Germanite

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Germanite
Germanite-231229.jpg
Germanite, probably from the Tsumeb Mine, Oshikoto Region, Namibia.
General
Category Sulfide mineral
Formula Cu26Ge4Fe4S32 [1]
IMA symbol Ger [2]
Strunz classification 2.CB.30
Dana classification 2.9.4.2
Crystal system Isometric
Crystal class Hextetrahedral (43m)
H-M symbol: (4 3m)
Space group P43n
Identification
ColorReddish grey tarnishing to dark brown
Crystal habit Usually massive; rarely as minute cubic crystals
Cleavage None
Tenacity Brittle
Mohs scale hardness4
Luster Metallic
Streak Dark grey to black
Diaphaneity Opaque
Specific gravity 4.4 to 4.6
Other characteristicsCell data: a = 10.585 Å Z = 1 [3]
References [4] [5]

Germanite is a rare copper iron germanium sulfide mineral, Cu26Fe4Ge4S32. It was first discovered in 1922, and named for its germanium content. [3] It is only a minor source of this important semiconductor element, which is mainly derived from the processing of the zinc sulfide mineral sphalerite. [6] Germanite contains gallium, zinc, molybdenum, arsenic, and vanadium as impurities. [3]

Its type locality is the Tsumeb Mine in Namibia where it occurs in a hydrothermal polymetallic ore deposit in dolomite in association with renierite, pyrite, tennantite, enargite, galena, sphalerite, digenite, bornite and chalcopyrite. [5] It has also been reported from Argentina, Armenia, Bulgaria, Cuba, Democratic Republic of Congo (Zaire), Finland, France, Greece, Japan, Republic of Congo (Brazzaville), Russia and the United States. [3]

X-Ray Powder Diffraction [7]
d spacing3.052.651.871.601.321.211.081.02
relative intensity101741221

References

  1. American Mineralogist (1984) 69:943-947
  2. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  3. 1 2 3 4 http://www.mindat.org/min-1681.html Mindat.org
  4. http://webmineral.com/data/Germanite.shtml Webmineral
  5. 1 2 http://rruff.geo.arizona.edu/doclib/hom/germanite.pdf Handbook of Mineralogy
  6. U.S. Geological Survey (2008), "Germanium—Statistics and Information", U.S. Geological Survey, Mineral Commodity Summaries https://minerals.usgs.gov/minerals/pubs/commodity/germanium/ Archived 2008-09-16 at the Wayback Machine
  7. Dana's New Mineralogy, 8th edition, Gaines et al., Wiley