Quartz is the most abundant single mineral in the Earth's crust (although behind the feldspar group when taken collectively), [1] and as such is present in a very large proportion of rocks both as primary crystals and as detrital grains in sedimentary and metamorphic rocks. Dynamic recrystallization is a process of crystal regrowth under conditions of stress and elevated temperature, commonly applied in the fields of metallurgy and materials science. Dynamic quartz recrystallization happens in a relatively predictable way with relation to temperature, and given its abundance quartz recrystallization can be used to easily determine relative temperature profiles, for example in orogenic belts or near intrusions.
Previous research has outlined several dislocation creep regimes present in experimental conditions. [2] Two main mechanisms for altering grain boundaries have been defined. The first is the process by which quartz softens as temperature increases, providing a means for internal stress reduction by migration of dislocations in the crystal lattice, known as dislocation creep. These dislocations concentrate into walls, forming new grain boundaries. The other process involves differences in stored strain energy between neighboring grains, resulting in migration of existing grain boundaries. The extent to which these occur is a function of strain rate and temperature, those being, respectively, the factors controlling introduction of new dislocations and the ability of dislocations to migrate and form subgrain boundaries which themselves migrate. [3]
Observable microstructures in quartz can be classified into three semi-distinct groupings that form a continuum of Dynamic recrystallization textures. These regimes will be discussed in terms of temperature changes, assuming a constant level of shear.
The lowest temperature texture (~250-400°C), bulging recrystallization (BLG) is characterized by bulges and small recrystallized grains along grain boundaries and, to some extent, microcracks. The at-large proportion and structure of the original quartz crystals is preserved to the greatest extent, compared with the other profiles. Formed by a combination of the two mechanisms mentioned, limited crystal plasticity (due to low temperature) prevents any further separation of subgrains. It follows, then, that an increase in temperature results in an increase in recrystallized grain size and volume proportion (0-25%) [4] as internal stress becomes more resolved.
Following an increase in temperature, the dominant texture changes to one marked by the presence of distinct subgrains. Recognizable in thin section by a more polygonized texture, the increased softening of the quartz allows for more thorough reduction of internal stresses. Recrystallized grains show relatively straight grain boundaries and little to no intragranular deformation features, such as undulose extinction or deformation lamellae. [4] Volume proportion of recrystallized grains in this regime roughly ranges from 30-90%, forming subgrains not only in interstitial space, but also within larger crystals or ribbon grains. Subgrains and recrystallized grains are roughly equal in size and shape.
The highest temperature of the three textures, grain boundary migration becomes the dominant mechanism at ~500-550°C. Exhibiting much larger recrystallized grain sizes than the other two regimes, in addition to lobate and highly interfingering boundaries, at these temperatures quartz is completely recrystallized. That is, no evidence for original grains can be found. At these high temperatures, grain boundaries are free to sweep across entire grains, resulting in much less localized boundary formation/change. In this case as well, intragranular deformation features have been erased, but may be present from later-stage overprinting.
Aside from the obvious increase in temperature, there are other trends which arise in this progression of recrystallization.
As mentioned above, with increased temperature there is a marked increase in the proportion of the rock having undergone recrystallization. From 0-30% in bulging recrystallization, up to 90% in subgrain rotation recrystallization and 100% in grain boundary migration, this property may be observed in quartzite, at least well enough to get relative temperature relationships in the field.
Progressing from around 15 μm (bulging recrystallization) to about 85 μm (subgrain rotation recrystallization) to up to a few millimeters (grain boundary migration), this exponential increase is not only noticeable, but is part of the basis on which the three recrystallization regimes were demarcated.
Observation of recrystallization in a rock sample can reveal a general temperature, but nothing very precise. This is because the process of recrystallization is strongly affected by the presence of water and the amount of strain present. As such, this information can be applied to determine relative temperatures of different rock much more reliably than it can determine absolute temperatures. Furthermore, this is an analysis that can be done, if only preliminarily, in the field by observing rocks in hand sample.
Metamorphism is the transformation of existing rock to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.
In physics and materials science, plasticity is the ability of a solid material to undergo permanent deformation, a non-reversible change of shape in response to applied forces. For example, a solid piece of metal being bent or pounded into a new shape displays plasticity as permanent changes occur within the material itself. In engineering, the transition from elastic behavior to plastic behavior is known as yielding.
A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains.
In materials science, creep is the tendency of a solid material to undergo slow deformation while subject to persistent mechanical stresses. It can occur as a result of long-term exposure to high levels of stress that are still below the yield strength of the material. Creep is more severe in materials that are subjected to heat for long periods and generally increases as they near their melting point.
The Portevin–Le Chatelier (PLC) effect describes a serrated stress–strain curve or jerky flow, which some materials exhibit as they undergo plastic deformation, specifically inhomogeneous deformation. This effect has been long associated with dynamic strain aging or the competition between diffusing solutes pinning dislocations and dislocations breaking free of this stoppage.
Dynamic recrystallization (DRX) is a type of recrystallization process, found within the fields of metallurgy and geology. In dynamic recrystallization, as opposed to static recrystallization, the nucleation and growth of new grains occurs during deformation rather than afterwards as part of a separate heat treatment. The reduction of grain size increases the risk of grain boundary sliding at elevated temperatures, while also decreasing dislocation mobility within the material. The new grains are less strained, causing a decrease in the hardening of a material. Dynamic recrystallization allows for new grain sizes and orientation, which can prevent crack propagation. Rather than strain causing the material to fracture, strain can initiate the growth of a new grain, consuming atoms from neighboring pre-existing grains. After dynamic recrystallization, the ductility of the material increases.
Mylonite is a fine-grained, compact metamorphic rock produced by dynamic recrystallization of the constituent minerals resulting in a reduction of the grain size of the rock. Mylonites can have many different mineralogical compositions; it is a classification based on the textural appearance of the rock.
In materials science, recrystallization is a process by which deformed grains are replaced by a new set of defect-free grains that nucleate and grow until the original grains have been entirely consumed. Recrystallization is usually accompanied by a reduction in the strength and hardness of a material and a simultaneous increase in the ductility. Thus, the process may be introduced as a deliberate step in metals processing or may be an undesirable byproduct of another processing step. The most important industrial uses are softening of metals previously hardened or rendered brittle by cold work, and control of the grain structure in the final product. Recrystallization temperature is typically 0.3–0.4 times the melting point for pure metals and 0.5 times for alloys.
In metallurgy, recovery is a process by which a metal or alloy's deformed grains can reduce their stored energy by the removal or rearrangement of defects in their crystal structure. These defects, primarily dislocations, are introduced by plastic deformation of the material and act to increase the yield strength of a material. Since recovery reduces the dislocation density, the process is normally accompanied by a reduction in a material's strength and a simultaneous increase in the ductility. As a result, recovery may be considered beneficial or detrimental depending on the circumstances.
Diffusion creep refers to the deformation of crystalline solids by the diffusion of vacancies through their crystal lattice. Diffusion creep results in plastic deformation rather than brittle failure of the material.
In metallurgy, materials science and structural geology, subgrain rotation recrystallization is recognized as an important mechanism for dynamic recrystallisation. It involves the rotation of initially low-angle sub-grain boundaries until the mismatch between the crystal lattices across the boundary is sufficient for them to be regarded as grain boundaries. This mechanism has been recognized in many minerals and in metals.
Cataclasite is a cohesive granular fault rock. Comminution, also known as cataclasis, is an important process in forming cataclasites. They fall into the category of cataclastic rocks which are formed through faulting or fracturing in the upper crust. Cataclasites are distinguished from fault gouge, which is incohesive, and fault breccia, which contains coarser fragments.
Cleavage, in structural geology and petrology, describes a type of planar rock feature that develops as a result of deformation and metamorphism. The degree of deformation and metamorphism along with rock type determines the kind of cleavage feature that develops. Generally, these structures are formed in fine grained rocks composed of minerals affected by pressure solution.
In geology, a deformation mechanism is a process occurring at a microscopic scale that is responsible for changes in a material's internal structure, shape and volume. The process involves planar discontinuity and/or displacement of atoms from their original position within a crystal lattice structure. These small changes are preserved in various microstructures of materials such as rocks, metals and plastics, and can be studied in depth using optical or digital microscopy.
In materials science, grain-boundary strengthening is a method of strengthening materials by changing their average crystallite (grain) size. It is based on the observation that grain boundaries are insurmountable borders for dislocations and that the number of dislocations within a grain has an effect on how stress builds up in the adjacent grain, which will eventually activate dislocation sources and thus enabling deformation in the neighbouring grain as well. By changing grain size, one can influence the number of dislocations piled up at the grain boundary and yield strength. For example, heat treatment after plastic deformation and changing the rate of solidification are ways to alter grain size.
Dislocation creep is a deformation mechanism in crystalline materials. Dislocation creep involves the movement of dislocations through the crystal lattice of the material, in contrast to diffusion creep, in which diffusion is the dominant creep mechanism. It causes plastic deformation of the individual crystals, and thus the material itself.
Grain boundary sliding (GBS) is a material deformation mechanism where grains slide against each other. This occurs in polycrystalline material under external stress at high homologous temperature and low strain rate and is intertwined with creep. Homologous temperature describes the operating temperature relative to the melting temperature of the material. There are mainly two types of grain boundary sliding: Rachinger sliding, and Lifshitz sliding. Grain boundary sliding usually occurs as a combination of both types of sliding. Boundary shape often determines the rate and extent of grain boundary sliding.
Paleostress inversion refers to the determination of paleostress history from evidence found in rocks, based on the principle that past tectonic stress should have left traces in the rocks. Such relationships have been discovered from field studies for years: qualitative and quantitative analyses of deformation structures are useful for understanding the distribution and transformation of paleostress fields controlled by sequential tectonic events. Deformation ranges from microscopic to regional scale, and from brittle to ductile behaviour, depending on the rheology of the rock, orientation and magnitude of the stress, etc. Therefore, detailed observations in outcrops, as well as in thin sections, are important in reconstructing the paleostress trajectories.
Salt deformation is the change of shape of natural salt bodies in response to forces and mechanisms that controls salt flow. Such deformation can generate large salt structures such as underground salt layers, salt diapirs or salt sheets at the surface. Strictly speaking, salt structures are formed by rock salt that is composed of pure halite (NaCl) crystal. However, most halite in nature appears in impure form, therefore rock salt usually refers to all rocks that composed mainly of halite, sometimes also as a mixture with other evaporites such as gypsum and anhydrite. Earth's salt deformation generally involves such mixed materials.
Julia Ann “Jan” Tullis was an American structural geologist and emerita Professor at Brown University. Tullis is known for her work in structural geology, especially for her experimental work in deformation mechanisms, microstructures, and rheology of crustal rocks.