Diamond battery

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Diamond battery is the name of a nuclear battery concept proposed by the University of Bristol Cabot Institute during its annual lecture [1] held on 25 November 2016 at the Wills Memorial Building. This battery is proposed to run on the radioactivity of waste graphite blocks (previously used as neutron moderator material in graphite-moderated reactors) and would generate small amounts of electricity for thousands of years.

Contents

The battery is a betavoltaic cell using carbon-14 (14C) in the form of diamond-like carbon (DLC) as the beta radiation source, and additional normal-carbon DLC to make the necessary semiconductor junction and encapsulate the carbon-14. [2]

Prototypes

Early prototypes use nickel-63 (63Ni) as their source with diamond non-electrolytes/semiconductors for energy conversion, which are seen as a stepping stone to a 14C diamond battery prototype.

University of Bristol prototype

In 2016, researchers from the University of Bristol claimed to have constructed one of those 63Ni prototypes. [3] [4]

From their Frequently Asked Questions (FAQ document [5] ), the estimated power of a small C-14 cell is 15 J/day for thousands of years. (For reference, a AA battery of the same size has about 10 kJ total, which is equivalent to 15 J/day for just 2 years.) They note it is not possible to directly replace an AA battery with this technology, because an AA battery can produce bursts of much higher power as well. Instead, the diamond battery is aimed at applications where a low discharge rate over a long period of time is required, such as space exploration, medical devices, seabed communications, microelectronics, etc.

Moscow Institute of Physics and Technology prototype

In 2018, researchers from the Moscow Institute of Physics and Technology (MIPT), the Technological Institute for Superhard and Novel Carbon Materials (TISNCM), and the National University of Science and Technology (MISIS) announced a prototype using 2-micron thick layers of 63Ni foil sandwiched between 200 10-micron diamond converters. It produced a power output of about 1 μW at a power density of 10 μW/cm3. At those values, its energy density would be approximately 3.3 Wh/g over its 100-year half-life, about 10 times that of conventional electrochemical batteries. [6] This research was published in April 2018 in the Diamond and Related Materials journal. [7]

University of Bristol 14C Battery

In December 2024, the University of Bristol announced that they had successfully created a battery using 14C. The battery functions in a way similar to a photocell, but capturing electrons instead of light within the diamond. [8]

Carbon-14

Researchers are trying to improve the efficiency and are focusing on use of radioactive 14C, which is a minor contributor to the radioactivity of nuclear waste. [3]

14C undergoes beta decay, in which it emits a low-energy beta particle to become Nitrogen-14, which is stable (not radioactive). [9]

14
6
C
14
7
N
+ 0
−1
β

These beta particles, having an average energy of 50 keV, undergo inelastic collisions with other carbon atoms, thus creating electron-hole pairs which then contribute to an electric current. This can be restated in terms of band theory by saying that due to the high energy of the beta particles, electrons in the carbon valence band jump to its conduction band, leaving behind holes in the valence band where electrons were earlier present. [10] [4]

Proposed manufacturing

In graphite-moderated reactors, fissile uranium rods are placed inside graphite blocks. These blocks act as a neutron moderator whose purpose is to slow down fast-moving neutrons so that nuclear chain reactions can occur with thermal neutrons. [11] During their use, some of the non-radioactive carbon-12 and carbon-13 isotopes in graphite get converted into radioactive 14C by capturing neutrons. [12] When the graphite blocks are removed during station decommissioning, their induced radioactivity qualifies them as low-level waste requiring safe disposal.

Researchers at the University of Bristol demonstrated that a large amount of the radioactive 14C was concentrated on the inner walls of the graphite blocks. Due to this, they propose that much of it can be effectively removed from the blocks. This can be done by heating them to the sublimation point of 3,915 K (3,642 °C; 6,587 °F) which will release the carbon in gaseous form. After this, blocks will be less radioactive and possibly easier to dispose of with most of the radioactive 14C having been extracted. [13]

Those researchers propose that this 14C gas could be collected and used to produce man-made diamonds by a process known as chemical vapor deposition using low pressure and elevated temperature, noting that this diamond would be a thin sheet and not of the stereotypical diamond cut. The resulting diamond made of radioactive 14C would still produce beta radiation which researchers claim would allow it to be used as a betavoltaic source. Researchers also claim this diamond would be sandwiched between non-radioactive man-made diamonds made from 12C which would block radiation from the source and would also be used for energy conversion as a diamond semiconductor instead of conventional silicon semiconductors. [13]

Proposed applications

Due to its very low power density, conversion efficiency and high cost, a 14C betavoltaic device is very similar to other existing betavoltaic devices which are suited to niche applications needing very little power (microwatts) for several years in situations where conventional batteries cannot be replaced or recharged using conventional energy harvesting techniques. [14] [15] [16] Due to its longer half-life, 14C betavoltaics may have an advantage in service life when compared to other betavoltaics using tritium or nickel. However, this will likely come at the cost of further reduced power density.

Commercialization

In September 2020, Morgan Boardman, an Industrial Fellow and Strategic Advisory Consultant with the Aspire Diamond Group at the South West Nuclear Hub of the University of Bristol, was appointed CEO of a new company called Arkenlight, which was created explicitly to commercialize their diamond battery technology and possibly other nuclear radiation devices under research or development at Bristol University. [17] In September 2024, Arkenlight announced that they had created a 14C diamond. [18]

Related Research Articles

Background radiation is a measure of the level of ionizing radiation present in the environment at a particular location which is not due to deliberate introduction of radiation sources.

A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferred to one of its electrons to release it as a conversion electron; or used to create and emit a new particle (alpha particle or beta particle) from the nucleus. During those processes, the radionuclide is said to undergo radioactive decay. These emissions are considered ionizing radiation because they are energetic enough to liberate an electron from another atom. The radioactive decay can produce a stable nuclide or will sometimes produce a new unstable radionuclide which may undergo further decay. Radioactive decay is a random process at the level of single atoms: it is impossible to predict when one particular atom will decay. However, for a collection of atoms of a single nuclide the decay rate, and thus the half-life (t1/2) for that collection, can be calculated from their measured decay constants. The range of the half-lives of radioactive atoms has no known limits and spans a time range of over 55 orders of magnitude.

<span class="mw-page-title-main">Beta particle</span> Ionizing radiation

A beta particle, also called beta ray or beta radiation, is a high-energy, high-speed electron or positron emitted by the radioactive decay of an atomic nucleus, known as beta decay. There are two forms of beta decay, β decay and β+ decay, which produce electrons and positrons, respectively.

<span class="mw-page-title-main">Nuclear technology</span> Technology that involves the reactions of atomic nuclei

Nuclear technology is technology that involves the nuclear reactions of atomic nuclei. Among the notable nuclear technologies are nuclear reactors, nuclear medicine and nuclear weapons. It is also used, among other things, in smoke detectors and gun sights.

<span class="mw-page-title-main">Pebble-bed reactor</span> Type of very-high-temperature reactor

The pebble-bed reactor (PBR) is a design for a graphite-moderated, gas-cooled nuclear reactor. It is a type of very-high-temperature reactor (VHTR), one of the six classes of nuclear reactors in the Generation IV initiative.

<span class="mw-page-title-main">Carbon-14</span> Radiosotope of carbon

Carbon-14, C-14, 14C or radiocarbon, is a radioactive isotope of carbon with an atomic nucleus containing 6 protons and 8 neutrons. Its presence in organic matter is the basis of the radiocarbon dating method pioneered by Willard Libby and colleagues (1949) to date archaeological, geological and hydrogeological samples. Carbon-14 was discovered on February 27, 1940, by Martin Kamen and Sam Ruben at the University of California Radiation Laboratory in Berkeley, California. Its existence had been suggested by Franz Kurie in 1934.

<span class="mw-page-title-main">Radioactive decay</span> Emissions from unstable atomic nuclei

Radioactive decay is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is considered radioactive. Three of the most common types of decay are alpha, beta, and gamma decay. The weak force is the mechanism that is responsible for beta decay, while the other two are governed by the electromagnetic and nuclear forces.

<span class="mw-page-title-main">Ionizing radiation</span> Harmful high-frequency radiation

Ionizing radiation, including nuclear radiation, consists of subatomic particles or electromagnetic waves that have sufficient energy to ionize atoms or molecules by detaching electrons from them. Some particles can travel up to 99% of the speed of light, and the electromagnetic waves are on the high-energy portion of the electromagnetic spectrum.

<span class="mw-page-title-main">Scintillation counter</span> Instrument for measuring ionizing radiation

A scintillation counter is an instrument for detecting and measuring ionizing radiation by using the excitation effect of incident radiation on a scintillating material, and detecting the resultant light pulses.

<span class="mw-page-title-main">Neutron radiation</span> Ionizing radiation that presents as free neutrons

Neutron radiation is a form of ionizing radiation that presents as free neutrons. Typical phenomena are nuclear fission or nuclear fusion causing the release of free neutrons, which then react with nuclei of other atoms to form new nuclides—which, in turn, may trigger further neutron radiation. Free neutrons are unstable, decaying into a proton, an electron, plus an electron antineutrino. Free neutrons have a mean lifetime of 887 seconds.

A radioactive tracer, radiotracer, or radioactive label is a synthetic derivative of a natural compound in which one or more atoms have been replaced by a radionuclide. By virtue of its radioactive decay, it can be used to explore the mechanism of chemical reactions by tracing the path that the radioisotope follows from reactants to products. Radiolabeling or radiotracing is thus the radioactive form of isotopic labeling. In biological contexts, experiments that use radioisotope tracers are sometimes called radioisotope feeding experiments.

A semiconductor detector in ionizing radiation detection physics is a device that uses a semiconductor to measure the effect of incident charged particles or photons.

An atomic battery, nuclear battery, radioisotope battery or radioisotope generator uses energy from the decay of a radioactive isotope to generate electricity. Like a nuclear reactor, it generates electricity from nuclear energy, but it differs by not using a chain reaction. Although commonly called batteries, atomic batteries are technically not electrochemical and cannot be charged or recharged. Although they are very costly, they have extremely long lives and high energy density, so they are typically used as power sources for equipment that must operate unattended for long periods, such as spacecraft, pacemakers, underwater systems, and automated scientific stations in remote parts of the world.

A betavoltaic device is a type of nuclear battery that generates electric current from beta particles (electrons) emitted from a radioactive source, using semiconductor junctions. A common source used is the hydrogen isotope tritium. Unlike most nuclear power sources which use nuclear radiation to generate heat which then is used to generate electricity, betavoltaic devices use a non-thermal conversion process, converting the electron-hole pairs produced by the ionization trail of beta particles traversing a semiconductor.

<span class="mw-page-title-main">Radiochemistry</span> Chemistry of radioactive materials

Radiochemistry is the chemistry of radioactive materials, where radioactive isotopes of elements are used to study the properties and chemical reactions of non-radioactive isotopes. Much of radiochemistry deals with the use of radioactivity to study ordinary chemical reactions. This is very different from radiation chemistry where the radiation levels are kept too low to influence the chemistry.

<span class="mw-page-title-main">Nuclear fuel</span> Material fuelling nuclear reactors

Nuclear fuel refers to any substance, typically fissile material, which is used by nuclear power stations or other nuclear devices to generate energy.

Various radionuclides emit beta particles, high-speed electrons or positrons, through radioactive decay of their atomic nucleus. These can be used in a range of different industrial, scientific, and medical applications. This article lists some common beta-emitting radionuclides of technological importance, and their properties.

An optoelectric nuclear battery is a type of nuclear battery in which nuclear energy is converted into light, which is then used to generate electrical energy. This is accomplished by letting the ionizing radiation emitted by the radioactive isotopes hit a luminescent material, which in turn emits photons that generate electricity upon striking a photovoltaic cell.

Induced radioactivity, also called artificial radioactivity or man-made radioactivity, is the process of using radiation to make a previously stable material radioactive. The husband-and-wife team of Irène Joliot-Curie and Frédéric Joliot-Curie discovered induced radioactivity in 1934, and they shared the 1935 Nobel Prize in Chemistry for this discovery.

<i>Nuclear Power and the Environment</i>

Nuclear Power and the Environment, sometimes simply called the Flowers Report, was released in September 1976 and is the sixth report of the UK Royal Commission on Environmental Pollution, chaired by Sir Brian Flowers. The report was dedicated to "the Queen's most excellent Majesty." "He was appointed "to advise on matters, both national and international, concerning the pollution of the environment; on the adequacy of research in this field; and the future possibilities of danger to the environment." One of the recommendations of the report was that:

"There should be no commitment to a large programme of nuclear fission power until it has been demonstrated beyond reasonable doubt that a method exists to ensure the safe containment of longlived, highly radioactive waste for the indefinite future."

References

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  4. 1 2 "Diamond nuclear battery could generate 100 μW for 5,000 years". Electronics Weekly. 2 December 2016.
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  6. "Prototype nuclear battery packs 10 times more power". mipt.ru.
  7. Bormashov, V.S.; Troschiev, S.Yu.; Tarelkin, S.A.; Volkov, A.P.; Teteruk, D.V.; Golovanov, A.V.; Kuznetsov, M.S.; Kornilov, N.V.; Terentiev, S.A.; Blank, V.D. (April 2018). "High power density nuclear battery prototype based on diamond Schottky diodes". Diamond and Related Materials. 84: 41–47. Bibcode:2018DRM....84...41B. doi: 10.1016/j.diamond.2018.03.006 .
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  10. "Flash Physics: Nuclear diamond battery, M G K Menon dies, four new elements named". Physics World. 30 November 2016.
  11. "'Diamond-age' of power generation as nuclear batteries developed". Youtube. University of Bristol. 28 November 2016.
  12. "Radioactive Diamond Batteries: Making Good Use Of Nuclear Waste". Forbes. 9 December 2016.
  13. 1 2 "'Diamond-age' of power generation as nuclear batteries developed". University of Bristol. 25 November 2016.
  14. "Bristol university Press release issued: 25 November 2016". Archived from the original on 20 November 2022. Retrieved 3 December 2016.
  15. "Bristol University interdisciplinary Aspire project, 2017". Archived from the original on 2021-05-29. Retrieved 2020-10-02.
  16. "Tritium Batteries as a Source of Nuclear Power". City Labs. Retrieved 25 May 2023.
  17. "New Atlas (formerly Gizmag) interview with Dr Boardman". 30 September 2020. Archived from the original on 2022-11-20. Retrieved 2020-10-02.
  18. Arkenlight (2024-09-29). "Arkenlight – Brilliant Power for Very Useful Things". Arkenlight Latest Updates. Retrieved 2024-11-07.