Goldmanite | |
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General | |
Category | Nesosilicates, garnet |
Formula (repeating unit) | Ca3(V3+,Al,Fe3+)2(SiO4)3 |
IMA symbol | Glm [1] |
Strunz classification | 9.AD.25 |
Dana classification | 51.4.3b.4 |
Crystal system | Isometric |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Ia3d |
Unit cell | a = 12.01 Å V = 1,732.32 Å3; Z = 8 |
Identification | |
Color | Green, brownish–green |
Crystal habit | Dodecahedral crystals and anhedral grains |
Cleavage | None |
Mohs scale hardness | 6–7 |
Luster | Vitreous |
Streak | White |
Diaphaneity | Transparent to sub-opaque |
Specific gravity | 3.74 – 3.77 (measured) |
Optical properties | Isotropic, may show weak anisotropism |
Refractive index | n = 1.821 |
Common impurities | Cr, Mn, Mg |
References | [2] [3] [4] [5] |
Goldmanite is a green or greenish-brown silicate mineral of the garnet group with a chemical formula of Ca3(V3+,Al,Fe3+)2(SiO4)3. [3] [5]
It was first described in 1964 for an occurrence in the Laguna District, Cibola County, New Mexico and is named after Marcus Isaac Goldman (1881–1965), an American petrologist. [4] The type locality, South Laguna (or Sandy) mine area, was in vanadium rich clay within a metamorphosed uranium-vanadium deposit in sandstone. [3] [5] While studying these deposits, it was noted that garnet in relatively unmineralized sandstone is colorless, whereas garnet in dark well-mineralized rock, containing abundant vanadium clay and uranium deposits was deep green or brownish green. To confirm the green color was due to vanadium, two samples of garnet were separated from dark ore, analyzed, and found to be rich in vanadium. The South Laguna mine area was studied in 1955 and 1956 as part of an investigation of the geology and uranium deposits of the Laguna district by the USGS. [2]
In addition to the type location in the Sandy mine in New Mexico, it has been reported from Coat-an-Noz, Cotes-du-Nord, France; in drill core from the North Sea; from Klatovy, Czech Republic; Ishimskaya Luka, northern Kazakhstan; the Slyudyanka complex, Sayan Mountains, near Lake Baikal region of Russia and the Yamoto mine, Kagoshima Prefecture, Japan. [3] One of the world's biggest goldmanite deposits can be found in the Pezinok District, Slovakia. It is also found in the metalliferious black shales of the Korean Peninsula. [6]
Goldmanite is composed of calcium (24.79%), aluminium (3.34%), vanadium (12.6%), iron (2.3%), silicon (17.37%), and oxygen (39.59%). [5] Its chemical formula is Ca3(V3+,Al,Fe3+)2(SiO4)3.
The approximate density (3.74±.03) of goldmanite was determined by finding the density of diluted Clerici solution in which small fragments remained suspended. Because of fine grain size, more accurate determination of density was not attempted. The calculated density (3.737) agrees with the approximate value. The index of refraction was found by immersion to be 1.821±.001, using sodium light and adjusting for small temperature changes. Like so many calcium garnets, goldmanite was found to be weakly anisotropic. The cell edge of goldmanite is 12.011 Å, as determined by x-ray powder diffraction analysis. [2]
Garnets are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives.
Prehnite is an inosilicate of calcium and aluminium with the formula: Ca2Al(AlSi3O10)(OH)2. Limited Fe3+ substitutes for aluminium in the structure. Prehnite crystallizes in the orthorhombic crystal system, and most often forms as stalactitic or botryoidal aggregates, with only just the crests of small crystals showing any faces, which are almost always curved or composite. Very rarely will it form distinct, well-individualized crystals showing a square-like cross-section, including those found at the Jeffrey Mine in Asbestos, Quebec, Canada. Prehnite is brittle with an uneven fracture and a vitreous to pearly luster. Its hardness is 6-6.5, its specific gravity is 2.80-2.90 and its color varies from light green to yellow, but also colorless, blue, pink or white. In April 2000, rare orange prehnite was discovered in the Kalahari Manganese Fields, South Africa. Prehnite is mostly translucent, and rarely transparent.
Carnotite is a potassium uranium vanadate radioactive mineral with chemical formula K2(UO2)2(VO4)2·3H2O. The water content can vary and small amounts of calcium, barium, magnesium, iron, and sodium are often present.
Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals. These minerals form as a result of alteration which occurs when hydrothermal fluids interact with a protolith of either igneous or sedimentary origin. In many cases, skarns are associated with the intrusion of a granitic pluton found in and around faults or shear zones that intrude into a carbonate layer composed of either dolomite or limestone. Skarns can form by regional, or contact metamorphism and therefore form in relatively high temperature environments. The hydrothermal fluids associated with the metasomatic processes can originate from either magmatic, metamorphic, meteoric, marine, or even a mix of these. The resulting skarn may consist of a variety of different minerals which are highly dependent on both the original composition of the hydrothermal fluid and the original composition of the protolith.
Epidote is a calcium aluminium iron sorosilicate mineral.
Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x.
Uvarovite is a chromium-bearing garnet group species with the formula: Ca3Cr2(SiO4)3. It was discovered in 1832 by Germain Henri Hess who named it after Count Sergei Semenovitch Uvarov (1765–1855), a Russian statesman and amateur mineral collector. It is classified in the ugrandite group alongside the other calcium-bearing garnets andradite and grossular.
The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.
Grossular is a calcium-aluminium species of the garnet group of minerals. It has the chemical formula of Ca3Al2(SiO4)3 but the calcium may, in part, be replaced by ferrous iron and the aluminium by ferric iron. The name grossular is derived from the botanical name for the gooseberry, grossularia, in reference to the green garnet of this composition that is found in Siberia. Other shades include cinnamon brown (cinnamon stone variety), red, and yellow. Grossular is a gemstone.
Andersonite, Na2Ca(UO2)(CO3)3·6H2O, or hydrated sodium calcium uranyl carbonate is a rare uranium carbonate mineral that was first described in 1948. Named after Charles Alfred Anderson (1902–1990) of the United States Geological Survey, who first described the mineral species, it is found in sandstone-hosted uranium deposits. It has a high vitreous to pearly luster and is fluorescent. Andersonite specimens will usually glow a bright lemon yellow (or green with blue hints depending on the deposit) in ultraviolet light. It is commonly found as translucent small rhombohedral crystals that have angles close to 90 degrees although its crystal system is nominally trigonal. Its Mohs hardness is 2.5, with an average specific gravity of 2.8.
Nontronite is the iron(III) rich member of the smectite group of clay minerals. Nontronites typically have a chemical composition consisting of more than ~30% Fe2O3 and less than ~12% Al2O3 (ignited basis). Nontronite has very few economic deposits like montmorillonite. Like montmorillonite, nontronite can have variable amounts of adsorbed water associated with the interlayer surfaces and the exchange cations.
Hectorite is a rare soft, greasy, white clay mineral with a chemical formula of Na0.3(Mg,Li)3Si4O10(OH)2.
Roscoelite is a green mineral from the mica group that contains vanadium.
Uranium ore deposits are economically recoverable concentrations of uranium within the Earth's crust. Uranium is one of the more common elements in the Earth's crust, being 40 times more common than silver and 500 times more common than gold. It can be found almost everywhere in rock, soil, rivers, and oceans. The challenge for commercial uranium extraction is to find those areas where the concentrations are adequate to form an economically viable deposit. The primary use for uranium obtained from mining is in fuel for nuclear reactors.
Piemontite is a sorosilicate mineral in the monoclinic crystal system with the chemical formula Ca2(Al,Mn3+,Fe3+)3(SiO4)(Si2O7)O(OH). It is a member of the epidote group.
Patronite is the vanadium sulfide mineral with formula VS4. The material is usually described as V4+(S22−)2. Structurally, it is a "linear-chain" compound with alternating bonding and nonbonding contacts between the vanadium centers. The vanadium is octa-coordinated, which is an uncommon geometry for this metal.
Danalite is an iron beryllium silicate sulfide mineral with formula: Fe2+4Be3(SiO4)3S.
Coconinoite is a uranium ore that was discovered in Coconino County, Arizona. It is a phosphate mineral; or uranyl phosphate mineral along with other subclass uranium U6+ minerals like blatonite, boltwoodite, metazeunerite and rutherfordine.
Tangeite, also known as calciovolborthite, is a calcium, copper vanadate mineral with formula: CaCu(VO4)(OH). It occurs as a secondary mineral that can be found in sandstone and also in the oxidized zones of vanadium bearing deposits.
Paramontroseite (V4+O2) is a relatively rare orthorhombic vanadium oxide mineral in the Ramsdellite group. Synthetic paramontroseite may have applications in medicine, batteries and electronics.