Electroplasticity

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Electroplasticity, describes the enhanced plastic behavior of a solid material under the application of an electric field. [1] This electric field could be internal, resulting in current flow in conducting materials, or external. The effect of electric field on mechanical properties ranges from simply enhancing existing plasticity, such as reducing the flow stress in already ductile metals, to promoting plasticity in otherwise brittle ceramics. The exact mechanisms that control electroplasticity vary based on the material and the exact conditions (e.g., temperature, strain rate, grain size, etc.). Enhancing the plasticity of materials is of great practical interest as plastic deformation provides an efficient way of transforming raw materials into final products. The use of electroplasticity to improve processing of materials is known as electrically assisted manufacturing.

Contents

History

Electroplasticity was first discovered by Eugene S. Machlin, who reported in 1959 that applying an electric field made NaCl weaker and more ductile. [2] Since then, the effect of electric fields on plasticity has been studied in many materials systems including metal, ceramics, and semiconductors. Various mechanisms have been posited to explain electroplastic effects and their dependence on materials properties and external conditions. For most materials the electroplastic effect arises from a combination of multiple mechanisms. This should not be all that surprising given that the electric fields directly affect electrons which dictate the bonding in materials and therefore all higher level phenomena such as dislocation motion, flow stress, vacancy diffusion, etc.

Electroplasticity in Metals

The application of DC electric fields is known to reduce the flow stress of metals and metal alloys while increasing the fracture strain. [3] Several mechanisms have been put forth to explain this effect including Joule heating, electron wind force, dissolution of metallic bonds, and unpinning of dislocations due the induction of magnetic fields. [3] [4] None of these mechanisms on their own can sufficiently explain the full extent of electroplasticity in metals. The application of electric fields has been shown to enhance the effect of superplasticity which occurs in polycrystalline metals at high homologous temperatures (T>0.5Tm). This is likely due to the electric field reducing cavitation, which can lead to premature fracture, and grain growth, which can prevent superplastic flow due to grain boundary sliding, in addition to reducing the activation energy for grain boundary sliding. [4] The strength of the electroplastic effect scales with the magnitude of the applied electric field past some threshold value. While the application of an electric field typically augments the plasticity of metals there are alloy systems that show a reduction in plasticity. Conrad and Li found that the activation energy for grain boundary sliding in Zn-5 wt.% Al increased by nearly 20% under the application of a 2 DC electric field, resulting in more difficult deformation. [5]

Electroplasticity in Ceramics

The application of electric fields to ceramics can give rise to plasticity in materials that traditionally exhibit no plastic deformation. High homologous temperatures are, however, typically necessary to achieve significant plastic deformation in ceramic materials. Plastic deformation ceramic oxides was found by Conrad et al. to occur under relatively modest electric field strengths (0.02-0.32 ). [4] Strain-mediating defects such as vacancies and dislocations tend to be charged in ceramic materials due to the ionic or covalent nature of bonding. Thus, the movement of electrons can have a direct impact on the mobility of these defects in ceramics and subsequent plastic deformation. The primary effect of the electric field in the deformation of fine-grained ceramic oxides is to shift the diffusion pathway from bulk diffusion to grain boundary diffusion, resulting in greater diffusion and easier grain boundary sliding. [4] [6]

Related Research Articles

<span class="mw-page-title-main">Ductility</span> Degree to which a material under stress irreversibly deforms before failure

Ductility refers to the ability of a material to sustain significant plastic deformation before fracture. Plastic deformation is the permanent distortion of a material under applied stress, as opposed to elastic deformation, which is reversible upon removing the stress. Ductility is a critical mechanical performance indicator, particularly in applications that require materials to bend, stretch, or deform in other ways without breaking. The extent of ductility can be quantitatively assessed using the percent elongation at break, given by the equation:

<span class="mw-page-title-main">Sintering</span> Process of forming and bonding material by heat or pressure

Sintering or frittage is the process of compacting and forming a solid mass of material by pressure or heat without melting it to the point of liquefaction. Sintering happens as part of a manufacturing process used with metals, ceramics, plastics, and other materials. The atoms/molecules in the sintered material diffuse across the boundaries of the particles, fusing the particles together and creating a solid piece.

<span class="mw-page-title-main">Plasticity (physics)</span> Non-reversible deformation of a solid material in response to applied forces

In physics and materials science, plasticity is the ability of a solid material to undergo permanent deformation, a non-reversible change of shape in response to applied forces. For example, a solid piece of metal being bent or pounded into a new shape displays plasticity as permanent changes occur within the material itself. In engineering, the transition from elastic behavior to plastic behavior is known as yielding.

In materials science, superplasticity is a state in which solid crystalline material is deformed well beyond its usual breaking point, usually over about 400% during tensile deformation. Such a state is usually achieved at high homologous temperature. Examples of superplastic materials are some fine-grained metals and ceramics. Other non-crystalline materials (amorphous) such as silica glass and polymers also deform similarly, but are not called superplastic, because they are not crystalline; rather, their deformation is often described as Newtonian fluid. Superplastically deformed material gets thinner in a very uniform manner, rather than forming a "neck" that leads to fracture. Also, the formation of microvoids, which is another cause of early fracture, is inhibited. Superplasticity must not be confused with superelasticity.

<span class="mw-page-title-main">Crystallite</span> Small crystal which forms under certain conditions

A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains.

<span class="mw-page-title-main">Creep (deformation)</span> Tendency of a solid material to move slowly or deform permanently under mechanical stress

In materials science, creep is the tendency of a solid material to undergo slow deformation while subject to persistent mechanical stresses. It can occur as a result of long-term exposure to high levels of stress that are still below the yield strength of the material. Creep is more severe in materials that are subjected to heat for long periods and generally increases as they near their melting point.

<span class="mw-page-title-main">Brittleness</span> Liability of breakage from stress without significant plastic deformation

A material is brittle if, when subjected to stress, it fractures with little elastic deformation and without significant plastic deformation. Brittle materials absorb relatively little energy prior to fracture, even those of high strength. Breaking is often accompanied by a sharp snapping sound.

Hardening is a metallurgical metalworking process used to increase the hardness of a metal. The hardness of a metal is directly proportional to the uniaxial yield stress at the location of the imposed strain. A harder metal will have a higher resistance to plastic deformation than a less hard metal.

The Portevin–Le Chatelier (PLC) effect describes a serrated stress–strain curve or jerky flow, which some materials exhibit as they undergo plastic deformation, specifically inhomogeneous deformation. This effect has been long associated with dynamic strain aging or the competition between diffusing solutes pinning dislocations and dislocations breaking free of this stoppage.

<span class="mw-page-title-main">Bauschinger effect</span>

The Bauschinger effect refers to a property of materials where the material's stress/strain characteristics change as a result of the microscopic stress distribution of the material. For example, an increase in tensile yield strength occurs at the expense of compressive yield strength. The effect is named after German engineer Johann Bauschinger.

<span class="mw-page-title-main">Transgranular fracture</span>

Transgranular fracture is a type of fracture that occurs through the crystal grains of a material. In contrast to intergranular fractures, which occur when a fracture follows the grain boundaries, this type of fracture traverses the material's microstructure directly through individual grains. This type of fracture typically results from a combination of high stresses and material defects, such as voids or inclusions, that create a path for crack propagation through the grains. A broad range of ductile or brittle materials, including metals, ceramics, and polymers, can experience transgranular fracture. When examined under scanning electron microscopy, this type of fracture reveals cleavage steps, river patterns, feather markings, dimples, and tongues. The fracture may change directions somewhat when entering a new grain in order to follow the new lattice orientation of that grain but this is a less severe direction change then would be required to follow the grain boundary. This results in a fairly smooth looking fracture with fewer sharp edges than one that follows the grain boundaries. This can be visualized as a jigsaw puzzle cut from a single sheet of wood with the wood grain showing. A transgranular fracture follows the grains in the wood, not the jigsaw edges of the puzzle pieces. This is in contrast to an intergranular fracture which, in this analogy, would follow the jigsaw edges, not the wood grain.

Diffusion creep refers to the deformation of crystalline solids by the diffusion of vacancies through their crystal lattice. Diffusion creep results in plastic deformation rather than brittle failure of the material.

<span class="mw-page-title-main">Nanocrystalline material</span>

A nanocrystalline (NC) material is a polycrystalline material with a crystallite size of only a few nanometers. These materials fill the gap between amorphous materials without any long range order and conventional coarse-grained materials. Definitions vary, but nanocrystalline material is commonly defined as a crystallite (grain) size below 100 nm. Grain sizes from 100 to 500 nm are typically considered "ultrafine" grains.

In geology and materials science, a deformation mechanism is a process occurring at a microscopic scale that is responsible for deformation: changes in a material's internal structure, shape and volume. The process involves planar discontinuity and/or displacement of atoms from their original position within a crystal lattice structure. These small changes are preserved in various microstructures of materials such as rocks, metals and plastics, and can be studied in depth using optical or digital microscopy.

<span class="mw-page-title-main">Grain boundary strengthening</span> Method of strengthening materials by changing grain size

In materials science, grain-boundary strengthening is a method of strengthening materials by changing their average crystallite (grain) size. It is based on the observation that grain boundaries are insurmountable borders for dislocations and that the number of dislocations within a grain has an effect on how stress builds up in the adjacent grain, which will eventually activate dislocation sources and thus enabling deformation in the neighbouring grain as well. By changing grain size, one can influence the number of dislocations piled up at the grain boundary and yield strength. For example, heat treatment after plastic deformation and changing the rate of solidification are ways to alter grain size.

Severe plastic deformation (SPD) is a generic term describing a group of metalworking techniques involving very large strains typically involving a complex stress state or high shear, resulting in a high defect density and equiaxed "ultrafine" grain (UFG) size or nanocrystalline (NC) structure.

<span class="mw-page-title-main">Grain boundary sliding</span> Material deformation mechanism

Grain boundary sliding (GBS) is a material deformation mechanism where grains slide against each other. This occurs in polycrystalline material under external stress at high homologous temperature and low strain rate and is intertwined with creep. Homologous temperature describes the operating temperature relative to the melting temperature of the material. There are mainly two types of grain boundary sliding: Rachinger sliding, and Lifshitz sliding. Grain boundary sliding usually occurs as a combination of both types of sliding. Boundary shape often determines the rate and extent of grain boundary sliding.

In materials science, Nabarro–Herring creep is a mechanism of deformation of crystalline materials that occurs at low stresses and held at elevated temperatures in fine-grained materials. In Nabarro–Herring creep, atoms diffuse through the crystals, and the rate of creep varies inversely with the square of the grain size so fine-grained materials creep faster than coarser-grained ones. NH creep is solely controlled by diffusional mass transport.

Atul Harish Chokshi is an Indian materials scientist, metallurgical engineer and a professor at the Department of Materials Engineering of the Indian Institute of Science. He is known for his studies on high temperature deformation and failure of ceramic materials and is an elected fellow of all the three major Indian science academies viz. the National Academy of Sciences, India, Indian Academy of Sciences, and Indian National Science Academy as well as the Indian National Academy of Engineering. The Council of Scientific and Industrial Research, the apex agency of the Government of India for scientific research, awarded him the Shanti Swarup Bhatnagar Prize for Science and Technology, one of the highest Indian science awards for his contributions to Engineering Sciences in 2003.

<span class="mw-page-title-main">Terence G. Langdon</span> British scientist and academic

Terence G. Langdon is a scientist and an academic. He is a Professor of Materials Science at the University of Southampton, and a Professor of Engineering Emeritus at the University of Southern California.

References

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