Process type | chemical |
---|---|
Industrial sector(s) | chemical industry, oil industry |
Feedstock | oil shale |
Product(s) | shale oil |
Main facilities | United States Bureau of Mines' Oil Shale Experiment Station |
Developer(s) | United States Bureau of Mines |
The gas combustion retort process (also referred as gas-combustion retorting process) was an above-ground retorting technology for shale oil extraction. It was a predecessor of the Paraho and Petrosix processes, and modern directly heated oil shale retorting technologies in general. [1]
The gas combustion retort process was developed by the United States Bureau of Mines at the end of the 1940s. The first gas combustion retort, designed by Cameron Engineers, went into operation in 1949 and it was located in the United States Bureau of Mines' Oil Shale Experiment Station at Anvil Point in Rifle, Colorado. The Bureau of Mines tested this process in three retorts with capacity of 6, 10, and 25 ton of oil shale per day accordingly. [1] The consortium of Mobil, Humble Oil, Continental Oil, Pan American Oil, Phillips Petroleum Company, and Sinclair Oil evaluated and improved this technology between 1964 and 1968. [1]
The gas combustion retort process is classified as an internal combustion technology. For the oil shale pyrolysis it uses a vertical vessel retort. [2]
Crushed raw oil shale is fed into the top of the retort, and it moves downward by gravity. When moving downward, oil shale is heated by the rising recycled gases, which cause decomposition of the rock. Recycled gases enter the retort from the bottom. Gases are heated on the lower part of retort by descended spent shale. On their way up, gases move through the combustion zone, where air and dilution gases are injected causing combustion of gases and carbonaceous residue of spent shale (char). The heat from combustion brings the temperature in the retorting zone above of the burning zone to the necessary level for retorting. The incoming raw oil shale cool oil vapors and gases, which then leave the top of the retort as a mist. [1] [2] [3] [4]
The main advantage of this process was that it does not require cooling water, which made it suitable for using in the semi-arid regions. [1] [4]
Shale oil is an unconventional oil produced from oil shale rock fragments by pyrolysis, hydrogenation, or thermal dissolution. These processes convert the organic matter within the rock (kerogen) into synthetic oil and gas. The resulting oil can be used immediately as a fuel or upgraded to meet refinery feedstock specifications by adding hydrogen and removing impurities such as sulfur and nitrogen. The refined products can be used for the same purposes as those derived from crude oil.
Petrosix is the world's largest surface oil shale pyrolysis retort with an 11 metres (36 ft) diameter vertical shaft kiln, operational since 1992. It is located in São Mateus do Sul, Brazil, and it is owned and operated by the Brazil energy company Petrobras. Petrosix means also the Petrosix process, an externally generated hot gas technology of shale oil extraction. The technology is tailored to Irati oil shale formation, a Permian formation of the Paraná Basin.
Shale oil extraction is an industrial process for unconventional oil production. This process converts kerogen in oil shale into shale oil by pyrolysis, hydrogenation, or thermal dissolution. The resultant shale oil is used as fuel oil or upgraded to meet refinery feedstock specifications by adding hydrogen and removing sulfur and nitrogen impurities.
The history of the oil shale industry started in ancient times. The modern industrial use of oil shale for oil extraction dates to the mid-19th century and started growing just before World War I because of the mass production of automobiles and trucks and the supposed shortage of gasoline for transportation needs. Between the World Wars oil shale projects were begun in several countries.
The Kiviter process is an above ground retorting technology for shale oil extraction.
The TOSCO II process is an above ground retorting technology for shale oil extraction, which uses fine particles of oil shale that are heated in a rotating kiln. The particularity of this process is that it use hot ceramic balls for the heat transfer between the retort and a heater. The process was tested in a 40 tonnes per hour test facility near Parachute, Colorado.
The Galoter process is a shale oil extraction technology for a production of shale oil, a type of synthetic crude oil. In this process, the oil shale is decomposed into shale oil, oil shale gas, and spent residue. A decomposition is caused by mixing raw oil shale with a hot oil shale ash, generated by combustion of carbonaceous residue (semi-coke) in the spent residue. The process was developed in 1950s and it is used commercially for the shale oil production in Estonia. There are projects for further development of this technology and for expansion of its usage, e.g. in Jordan and USA.
The Alberta Taciuk process is an above-ground dry thermal retorting technology for extracting oil from oil sands, oil shale and other organics-bearing materials, including oil contaminated soils, sludges and wastes. The technology is named after its inventor William Taciuk and the Alberta Oil Sands Technology and Research Authority.
The Fushun process is an above-ground retorting technology for shale oil extraction. It is named after the main production site of Fushun, Liaoning province in northeastern China.
Chevron CRUSH is an experimental in situ shale oil extraction technology to convert kerogen in oil shale to shale oil. The name stands for Chevron's Technology for the Recovery and Upgrading of Oil from Shale. It is developed jointly by Chevron Corporation and the Los Alamos National Laboratory.
The Paraho process is an above ground retorting technology for shale oil extraction. The name "Paraho" is delivered from the words "para homem", which means in Portuguese "for mankind".
The Lurgi–Ruhrgas process is an above-ground coal liquefaction and shale oil extraction technology. It is classified as a hot recycled solids technology.
The Nevada–Texas–Utah retort process was an above-ground shale oil extraction technology to produce shale oil, a type of synthetic crude oil. It heated oil shale in a sealed vessel (retort) causing its decomposition into shale oil, oil shale gas and spent residue. The process was developed in the 1920s and used for shale oil production in the United States and in Australia. The process was simple to operate; however, it was ceased from the operation because of a small capacity and labor extensiveness.
The Superior multimineral process is an above ground shale oil extraction technology designed for production of shale oil, a type of synthetic crude oil. The process heats oil shale in a sealed horizontal segmented vessel (retort) causing its decomposition into shale oil, oil shale gas and spent residue. The particularities of this process is a recovery of saline minerals from the oil shale, and a doughnut-shape of the retort. The process is suitable for processing of mineral-rich oil shales, such as in the Piceance Basin. It has a relatively high reliability and high oil yield. The technology was developed by the American oil company Superior Oil.
The Union process was an above ground shale oil extraction technology for production of shale oil, a type of synthetic crude oil. The process used a vertical retort where heating causes decomposition of oil shale into shale oil, oil shale gas and spent residue. The particularity of this process is that oil shale in the retort moves from the bottom upward to the top, countercurrent to the descending hot gases, by a mechanism known as a rock pump. The process technology was invented by the American oil company Unocal Corporation in late 1940s and was developed through several decades. The largest oil shale retort ever built was the Union B type retort.
The Chevron STB process is an above-ground shale oil extraction technology. It is classified as a hot recycled solids technology.
LLNL HRS process is an above-ground shale oil extraction technology. It is classified as a hot recycled solids technology.
KENTORT II is an above-ground shale oil extraction process developed by the Center for Applied Energy Research of the University of Kentucky. It is a hot recycled solids fluidized bed retorting process developed since 1982 for processing the eastern United States Devonian oil shales. The concept of this process was initiated in 1986 in the test unit.
The Shell Spher process is an above ground fluidization bed retorting technology for shale oil extraction. It is classified as a hot recycled solids technology.
The LLNL RISE process was an experimental shale oil extraction technology developed by the Lawrence Livermore National Laboratory. The name comes from the abbreviation of the Lawrence Livermore National Laboratory and words 'rubble in situ extraction'.
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