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Other names Ethenol, polymer with ethene | |
Identifiers | |
ChemSpider |
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CompTox Dashboard (EPA) | |
Properties | |
(C2H4O-C2H4)x | |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Ethylene vinyl alcohol (EVOH) is a formal copolymer of ethylene and vinyl alcohol. Because the latter monomer mainly exists as its tautomer acetaldehyde, the copolymer is prepared by polymerization of ethylene and vinyl acetate to give the ethylene vinyl acetate (EVA) copolymer followed by hydrolysis. EVOH copolymer is defined by the mole % ethylene content: lower ethylene content grades have higher barrier properties; higher ethylene content grades have lower temperatures for extrusion.
The plastic resin is commonly used as an oxygen barrier in food packaging. It is better than other plastics at keeping air out and flavors in, is highly transparent, weather resistant, oil and solvent resistant, flexible, moldable, recyclable, and printable. Its drawback is that it is difficult to make and therefore more expensive than other food packaging. Instead of making an entire package out of EVOH, manufacturers keep costs down by coextruding or laminating it as a thin layer between cardboard, foil, or other plastics. [1] [2]
It is also used as a hydrocarbon barrier in plastic fuel tanks and pipes.
Because of the high capital cost to build an EVOH plant, and the complexity of making a food grade product, only a few companies produce EVOH:
Kuraray produces EVOH resin under the name "EVAL," with a 10,000 ton plant in Okayama, Japan; a 58,000 ton plant in the U.S. (near Houston, TX) under its subsidiary Kuraray America; and a 35,000 ton plant in Belgium under its subsidiary EVAL Europe. [3]
Nippon Gohsei produces EVOH under the trade name Soarnol. It has production sites in Mizushima, Japan; La Porte, Texas in the USA; and at Salt End, Hull, England. [4]
Chang Chun Petrochemical produces EVOH under the trade name EVASIN. It has a single site in Taipei, Taiwan.
Due to its strong barrier against gasses (especially oxygen), odors and flavours, [5] food packaging manufacturers use EVOH in their packaging structure to extend the shelf life of food products. [6]
A downside of EVOH is its relatively high moisture sensitivity, meaning that the barrier capabilities of EVOH decrease in environments with high humidity. [7] As such, EVOH is often applied within a multiplayer film. Here, one or more inside layers contain EVOH, but the outside layers consist of a different plastic that is less sensitive to moisture, such as polyethylene.
EVOH is used in a liquid embolic system in interventional radiology, e.g. in Onyx. [8] Dissolved in dimethyl sulfoxide (DMSO) and mixed with a radiopaque substance, ethylene vinyl alcohol copolymer is used to embolize blood vessels.
Petrochemicals are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewable sources such as maize, palm fruit or sugar cane.
Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging (plastic bags, plastic films, geomembranes and containers including bottles, cups, jars, etc.). As of 2017, over 100 million tonnes of polyethylene resins are being produced annually, accounting for 34% of the total plastics market.
A thermoplastic, or thermosoftening plastic, is any plastic polymer material that becomes pliable or moldable at a certain elevated temperature and solidifies upon cooling.
Polyvinyl acetate (PVA, PVAc, poly(ethenyl ethanoate)), commonly known as wood glue (a term that may also refer to other types of glues), PVA glue, white glue, carpenter's glue, school glue, or Elmer's Glue in the US, is a widely available adhesive used for porous materials like wood, paper, and cloth. An aliphatic rubbery synthetic polymer with the formula (C4H6O2)n, it belongs to the polyvinyl ester family, with the general formula −[RCOOCHCH2]−. It is a type of thermoplastic.
Polyethylene terephthalate (or poly(ethylene terephthalate), PET, PETE, or the obsolete PETP or PET-P), is the most common thermoplastic polymer resin of the polyester family and is used in fibres for clothing, containers for liquids and foods, and thermoforming for manufacturing, and in combination with glass fibre for engineering resins.
Although PET is used in several applications, as of 2022 only bottles are collected at a substantial scale. The main motivations have been either cost reduction or recycle content of retail goods. An increasing amount is recycled back into bottles, the rest goes into fibres, film, thermoformed packaging and strapping. After sorting, cleaning and grinding, 'bottle flake' is obtained, which is then processed by either:
Polyoxymethylene (POM), also known as acetal, polyacetal, and polyformaldehyde, is an engineering thermoplastic used in precision parts requiring high stiffness, low friction, and excellent dimensional stability. Short-chained POM is also better known as paraformaldehyde (PFA). As with many other synthetic polymers, polyoxymethylenes are produced by different chemical firms with slightly different formulas and sold as Delrin, Kocetal, Ultraform, Celcon, Ramtal, Duracon, Kepital, Polypenco, Tenac and Hostaform.
Polyvinyl alcohol (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH2CH(OH)]n. It is used in papermaking, textile warp sizing, as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) adhesive formulations, in a variety of coatings, and 3D printing. It is colourless (white) and odorless. It is commonly supplied as beads or as solutions in water. Without an externally added crosslinking agent, PVA solution can be gelled through repeated freezing-thawing, yielding highly strong, ultrapure, biocompatible hydrogels which have been used for a variety of applications such as vascular stents, cartilages, contact lenses, etc.
Kuraray Co., Ltd is a Japanese manufacturer of chemicals, fibers and other materials. Their main manufacturing facilities are located in Kurashiki, Okayama. The company's Tokyo administrative offices are located in Otemachi, Chiyoda in the Ote Center Building and its Osaka offices are located in the Umeda Hankyu Building). As of June 2007, Kuraray was the sole worldwide producer of Vectran liquid crystal polymer (LCP) fibre.
Ethylene-vinyl acetate (EVA), also known as poly(ethylene-vinyl acetate) (PEVA), is a copolymer of ethylene and vinyl acetate. The weight percent of vinyl acetate usually varies from 10 to 50%, with the remainder being ethylene. There are three different types of EVA copolymer, which differ in the vinyl acetate (VA) content and the way the materials are used.
An ionomer is a polymer composed of repeat units of both electrically neutral repeating units and ionized units covalently bonded to the polymer backbone as pendant group moieties. Usually no more than 15 mole percent are ionized. The ionized units are often carboxylic acid groups.
Hot-melt adhesive (HMA), also known as hot glue, is a form of thermoplastic adhesive that is commonly sold as solid cylindrical sticks of various diameters designed to be applied using a hot glue gun. The gun uses a continuous-duty heating element to melt the plastic glue, which the user pushes through the gun either with a mechanical trigger mechanism on the gun, or with direct finger pressure. The glue squeezed out of the heated nozzle is initially hot enough to burn and even blister skin. The glue is sticky when hot, and solidifies in a few seconds to one minute. Hot-melt adhesives can also be applied by dipping or spraying, and are popular with hobbyists and crafters both for affixing and as an inexpensive alternative to resin casting.
A blister pack is any of several types of pre-formed plastic packaging used for small consumer goods, foods, and for pharmaceuticals.
Polyethylene or polythene film biodegrades naturally, albeit over a long period of time. Methods are available to make it more degradable under certain conditions of sunlight, moisture, oxygen, and composting and enhancement of biodegradation by reducing the hydrophobic polymer and increasing hydrophilic properties.
Polyvinylidene chloride, or polyvinylidene dichloride (PVDC), is a homopolymer of vinylidene chloride.
Vacuum packing is a method of packaging that removes air from the package prior to sealing. This method involves placing items in a plastic film package, removing air from inside and sealing the package. Shrink film is sometimes used to have a tight fit to the contents. The intent of vacuum packing is usually to remove oxygen from the container to extend the shelf life of foods and, with flexible package forms, to reduce the volume of the contents and package.
Cyclic olefin copolymer (COC) is an amorphous polymer made by several polymer manufacturers. COC is a relatively new class of polymers as compared to commodities such as polypropylene and polyethylene. This newer material is used in a wide variety of applications including packaging films, lenses, vials, displays, and medical devices.
A plastic bottle is a bottle constructed from high-density or low density plastic. Plastic bottles are typically used to store liquids such as water, soft drinks, motor oil, cooking oil, medicine, shampoo or milk. They range in sizes, from very small bottles to large carboys. Consumer blow molded containers often have integral handles or are shaped to facilitate grasping.
In interventional radiology, Onyx is a trade name for a copolymer used for embolisation therapy, which involves the occlusion of blood vessels. It is a liquid embolic agent. Onyx is produced and sold by Medtronic.
Multi-layered packaging are multilayer or composite materials using innovative technologies aimed to give barrier properties, strength and storage stability to food items, new materials as well as hazardous materials.