter) and high temperature (plasma temperatures up to 109 K). Theories and simulations are essential parts herein, as cosmic nuclear reaction environments cannot be realized, but at best partially approximated by experiments.
A nucleogenic isotope, or nuclide, is one that is produced by a natural terrestrial nuclear reaction, other than a reaction beginning with cosmic rays. The nuclear reaction that produces nucleogenic nuclides is usually interaction with an alpha particle or the capture of fission or thermal neutrons. Some nucleogenic isotopes are stable and others are radioactive.
An extinct radionuclide is a radionuclide that was formed by nucleosynthesis before the formation of the Solar System, about 4.6 billion years ago, but has since decayed to virtually zero abundance and is no longer detectable as a primordial nuclide. Extinct radionuclides were generated by various processes in the early Solar system, and became part of the composition of meteorites and protoplanets. All widely documented extinct radionuclides have half-lives shorter than 100 million years.
Isotopes are distinct nuclear species of the same chemical element. They have the same atomic number and position in the periodic table, but different nucleon numbers due to different numbers of neutrons in their nuclei. While all isotopes of a given element have similar chemical properties, they have different atomic masses and physical properties.
Surface exposure dating is a collection of geochronological techniques for estimating the length of time that a rock has been exposed at or near Earth's surface. Surface exposure dating is used to date glacial advances and retreats, erosion history, lava flows, meteorite impacts, rock slides, fault scarps, cave development, and other geological events. It is most useful for rocks which have been exposed for between 103 and 106 years.
Nuclear transmutation is the conversion of one chemical element or an isotope into another chemical element. Nuclear transmutation occurs in any process where the number of protons or neutrons in the nucleus of an atom is changed.