George-ericksenite | |
---|---|
General | |
Category | Sulfate mineral |
Formula (repeating unit) | Na6CaMg(IO3)6(CrO4)2(H2O)12 |
IMA symbol | Gek [1] |
Strunz classification | 4.KD.10 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | C2/c |
Unit cell | a = 23.645 Å b = 10.918 Å c = 15.768 Å β = 114.42°; Z=4 |
Identification | |
Color | Pale yellow (crystals) to bright lemon yellow (aggregates) |
Crystal habit | Prismatic to acicular along [001] and somewhat flattened on {110} |
Twinning | None observed megascopically nor during single-crystal study |
Cleavage | None observed |
Fracture | Unknown |
Tenacity | Brittle |
Mohs scale hardness | 3-4 (estimated) |
Luster | Vitreous |
Streak | Pale yellow |
Diaphaneity | Transparent (crystals) to translucent (aggregates) |
Density | 3.035 g/cm3 |
Birefringence | δ = 0.057 |
Pleochroism | Slight; X 5 very pale yellow, Z 5 distinct yellow-green |
Solubility | Extreme in cold water |
References | [2] [3] |
George-ericksenite is a mineral with the chemical formula Na6CaMg(IO3)6(CrO4)2(H2O)12. It is vitreous, pale yellow to bright lemon yellow, brittle, and features a prismatic to acicular crystal habit along [001] and somewhat flattened crystal habit on {110}. It was first encountered in 1984 at the Pinch Mineralogical Museum. One specimen of dietzeite from Oficina Chacabuco, Chile had bright lemon-yellow micronodules on it. These crystals produced an X-ray powder diffraction pattern that did not match any XRD data listed for inorganic compounds. The X-ray diffraction pattern and powder mount were set aside until 1994. By then, the entire mineral collection from the Pinch Mineralogical Museum had been purchased by the Canadian Museum of Nature. The specimen was then retrieved and studied further. This study was successful and the new mineral george-ericksenite was discovered. The mineral was named for George E. Ericksen who was a research economic geologist with the U.S. Geological Survey for fifty years. The mineral and name have been approved by Commission on New Minerals and Mineral Names (IMA). The specimen, polished thin section, and the actual crystal used for the structure determination are kept in the Display Series of the National Mineral Collection of Canada at the Canadian Museum of Nature, Ottawa, Ontario.
George-ericksonite is commonly found as isolated bright lemon-yellow micronodules of crystals that are concentrated on the surface of one part of the mineral specimen. However, in some cases the micronodules occur as groupings instead of isolated occurrences. The average size of these micronodules is approximately 0.2 mm and each consists of numerous individual crystals in random orientation. [4]
This examination was carried out by attaching two acicular crystals to the surface of a disk with epoxy and then examining them with a CAMECA SX-50 electron microprobe. One of the crystals had the (100) surface facing up, and the other crystal had a growth face of the form (110) facing up. The microprobe was operating in wavelength-dispersive mode at 15 kV and ran various currents from 20 nA to 0.5 nA. The CAMECA SX-50 has three spectrometers and the samples were examined in the sequence (Na, Cl, I), then (Mg, S, Ca). When the crystal was exposed to the electron beam for the first 200 seconds, the counts per second on each element varied greatly which indicates that the crystals are extremely unstable in the electron beam. The counts per second for each element were also dependent on the surface of the crystal [(100) or (110)] analyzed. Over shorter counting times (<10 s) at 15 kV and 5 nA, there is a gain in I2O5 and a drop in Na2O relative to ideal values. However, a significant orientation effect exists for SO3 and CaO values for the (100) and (110) surfaces on either side of the ideal values. With increasing exposure to the electron beam, Na2O increases and all other oxides decrease. This behavior is also more rapid on the (100) surface than on the (110) crystal face. The (100) surface is overall more reactive to the electron beam than the (110) surface, but both surfaces seem to approach equilibrium with the beam and give similar oxides weight percentages after 200 seconds. [4]
Even at low currents and short counting times george-ericksenite is extremely unstable under the electron beam. After examination, the crystal faces are stained brown from the reaction with I2 and the decrease in analyzed I2O5 with increasing time. The crystallographic orientation of the material analyzed has a large impact on the analytical values at any given time. The overall quantitative behavior of george-ericksenite in the electron beam is consistent with the chemical composition derived (ideally I2O5 59.13, CrO3 9.92. SO3 1.51, MgO 2.38, CaO 3.31, Na2O 10.98, H2O 12.77 weight %). [4]
A 0.046 X 0.059 X 0.060 mm3 crystal was mounted on a Siemans P4 four-circle diffractometer. The crystal was aligned using 42 reflections automatically centered following measurement from a rotation photograph. The orientation matrix and unit-cell dimensions were determined from the setting angles of least-squares refinement. 3872 reflections were recorded out to 60° 2θ with a fixed scan speed of 1.33° 2θ/min. Corrections for absorption by Gaussian quadrature integration were applied. Corrections for Lorentz, polarization, and background effects were also applied as well as reduction of intensities to structure factors. [4]
The SHELXTL PC Plus system of programs were used for the calculations. The R and Rw indices are of the conventional form. The structure was solved by direct methods. The structure is centrosymmetric as indicated by the E statistics. Systematic absences also indicate the presence of a c glide for the C-centered cell. The result was placing george-ericksenite in the C2/c space group. The structure was refined by a combination of least-squares refinement and difference-Fourier synthesis to an R index of 3.5% and Rw equal to 3.5%. Site occupancies were determined by the basis of site-scattering refinement and crystal-chemical criteria. [4]
There is one chromium (Cr) site that is symmetrically distinct and is tetrahedrally coordinated by four oxygen (O) atoms. The average length of the bonds is 1.61 Å which indicates that the Cr cation is hexavalent. The average bond length at the Cr site is less than would be expected for complete occupancy by Cr6+. This difference can be accounted for by partial substitution of sulfur (S) atoms. [4]
There are three iodine (I) sites that are coordinated by three oxygen (O) atoms arranged in a triangle to one side of the cation. The distances of the bonds between the I and O atoms is 1.81 Å. This results in the IO3 group forming a triangular pyramid with the I site at the top of the pyramid. At each I sites there are also three additional ligands that causes the iodine atoms to have a distorted octahedral coordination. This also causes the I atom to occupy off centered positions within each octahedron. The long bonds between the atoms at the I sites contributes significant bond valence to the bonded anions. [4]
There are three sodium (Na) sites that are each unique. Each site has a different type of coordination. The Na1 site is encompassed by two O atoms and four H2O groups in a distorted octahedral arrangement with a Na1-Φ distance (where Φ=unspecified ligand) of 2.41 Å. The Na2 site is surrounded by five O atoms and 2 H2O groups in an augmented octahedral arrangement with a Na2-Φ distance of 2.54 Å. The Na3 site is surrounded by five O atoms and three H2O atoms in a triangular dodecahedral arrangement with a Na3-Φ distance of 2.64 Å. [4]
There is only one magnesium (Mg) site which is coordinated by six O atoms in an octahedral arrangement with a Mg-O distance of 2.09 Å. This bond length is in accord with this site being entirely occupied by Mg with not substitution. [4]
The one calcium (Ca) site is coordinated by six O atoms and two H2O groups in a square-antiprismatic arrangement with a Ca-Φ distance of 2.50 Å. This bond length is in accord with this site being entirely occupied by Ca with not substitution. [4]
George-ericksenite features a structural arrangement that is composed of slabs of polyhedra orthogonal to [100]. These slabs feature the same composition as the mineral itself and are a half of a unit thick in the [100] direction. These are connected to adjacent slabs solely by hydrogen bonding. The edges of each slab are bounded by near-planar layers of anions. The slabs themselves are composed of three planar layers of cations. There are also three planar layers of cations parallel to the edges of the slabs. This indicates that each slab consists of three layers of polyhedra. The c-glide symmetry relates the top and bottom of the slab which means the slab may be broken into two unique sheets of polyhedra.
There is a prominent zigzag pattern of chains of Na polyhedra extending in the c direction on the outer layer of the slab. The Na1 octahedron shares an edge with the Na2 augmented octahedron which shares a face with the Na3 triangular dodecahedron. This forms a linear trimer that extends in the [011] direction. This trimer is then links by edge-sharing between the Na3 and a1 polyhedra to another trimer extending in the [0-11] direction. This motif continues to form a [Na3Φ14] zigzag chain extending in the c direction. In each embayment of this chain the polyhedra are accented by two (IO3+3) groups. Identical chains run parallel to the c axis that are linked only by one weak I-O bond.
The inner layer of the slab is composed of one Mg octahedron that shares corners with two Cr tetrahedra. This forms a [MT2Φ12] cluster. The other two anions of the Mg octahedron link by corner-sharing to two (IO3+3) groups. These [Mg(CrO4)2(IO3+3)2O2] clusters link together two (CaΦ8) polyhedra. This forms chains parallel to the b axis. Weak I-O bonds link these chains to form the central layer of the slab.
The only other chromate-iodate mineral is dietzeite, Ca(IO3)2(CrO4)(H2O). Dietzeite and george-ericksenite have no structural relationship. Fuenzalidaite and carlosruizite are sulphate-iodate minerals found in the Chilean nitrate fields and contain small amounts of Cr substituting for S. They are also sheet structures, but the sheets are vastly different in terms of connectivity than in george-ericksenite.
A borate is any of a range of boron oxyanions, anions containing boron and oxygen, such as orthoborate BO3−3, metaborate BO−2, or tetraborate B4O2−7; or any salt of such anions, such as sodium metaborate, Na+[BO2]− and borax (Na+)2[B4O7]2−. The name also refers to esters of such anions, such as trimethyl borate B(OCH3)3 but they are alkoxides.
Sekaninaite ((Fe+2,Mg)2Al4Si5O18) is a silicate mineral, the iron-rich analogue of cordierite.
An oxyanion, or oxoanion, is an ion with the generic formula A
xOz−
y. Oxyanions are formed by a large majority of the chemical elements. The formulae of simple oxyanions are determined by the octet rule. The corresponding oxyacid of an oxyanion is the compound H
zA
xO
y. The structures of condensed oxyanions can be rationalized in terms of AOn polyhedral units with sharing of corners or edges between polyhedra. The oxyanions adenosine monophosphate (AMP), adenosine diphosphate (ADP) and adenosine triphosphate (ATP) are important in biology.
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.
Belite is an industrial mineral important in Portland cement manufacture. Its main constituent is dicalcium silicate, Ca2SiO4, sometimes formulated as 2 CaO · SiO2 (C2S in cement chemist notation).
Julgoldite is a member of the pumpellyite mineral series, a series of minerals characterized by the chemical bonding of silica tetrahedra with alkali and transition metal cations. Julgoldites, along with more common minerals like epidote and vesuvianite, belong to the subclass of sorosilicates, the rock-forming minerals that contain SiO4 tetrahedra that share a common oxygen to form Si2O7 ions with a charge of 6− (Deer et al., 1996). Julgoldite has been recognized for its importance in low grade metamorphism, forming under shear stress accompanied by relatively low temperatures (Coombs, 1953). Julgoldite was named in honor of Professor Julian Royce Goldsmith (1918–1999) of the University of Chicago.
Plumbogummite is a rare secondary lead phosphate mineral, belonging to the alunite supergroup of minerals, crandallite subgroup. Some other members of this subgroup are:
Dicopper chloride trihydroxide refers to the compound with chemical formula Cu2(OH)3Cl. It is often referred to as tribasic copper chloride (TBCC), copper trihydroxyl chloride or copper hydroxychloride. This greenish substance is encountered as the minerals atacamite, paratacamite, and botallackite. Similar materials are assigned to green solids formed upon corrosion of various copper objectss.
This list gives an overview of the classification of non-silicate minerals and includes mostly International Mineralogical Association (IMA) recognized minerals and its groupings. This list complements the List of minerals recognized by the International Mineralogical Association series of articles and List of minerals. Rocks, ores, mineral mixtures, not IMA approved minerals, not named minerals are mostly excluded. Mostly major groups only, or groupings used by New Dana Classification and Mindat.
In chemistry, a molybdate is a compound containing an oxyanion with molybdenum in its highest oxidation state of +6: O−−Mo(=O)2−O−. Molybdenum can form a very large range of such oxyanions, which can be discrete structures or polymeric extended structures, although the latter are only found in the solid state. The larger oxyanions are members of group of compounds termed polyoxometalates, and because they contain only one type of metal atom are often called isopolymetalates. The discrete molybdenum oxyanions range in size from the simplest MoO2−
4, found in potassium molybdate up to extremely large structures found in isopoly-molybdenum blues that contain for example 154 Mo atoms. The behaviour of molybdenum is different from the other elements in group 6. Chromium only forms the chromates, CrO2−
4, Cr
2O2−
7, Cr
3O2−
10 and Cr
4O2−
13 ions which are all based on tetrahedral chromium. Tungsten is similar to molybdenum and forms many tungstates containing 6 coordinate tungsten.
Pimelite was discredited as a mineral species by the International Mineralogical Association (IMA) in 2006, in an article which suggests that "pimelite" specimens are probably willemseite, or kerolite. This was a mass discreditation, and not based on any re-examination of the type material. Nevertheless, a considerable number of papers have been written, verifying that pimelite is a nickel-dominant smectite. It is always possible to redefine a mineral wrongly discredited.
Donnayite-(Y) is a rare-earth carbonate mineral containing the rare-earth metal yttrium. It was first discovered in 1978 at Mont Saint-Hilaire, Quebec. Donnayite was subsequently identified and named after Joseph D. H. Donnay and his wife, Gabrielle Donnay. Both were prominent mineralogists and crystallographers, and J. D. H. Donnay was awarded the Roebling Award by the Mineralogical Society of America in 1971 for his emphasis on the importance of optical mineralogy and crystal morphology. Donnayite tends to occur in small quantities in the pegmatite dykes and miarolitic cavities of mountainous regions. It crystallizes in this environment with increasing alkalinity values until the alkalinity suddenly drops during the last stage of crystallization. This results in increasing amounts of Na carbonates and REE minerals. First discovered at Mont St-Hilaire, donnayite has since been found in the Southern Ural Mountains of Russia and the Narssarssuk pegmatite of South Greenland. Donnayite crystals tend to be small and the color is commonly pale yellow to yellow with a white streak and a vitreous luster. Donnayite crystals usually display trigonal or hexagonal symmetry and have a hardness of 3. Twinning is extremely common in this mineral. Minerals closely related to donnayite include synchysite, calcite, sphalerite, microcline, and analcime. Donnayite is isomorphous with weloganite and mckelveyite.
Carlosruizite is a sulfate or selenate–iodate mineral with chemical formula: K6(Na,K)4Na6Mg10(SeO4)12(IO3)12·12H2O. It has a low density (specific gravity of 3.36), colorless to pale yellow, transparent mineral which crystallizes in the trigonal crystal system. It forms a series with fuenzalidaite.
Farneseite is a mineral from the cancrinite sodalite group with 14 layer stacking. It is a complex silicate mineral with formula (Na,Ca,K)56(Al6Si6O24)7(SO4)12·6H2O. It was named after a location in Farnese, Lazio, Italy. It is a member of the cancrinite-sodalite group, approved in 2004 as a new mineral species. The group is characterized by the number of stacking layers making up each member, with farneseite being one of newest minerals in the group with a 14 layer stacking structure. It is a clear transparent mineral and has a hexagonal crystal system with crystal class of 6/m and space group of P63/m. The specimens discovered in Farnese were in a pyroclastic rock from the Làtera Cauldera region.
The mineral hubeite, Ca
2Mn2+
Fe3+
[Si
4O
12(OH)]·(H
2O)
2, is a sorosilicate of the Si
4O
13 group. Structurally it also belongs to the Akatoreite group. It was found and named after the province of Hubei, China. It is common to iron ores in a mine of that region. It occurs mainly as aggregates of fan like crystals. It is dark to pale brown, has orange-brown streak and is vitreous. Hubeite has a hardness of 5.5 in the Mohs scale, one good cleavage and conchoidal fracture. It is triclinic with a space group of P1*. The structure of hubeite is very uncommon, and in fact there is only one other mineral that fits the Si
4O
13 group, which is ruizite.
Gottlobite, CaMg(VO4,AsO4)(OH), is a mineral found as isolated crystals or isometric grains of orange or orange-brown color. The size of the crystals are a half millimeter in diameter and are part of the orthorhombic crystal system. Gottlobite forms a solid solution with adelite, which is an end member composition of CaMg(VO4)(OH), as well as being classified in the adelite group. Gottlobite is also part of the vanadates and arsenates group. With these characteristics, it is similar to the minerals tangeite and austinite by X-ray diffraction methods.
Meyrowitzite, Ca(UO2)(CO3)2·5H2O, is a carbonate mineral verified in May of 2018 by the Commission of New Minerals, Nomenclature and Classification of the International Mineralogical Association. It is an extremely rare mineral, discovered in the Markey mine Utah, U.S.A. The mineral is a transparent yellow and has blades up to approximately 0.2 mm in length. It is soluble in water or aqueous solutions. Meyrowitzite is named in honor of Robert Meyrowitz (1916–2013), an American analytical chemist. After serving in WW II, he joined the United States Geological Survey (USGS). He was known for developing innovative new methods for analyzing small and difficult to study mineralogical samples along with his formulation of the high-index immersion liquids.
Zigrasite is a phosphate mineral with the chemical formula of MgZr(PO4)2(H2O)4. Zigrasite was discovered and is only known to occur in the Dunton Quarry at Oxford County, Maine. Zigrasite was specifically found in the giant 1972 gem tourmaline-bearing pocket at the Dunton Quarry. Zigrasite is named after James Zigras who originally discovered and brought the mineral to attention.
Lemanskiite is a mineral that was first discovered in a mine at Abundancia mine, El Guanaco mining district, Chile, with the ideal formula of NaCaCu5(AsO4)4Cl·3H2O. Originally, this mineral was discovered as being dimorphus with lavendulan, but in 2018 it was revised to only have 3 water molecules. Lemanskiite typically occurs as rosette-shaped aggregates of thin lamellar or needle-shaped aggregates, such as lammerite. Lemanskiite is dark sky blue with a light blue streak, it is brittle with an excellent cleavage plane. It was found on a dumping site in the abandoned Abundancia mine, El Guanaco mining district, Region II, Antofagasta Province, Chile The new mineral has been named after Chester S. Lemanski, Jr. This mineral and name were then approved by the Commission on New Minerals and Mineral Names of the International Mineralogical Association.
Tuzlaite is a borate mineral, associated with halides, named after the Tuzla salt mines in Bosnia and Hercegovina. A multitude of rare evaporate minerals have been discovered there, it being the only major evaporate deposit in the Balkans. This mineral has been approved as tuzlaite by the International Commission on New Minerals and Mineral Names.